硅橡膠與氟硅橡膠在汽車中的應(yīng)用

1、MOMENTIVEperformanee materialsThe scienee behind the solutions.邁圖高新材料集團(tuán)第四屆橡塑技術(shù)在汽車部件生產(chǎn)中的應(yīng)用論壇2009年08月0607口 上海硅橡膠與氟硅橡膠在汽車工業(yè)中的應(yīng)用與發(fā)展武玉斌 彈性體汽車應(yīng)用市場經(jīng)理/邊圖中國 劉增君 研發(fā)及應(yīng)用工程師/邁圖中國MOMENTIVEperformance materialsPresentation Agenda報告內(nèi)容邁圖高新材料集團(tuán)汽車行業(yè)的發(fā)展全球?qū)I(yè)有機硅公司對有機硅應(yīng)用的影響硅橡膠/氟硅橡膠的發(fā)展及在汽車零部件中的應(yīng)用 LSR液體硅橡膠在汽車零部件中的應(yīng)用4- MOMEN

2、TIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.The science behind the solutions.邁圖高新材料集團(tuán)Momentive Performanee Materials今前身為GE Advanced Materials GE高新材料寸 GE SiliconesGE有機硅GEBayer Silicones GE拜耳有機硅GE Toshiba Silicones GE東芝有機硅The science behind the sol

3、utions.The science behind the solutions.The science behind the solutions.4- MOMENTIVE performance materials邁圖高新材料集團(tuán)Momentive Performance Materials全球領(lǐng)先的一系列高科技材料的解決方案的提供者A global leader in a range of high-technology materials solutionsThe science behind the solutions.The science behind the solutions.S

4、ilicones有機硅QuartzAdvaneed Ceramics密封膠與粘合劑石英先進(jìn)陶瓷Sealant & AdhesivesElastomer, RTV彈性體,RTVHigh-purityfused quartzCeramic materialsSilicone and acrylic sealantsSilanes, Resinsand Specialties硅烷，硅樹脂Specialty Fluids特種硅油Urethane Additives聚氨酯添加劑MOMENTIVEperformanee materialsThe science behind the solutio

5、ns.Sealants & Adhesives密封膠與粘合劑4-MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.The science behind the solutions.中國車產(chǎn)量20032008一數(shù)據(jù)來源:Marklines Co.The science behind the solutions.The science behind the solutions.1O5OOO5OOOChina Vehicle Output2

6、0032004200520062007200 Cars Trucks Buses Total6,000,0005,000,0004,000,0003,000,0002,000,000 1,000,0000The science behind the solutions.YearThe science behind the solutions.The science behind the solutions.The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Perform

7、ance Materials Inc. All rights reserved.The science behind the solutions.中國車產(chǎn)量2009 1 -4一數(shù)據(jù)來源:Marklines Co.China Auto Output 2009 VS 20084,000,00G 呂 3,500,000 W 3,000,0002,500,0002,000,000 2009 Output 2008 Outputo n uQ)IE1,500,0001,000,000500,000JanFebMarMonthApr Jan to Apr4-MOMENTIVEperformance mate

8、rialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.9The science behind the solutions.全球研發(fā)平臺更多保證與更長使用壽命 更高的引擎效率更多電子控降低噪音新能源更嚴(yán)格的排放法規(guī)Automotive Trends汽車行業(yè)發(fā)展趨勢Global platformsHigher warranty/longer lifecycl

9、eBetter engine efficiencyMore electronicsNoise reductionNew engergyTighter Emission regulationsAll points accelerate growth of Silicones所有這些要求都促進(jìn)有機硅的應(yīng)用發(fā)展Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.Copyright 2009 Momentive Performance Mate

10、rials Inc. All rights reserved.11The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the so

11、lutions.汽車用硅橡膠/氟硅橡膠發(fā)展趨勢汽車工業(yè)的發(fā)展促進(jìn)了對有機硅彈性體材料的需求部分傳統(tǒng)的橡膠(NR, EPDM.ACM.FKM.) 9硅橡膠VMQ固體硅橡膠HCE今液體硅橡膠LSR固體氟硅橡膠FSE 9全氟液體氟硅橡膠FFSLMOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reservedperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.13The sc

12、ience behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.硅橡膠=VMQHCE / HCRLSR氟硅橡膠材料=FVMQFSE / FQE FSL / FFSL4- MOMENTIVE performance materialsWhy use silicone elastomers?為何使用硅橡膠?Easy and flexible in processing and production!加工工藝與生產(chǎn)簡便靈活Gen erally stable at high temper

13、ature通常高溫下穩(wěn)定Gen erally flexible at low temperature通常低溫下柔軟Little change of properties over a broad temperature range 在寬廣溫度范圍內(nèi)性能變化較小Heat CuredElastomer固體硅橡膠HCE HCR- HTVFVMQ- FSE- FQEResistant to many fluids耐多種液體Outstanding sealing properties 優(yōu)異的密封性Long service life 使用壽命長Excellent weatherability優(yōu)異的耐候性L

14、iquid siliconerubberI nert 一 non reactive with most materials惰性與大多數(shù)材料不反應(yīng)Very good dielectric properties 很好的介電性能液體硅橡膠LSR- LIM* Easily pigmentable under most conditions大多數(shù)情況下易著色Favorable flammability characteristics良好的阻燃特性FSL FFSLLow hardness without plasticizers低硬度無增塑劑Copyright 2009 Momentive Perform

15、ance Materials Inc. All rights reserved.15The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.Broad spectrum of properties具有諸多性能優(yōu)點Momentive Technology / Service / Support 邁圖集團(tuán)技術(shù)/服務(wù)/支持MOMENTIVEperformance materials

16、Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.not 140Required不要求12010080604030Volume swell in I RM 903 oil % 在I RM 903油中體積溶脹率% Overview ASTM D2000 Silicones vs Organic Elastomers 材料的ASTM分類一有機硅彈性體與其他橡膠材料的性能比較FKMVMQFSLFVMQ=HCE, HCR=FSE/ FQE/

17、FEPDM/LSRAEM, ACM, HNBRHRCPE / CSMNBR, ECOSBRCRNR2010FFKM75o5o7521o20522752Good heat & oil resista nee brings silicone elastomers big pote ntial applicati onsin Automotive有機硅橡膠與氟硅橡膠的耐高溫性和耐油性可滿足汽車的很多應(yīng)用Low Temperature Flexibility of Silicone Elastomer 有機硅彈性體的低溫柔性LTflexibility 55° C,TR10 = 60

18、° CExample 1: General Purpose Grade Silopren® LSR 2650 (Hardness 50 Sh.A) 通用液體硅橡膠Silopren® LSR 2650Example 2: Fluorosilicone RubberFSE and FFSL series氟硅橡膠系列產(chǎn)品TR10(DMA) TR10 DSC° c ° c ° cFFSL 7040-5961七7FFSL 7050-59FFSL 7060-61FFSL 7070-64-64FSE 7560 black -60FSE 7570 b

19、lack -57Fig. 15: Logarithmic decrement and shear modulus of Silopren LSR 2650 as a function of temperatureI' 焜罄Temperature (rC)snaPOLUsnQsqa(i) lest data. Actual results may vary,實際結(jié)果對能仃丈Both general purpose LSR and Fluorosilicone Elatomer have good low temperature flexibility通用型LSR與氟硅橡膠都具有良好的低溫

20、柔性The science behind the solutions.A動力系統(tǒng)/總成：發(fā)動機內(nèi)部與周邊A燃油系統(tǒng)：油箱與油路系統(tǒng)硅橡膠/氟硅橡膠在汽車橡膠零部件中的應(yīng)用部位Copyright 2009 Momentive Performance Materials Inc. All rights reserved.19The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.

21、調(diào)，雨刮A底盤：減震，管路A電器零部件：汽車電子防水包裝連接器密封，點火系統(tǒng)，車燈系統(tǒng)等Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.HCR/ LSR的部分應(yīng)用實

22、例汽車工業(yè)火花塞護(hù)套點火電纜冷卻器墊圈 發(fā)動機蓋密封 傳動系統(tǒng)密封Copyright 2009 Momentive Performance Materials Inc. All rights reserved.21The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.O形密封Copyright 2009 Momentive Performance Materials Inc

23、. All rights reserved.#The science behind the solutions.接頭密封套 插頭墊圈膠管4- MOMENTIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.#The science behind the solutions.邁圖有機硅一自潤滑液體硅橡膠LSR自潤滑LSR產(chǎn)品規(guī)格5ShoreA10ShoreA標(biāo)準(zhǔn)產(chǎn)品MOMENTIVEperformance materialsSilopren*LSR 348

24、6/：TP 3648超低壓縮 變形產(chǎn)品低壓縮變 形產(chǎn)品20ShoreA30ShoreA4050Shore ShoreAASilopren*口;R 3785/STr 7%Att=M75ttpilopre n*"T$R 3485/354% oilpren13596oililopren* R 3596/30 TPJ967 nilSilopre rTSR 3786/2 0.TP 394460ShoreA70ShoreA80ShoreAollOpren'" ItSR 3285/5C2 %叫Silopren*H)R 3485/ >0Silopren*1 SR 3186/5

25、TP 3651Silopren* | Silopren*SR 3286/4CSR 3286/!TP 3649 TP 4224Silopren* | Silopren*SR 3286/OflSR 3286/7TP 0125 I TP 36502%-otiSilopren* | Silopren* | Silopren*SR 3386/：TP 3616R 3386/，>R 3486/5 TP 42683%otFCopyright 2009 Momentive Performance Materials Inc. All rights reserved.23The science behind

26、 the solutions.應(yīng)用一發(fā)動機IMTF.WXLEawwroRWiCTERPUM9/ITURBOCKAnGCHNTAKC VAMFOLDtOCCMTRIC WFTL PICKUP加伽 ql蝕辟Ufam CtyTCH硅橡膠/氟硅橡膠產(chǎn)品SE系列 高性能硅橡膠TSE系列耐熱硅橡膠3.硅膠膠管 Rubber Hoses冷卻液管 Coolant Hoses熱風(fēng)管 Hot Air Hoses渦輪增壓管 Turbocharger Hoses生產(chǎn)工藝FSE系列氟硅橡膠-渦輪增壓管硅膠簾線壓延成型工藝，擠出纏繞工藝/熱空氣/蒸汽硫化編能2高溫穩(wěn)定性耐冷卻液要求較好的膠料格林強度要求膠料良好的加工性，

27、粘合性MOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reservedperformance materials0型圈 O-RingsThe science behind the solutions.The science behind the solutions.應(yīng)用P3密封件硅橡膠產(chǎn)品固體膠硅橡膠TSE或SE系列氟硅橡膠FSE液體膠 LSR FSL/ FFSL模壓/注壓注射性能特點要求加工性耐介質(zhì)性能（汕，燃油，OEM油等.）盡管都是VMQ或FVMQ,但不同廠家/規(guī) 格的硅膠/氟硅膠性能/穩(wěn)定性

28、差異性往往很 大，要關(guān)注混煉膠的物性，也要關(guān)注其加工性和穩(wěn)定性需要認(rèn)真嚴(yán)格的系列試驗評估。壓縮變形威蠶穩(wěn)定性MOMENTIVEperformance materials邁圖公司為客戶提供穩(wěn)定的適合不同用途的系列產(chǎn)品Copyright 2009 Momentive Performance Materials Inc. All rights reserved17耐高低溫性The science behind the solutions.生產(chǎn)工藝濾油器墊片HCELSR /LIM應(yīng)用Anti Drain Back valve模壓或注射成型性能特點1. 濾油器墊片 Oil filter element耐

29、油，耐熱寬廣使用穩(wěn)定范圍：綜合了高溫穩(wěn)定性與低溫柔性 低壓縮永久變形Copyright 2009 Momentive Performance Materials Inc. All rights reserved.29MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the sol

30、utions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.4.發(fā)動機周邊部件密封墊片進(jìn)氣岐閥密封墊片發(fā)動機蓋密封墊片Copyright 2009 Momentive Performance Materials Inc. All rights reserved.31MOMENTIVEperformance materialsThe science behind the s

31、olutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.XE20- 53x系列XE20-C4xx 系列LSx85/zLSR3x86/zLSR3x96/z FSL7x86/z邁圖提供“系列多規(guī)格LSR” 和客戶定制產(chǎn)品Copyright 2009 Momentive Performance Materials Inc. All rights reserved20安裝便

32、利，高安全和穩(wěn)定性 寬廣的使用溫度（60+2009） 優(yōu)異的耐熱性能優(yōu)異穩(wěn)定的電性能抗外界電場干擾強 密封性能優(yōu)異耐侯性，耐老化性優(yōu)異LSR加工容易，高效 MOMENTIVEperformance materials汽車性能提高對汽車電子連接器密封提出新要求更多汽車電子控制 9使用更多連接器,單車達(dá)幾百個更穩(wěn)定的電子操控 9更好的密封硅橡膠/氟硅橡膠材料更簡易的加工/安裝9LSR注射成型自潤滑密封件Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materi

33、alsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.o環(huán)保與燃油的要求o汽車發(fā)動機的溫度o對壓縮永久變形的要求9耐介質(zhì)9耐高低溫9降低壓縮永久變形Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEp

34、erformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.MOMENTIVEperformance materialsThe scienc

35、e behind the solutions.6.硅橡膠用于點火系統(tǒng)-火花塞護(hù)套不斷發(fā)展的邁圖有機硅彈性體產(chǎn)品滿足新的應(yīng)用要求TSE221 TSE2527SC0601 -608BAC161-SP高安全穩(wěn)定性寬廣的使用溫度(60+200'C) 優(yōu)異的耐熱性能優(yōu)異穩(wěn)定的絕緣性能，耐電弧性 抗外界電場干擾強密封性能優(yōu)異耐侯性，耐老化性優(yōu)異加工容易LSR2660Z邁圖舉供“即買即用的客戶定制硅膠MOMENTIVEperformance materialsThe science behind the solutions.Car body chassis7.硅橡膠用于底盤減震-排氣管吊耳 不斷發(fā)展

36、的邁圖有機硅彈性體產(chǎn)品滿足新的應(yīng)用要求硅橡膠取代傳統(tǒng)的合成橡膠-降低噪音提高車的乘用舒適性 寬廣的使用溫度(60+20(TC) 耐侯性，耐老化性優(yōu)異-耐高溫優(yōu)異-長期使用穩(wěn)定性好-彈性好，耐油性邁圖提供“即買即用的客戶定制硅膠 4-Copyright 2009 Momentive Performance Materials Inc. All rights reserved.LSR23易加工9.氟硅在汽車中的應(yīng)用Seals / Gaskets密封圈與密封墊2- comp. Molding 雙射成型Umbrella-Valves 傘閥MOMENTIVEperformance materialsTh

37、e science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.Flaps 薄墊片 I Fuel燃規(guī)Ives I O-Rings osyfflMOMENTIVEperformance materialsThe science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions.Conn ecto®連接器硬度（邵氏A） 40Membranes 隔膜M

38、OMENTIVEperformance materialsThe science behind the solutions.MOMENTIVEperformance materialsThe science behind the solutions. Ml urwfLx»amr rvwowwiisting FVMQ Applications 現(xiàn)有氟硅橡膠的應(yīng)用MOMENTIVEperformance materialsThe science behind the solutions.8.燃油系統(tǒng)Fuel systemFluorosilicone Applicatio ns燃油管的連接

39、快速接頭密封燃油箱一燃油密封閥一進(jìn)入閥控制閥FVMQ are used in fuel system where needs good sealing & fuel resistance氟硅橡膠用于燃油系統(tǒng)需要密封和耐油的部件purrornTdnLCiTTdTerTdTbFluorosilicone Products Family Heat Cured Rubber 氟硅橡膠高溫硫化固體氟硅橡膠Copyright 2009 Momentive Performance Materials Inc. All rights reserved.41MOMENTIVEperformance ma

40、terialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Shore A硬度203040506070通用低壓縮變形Standard Low C/SFSE7520FSE7540FSE7560FSE7570Copyright 2009 Momentive Performance Materials Inc.

41、All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.FSE7340FSE7360High Tear Strength高抗撕裂Copyright 2009 Momentive Performance Materia

42、ls Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.

43、43MOMENTIVEperformance materialsThe science behind the solutions.硬度FSL液體氟硅橡膠產(chǎn)品系列30 Sh. A 40 Sh. A 50 Sh. A 60 Sh. ACopyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials In

44、c. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.#MOMENTIVEperformance materialsThe science behind the solutions.FFSL全氟液體氟硅橡膠產(chǎn)品系列The science behind the solutions.The science behind the solut

45、ions.40 Sh. A50 Sh A60 Sh.A70 Sh.AThe science behind the solutions.4- MOMENTIVE performance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.28The science behind the solutions.9邁圖超透明LSR在光學(xué)產(chǎn)品中的應(yīng)用潛力The science behind the solutions.The science behind the solutions.The sc

46、ience behind the solutions.The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.294- MOMENTIVE performance materials邁圖新開發(fā)的Crystal Clear LSR超低硬度高透明液體硅橡膠Silopren® LSR 7005> Silopren® LSR 7005 新產(chǎn)品邁圖公司新開發(fā)的高透明液體硅橡膠> Application應(yīng)用基于照相技術(shù)的駕

47、駛輔助系統(tǒng)，集成了雨水和光傳感器為一體。Ref: KOSTAL GmbH & Co. KG and Momentive Performance Materials GmbMOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.30Ultra-Clear LSR超透明液體硅橡膠潛在的汽車光學(xué)應(yīng)用The science behind the solutions.The science behind the solutions.LED鏡片high

48、 heat resistance high UV resistance光學(xué)鏡片high transparency no inner stress no birefringeneeThe science behind the solutions.The science behind the solutions.Copyright 2009 Momentive Performance Materials Inc. All rights reserved.314-MOMENTIVEperformance materialsEschenbachThe science behind the soluti

49、ons.硅橡膠/氟硅橡膠材料的發(fā)展高性能、易加工、功能提升、新應(yīng)用更宣ouels-spw_丄Processability加工性優(yōu)異的加工性、穩(wěn)定的產(chǎn)品性能、合理的性/價比, 共同開發(fā)，協(xié)同雙贏液體硅橡膠LSR注的優(yōu)勢MOMENTIVECopyright 2009 Momentive Performance Materials Inc. All rights reserved,performance materialsThe science behind the solutions.具有成本優(yōu)勢的液體硅橡膠LSR加工工藝A全自動化工藝，自動生產(chǎn)單元A生產(chǎn)周期短A流動性優(yōu)異，可充滿長模具流道單?？啥噙_(dá)256模腔制品無廢邊冷流道技術(shù)，無注膠口膠或注膠損失A最低模具磨損，可達(dá)100萬次單件成本可能低The science behind the solutions.The science behind the solutions.MOMENTIVEperformance materialsCopyright 2009 Momentive Performance Materials Inc. All rights reserved.34The science behind the solutions.2 Componets Injection Molding with