DB37-T 3979-2020 動物源性食品中211種農(nóng)藥及相關(guān)化學(xué)品殘留量的測定　氣相色譜-質(zhì)譜法-（高清版）

ICS67.050X04

DB37山 東 省 地 方 標(biāo) 準(zhǔn)DB37/T3979—2020Determinationof211pesticidesandrelatedchemicalsresiduesinanimal-derivedfoods—Gaschromatography-tandemmassspectrometry202006Determinationof211pesticidesandrelatedchemicalsresiduesinanimal-derivedfoods—Gaschromatography-tandemmassspectrometry20200608發(fā)布20200708山東省市場監(jiān)督管理局發(fā)布目次目次前言 II112范引文件 1314劑材料 15器設(shè)備 36處理 3748果算表述 59密度 510量和收率 6附錄B（料附）211農(nóng)及關(guān)學(xué)保留間定離對定性子對 14附錄B（料附）211農(nóng)及關(guān)學(xué)保留間定離對定性子對 14附錄C（料附）211農(nóng)及代物標(biāo)化物反監(jiān)（MRM）色圖 21附錄D（范附）實(shí)驗(yàn)內(nèi)復(fù)要求 28附錄E（范附）實(shí)驗(yàn)間現(xiàn)要求 29附錄F（料附）樣品加度及回率實(shí)驗(yàn)據(jù) 30前言前言本標(biāo)準(zhǔn)按照GB/T1.1—2009給出的規(guī)則起草。本標(biāo)準(zhǔn)由青島海關(guān)提出、歸口并組織實(shí)施。本標(biāo)準(zhǔn)起草單位：青島海關(guān)技術(shù)中心、通標(biāo)標(biāo)準(zhǔn)技術(shù)服務(wù)（青島）有限公司。本標(biāo)準(zhǔn)主要起草人：朱文璇、王渤、程剛、王劍、王侖、陳凱、逄昔莎、崔曉妮、辛文、湯永嬌、田壯、王林、王宮璞、王玉花、王磊磊、孫正君、赫秀萍。動物源性食品中211種農(nóng)藥及相關(guān)化學(xué)品殘留量的測定氣相色譜-質(zhì)譜法范圍211它食品可參照執(zhí)行。GB2763食品安全國家標(biāo)準(zhǔn)食品中農(nóng)藥最大殘留限量。GB/T6682分析實(shí)驗(yàn)室用水規(guī)格和試驗(yàn)方法。3原理3原理試樣中的農(nóng)藥經(jīng)乙腈提取，采用分散固相萃?。╠-SPE）或固相萃?。⊿PE）方法凈化，氣相色譜-串聯(lián)質(zhì)譜儀檢測，內(nèi)標(biāo)法或者外標(biāo)法定量。4試劑與材料除另有規(guī)定外，在分析中僅使用確認(rèn)為符合殘留檢測要求等級的試劑，水為符合GB/T6682規(guī)定的一級水。試劑乙腈（CH3CN，CAS：75-05-8）丙酮（CH3COCH3，CAS67-64-1）（MgSO4，CAS：7487-88-9）4.1.4（Na3C6H5O7，CAS：6132-04-3）（C6H6Na2O7，CAS：6132-05-4）（(CH3COO)2Pb，CAS301-04-2）飽和乙酸鉛溶液配制：將45g乙酸鉛加入100g水中溶解，一邊攪拌，直到加進(jìn)的乙酸鉛飽和。標(biāo)準(zhǔn)品211954.3.2：95.4100.1mg）10mL-18℃±4℃避、、C）211C10mL10mg/L（18℃±41.0mLA、B、（4.4.2）于10mLmg/L0℃～4℃避光10mg（0.1mg）10mL1000mg/L的內(nèi)標(biāo)儲備液。吸取0.1mL的內(nèi)標(biāo)儲備溶于10mL容量瓶中，用丙酮定容至刻度，配制成10mg/L2mL10mLmg/L（4.4.3）0.05mL、0.1mL、0.2mL0.5mL、1.0mL于10mL0.5mL5μg/L10μg/L20μg/L50μg/L100μg/LA0.02mg/kg和0.05mg/kg50μL（4.4.3）mL（4.5.7）材料SPE（）：PSA/C18，1000mg/1000mg，6mL-N（PSA）：40～60μm（C18）：40～60μmQuEChERS（4g0.5g1g，1gQuEChERS（PSA300mg/C18300mg）。EMR（）：（300mg/3mL）4.5.7）：13mm×0.22μm（GC-MS/MS）（EI）5.20.01g0.000g8500r/min前處理從所取全部樣品中取出有代表性樣品約500g，用組織搗碎機(jī)充分搗碎均勻，均分成兩份，分別裝入潔凈容器中，密封，并標(biāo)明標(biāo)記。從所取全部樣品中取出有代表性樣品約500g，充分混勻，均分成兩份，分別裝入潔凈容器中，密封，并標(biāo)明標(biāo)記。注：以上樣品取樣部位按GB2763附錄A執(zhí)行。樣品于-18℃以下冷凍保存。5g0.01g）50mL5mL3mL10mL（4.5.4），250rpm振蕩min8500rpm離心2min0.45μmmLEMR柱（4.5.6）50μL1.00.22μm牛奶5g0.0150mL3mL10mL（4.5.4），250rpm30min8500rpm2min，取5mL2mL50μL0.22μm肝臟準(zhǔn)確稱取5g樣品（精確至0.01g）置于50mL離心管中，加入5mL水浸泡后，加入3mL飽和乙酸鉛溶液（4.3），加10mL乙腈，加萃取鹽包（4.5.4），渦勻。250rpm振蕩30min提取，8500rpm離心2min，上清液冷凍4h過0.45μm微孔濾膜后取2mL使用SPEPSA/C18（4.5.1）串聯(lián)柱（乙腈活化上樣和洗脫）凈化后旋蒸至近干，如果用內(nèi)標(biāo)法，需加入50μL內(nèi)標(biāo)溶液（4.4.4），用乙腈定容至1.0mL，過0.22μm微孔濾膜后，用于測定。測定530m×250mm×0.25μm：702min25℃/min1503℃/min200℃/min280min7.1.399.9991.0mL/min7.1.42601μL7.1.770eV7.1.770eV7.1.8230GC-MS230℃。B被測試樣中目標(biāo)農(nóng)藥色譜峰的保留時(shí)間與相應(yīng)標(biāo)準(zhǔn)色譜峰的保留時(shí)間相比較，相對誤差應(yīng)在±2.5%之內(nèi)。1表1定性測定時(shí)相對離子豐度的最大允許偏差單位為百分率本方法的標(biāo)準(zhǔn)物質(zhì)多反應(yīng)監(jiān)測GC-MS/MS圖參見附錄C。相對離子豐度＞5020～50（含）10～20（含）≤10允許相對偏差±20±25±30±507.2.3定量內(nèi)標(biāo)法或外標(biāo)法定量。按以上步驟對同一試樣進(jìn)行平行測定。除不稱取試樣外，均按上述步驟進(jìn)行。 ..................................(1) ......................................(2)式中：ω——試樣中被測物殘留量，單位為毫克每千克（mg/kg）；ρ（μg/mL）；AAsρi（μg/mL）；ρsi（μg/mL）；AsiAiV（mL）；m（g）。mg/kg精密度（）D（）E定量限本方法的定量限見附錄A。當(dāng)添加水平為0.01mg/kg、0.02mg/kg、0.05mg/kg時(shí)，添加回收率參見附錄F。附錄A（資料性附錄）211種農(nóng)藥及相關(guān)化學(xué)品中英文名稱、CAS號、定量限211種農(nóng)藥及相關(guān)化學(xué)品中英文名稱、CAS號、定量限見表A.1。表A.1211CAS序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋內(nèi)標(biāo)D10-Chlorpyrifos氘代毒死蜱285138-81-0————————————A組1Ametryn莠滅凈834-12-80.010.010.010.010.010.012Benfuresate呋草磺/呋草黃68505-69-10.010.010.010.010.010.013BHC-alphaα-六六六319-84-60.010.010.010.010.010.014BHC-betaβ-六六六319-85-70.010.010.010.010.010.015BHC-deltaδ-六六六319-86-80.010.010.010.010.010.016BHC-epsilonepsilon-六六六6108/10/70.010.010.010.010.010.017Bifenox甲羧除草醚42576-02-30.010.010.010.010.010.018Bromopropylate溴螨酯18181-80-10.010.010.010.010.010.019Buprofezin噻嗪酮69327-76-00.010.010.010.010.010.0110Chlordane-trans反式氯丹5103-74-20.010.010.010.010.010.0111Chlorpropham氯苯胺靈101-21-30.010.010.010.010.010.0112Cyflufenamid環(huán)氟箘胺180409-60-30.010.010.010.010.010.0113Cyhalothrin(lambda)高效氯氟氰菊酯65732-07-20.010.010.010.010.010.0114Cyproconazole環(huán)丙唑醇94361-06-50.010.010.010.010.010.0115Chlorthal-dimethyl氯酞酸甲酯1861-32-10.010.010.010.010.010.0116DDD-o，p'o，p'-滴滴滴53-19-00.010.010.010.010.010.0117DDD-p，p'p，p'-滴滴滴72-54-80.010.010.010.010.010.0118DDE-o，p'o，p'-滴滴伊3424-82-60.010.010.010.010.010.0119DDT-o，p'o，p'-滴滴涕789-02-60.010.010.010.010.010.0120Deltamethrin溴氰菊酯52918-63-50.010.010.010.010.010.0121Dicloran氯硝胺99-30-90.010.010.010.010.010.0122Dieldrin狄氏劑60-57-10.010.010.010.010.010.0123Diphenamid雙苯酰草胺957-51-70.010.010.010.010.010.0124Edifenphos敵瘟磷17109-49-80.010.010.010.010.010.0125Endosulfan-alphaα-硫丹959-98-80.010.010.020.010.010.0126Endosulfan-betaβ-硫丹33213-65-90.010.010.010.010.010.01A.1211CAS（）序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋27Ethalfluralin乙丁烯氟靈55283-68-60.010.010.010.010.010.0128Fenothiocarb苯硫威(苯丁硫威)62850-32-20.010.010.010.010.010.0129Fenvalerate&EsFenvalerate氰戊菊酯&高效氰戊菊酯51630-58-1&66230-04-40.010.010.010.010.010.0130Flurochloridone氟咯草酮/氟氯戊菊酯61213-25-00.010.010.010.010.010.0131Flutolanil氟酰胺66332-96-50.010.010.010.010.010.0132Heptenophos庚烯磷23560-59-00.010.010.010.010.010.0133Isazofos氯唑磷42509-80-80.010.010.010.010.010.0134Mepronil滅銹胺55814-41-00.010.010.010.010.010.0135Monocrotophos久效磷6923-22-40.010.020.010.010.010.0136Oxadixyl惡霜靈77732-09-30.010.010.010.010.010.0137Penconazole戊菌唑66246-88-60.010.010.010.010.010.0138Pendimethalin二甲戊樂靈40487-42-10.010.010.010.010.010.0139Pentachloroanisole五氯茴香醚1825-21-40.010.010.010.010.010.0140Pentoxazone戊基惡唑酮/環(huán)戊惡草酮110956-75-70.010.010.010.010.010.0141Phenthoate稻豐散2546420.010.010.010.010.010.0142Phenylphenol，2-鄰苯基苯酚90-43-70.010.010.010.010.010.0143Pirimiphos-methyl甲基嘧啶磷29232-93-70.010.010.010.010.010.0144Procymidone腐霉利32809-16-80.010.010.010.010.010.0145Profenofos丙溴磷41198-08-70.010.010.010.010.010.0146Propaphos丙蟲磷7292-16-20.010.010.010.010.010.0147Propham苯胺靈122-42-90.010.010.010.010.010.0148Sulprofos硫丙磷35400-43-20.010.010.010.010.010.0149Tolclofos-methyl甲基立枯磷57018-04-90.010.010.010.010.010.0150Triallate野麥畏2303-17-50.010.010.010.010.010.0151Triazophos三唑磷24017-47-80.010.010.010.010.010.0152Vinclozolin乙烯菌核利50471-44-80.010.010.010.010.010.01B組53Acrinathrin氟丙菊酯101007-06-10.010.010.010.010.010.0154Alachlor甲草胺15972-60-80.010.010.010.010.010.0155Azinphos-ethyl乙基谷硫磷(乙基保棉磷)2642-71-90.010.010.010.010.010.0156Benalaxyl苯霜靈71626-11-40.010.010.010.010.010.0157Bendiocarb惡蟲威22781-23-30.010.010.010.010.010.0158Benfluralin乙丁氟靈1861-40-10.010.010.010.010.010.01序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋59Bromophos甲基溴硫磷(溴硫磷)2104-96-30.010.010.010.010.010.0160Bromophos-ethyl乙基溴硫磷4824-78-60.010.010.010.010.010.0161Butralin地樂胺(雙丁樂靈)33629-47-90.010.010.010.010.010.0162Cadusafos硫線磷95465-99-90.010.010.010.010.010.0163Carbophenothion三硫磷786-19-60.010.010.010.010.010.0164Chlorbenside氯殺螨103-17-30.010.010.010.010.010.0165Chlordane-cis順式氯丹5103-71-90.010.010.010.010.010.0166Chlordane-oxy氧氯丹27304-13-80.010.010.010.010.010.0167Chlorfenapyr蟲螨腈(溴蟲腈）122453-73-00.010.010.010.010.010.0268Chlorfenson殺螨酯80-33-10.010.010.010.010.010.0169Chlorfenvinphos毒蟲畏470-90-60.010.010.010.010.010.0170Chlorobenzilate乙酯殺螨醇510-15-60.010.010.010.010.010.0171Chlorpyrifos毒死蜱2921-88-20.010.010.010.010.010.0172Chlorpyrifos-methyl甲基毒死蜱5598-13-00.010.010.010.010.010.0173Cyanophos殺螟腈2636-26-20.010.010.010.010.010.0174Cyhalofop-butyl氰氟草酯122008-85-90.010.010.010.010.010.0175DDE-p，p'p，p'-滴滴伊72-55-90.010.010.010.010.010.0176DDT-p，p'p，p'-滴滴涕50-29-30.010.010.010.010.010.0177Tribufos脫葉磷78-48-80.010.010.010.010.010.0178Diazinon二嗪磷333-41-50.010.010.010.010.010.0179Diclofop-methyl二氯硫醚磷51338-27-30.010.010.010.010.010.0180Dicrotofos百治磷141-66-20.010.010.010.010.010.0181Dimepiperate哌草丹61432-55-10.050.010.010.020.010.0182Dimethipin噻節(jié)因55290-64-70.020.010.050.010.010.0183Dimethylvinphos甲基毒蟲畏67628-93-70.010.010.010.010.010.0184Dioxathion敵殺磷78-34-20.010.010.010.010.010.0185Diphenylamine二苯胺122-39-40.010.010.010.010.010.0186Dithiopyr氟硫草定97886-45-80.010.010.010.010.010.0187Endrin異狄氏劑72-20-80.010.010.010.010.010.0188EPN苯硫磷2104-64-50.010.010.010.010.010.0189Ethion乙硫磷563-12-20.010.010.010.010.010.0190Ethofumesate乙氧呋草黃26225-79-60.010.010.010.010.010.0191Ethychlozate吲熟酯27512-72-70.010.010.010.010.010.0192Etofenprox醚菊酯80844-07-10.010.010.010.010.010.0193Etoxazole乙螨唑、依殺螨153233-91-10.010.010.010.010.010.0194Fenamidone咪唑菌酮161326-34-70.010.010.010.010.010.0195Fenamiphos苯線磷22224-92-60.010.010.010.010.010.01序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋96Fenarimol氯苯嘧啶醇60168-88-90.010.010.010.010.010.0197Fenpropathrin甲氰菊酯39515-41-80.010.020.020.020.020.0298Fensulfothion豐索磷115-90-20.010.010.010.010.010.0199Fluacrypyrim嘧螨酯229977-93-90.010.010.010.010.010.01100Fluvalinate-tau氰戊菊酯51630-58-10.050.050.050.050.050.05101Fonofos地蟲硫磷944-22-90.010.010.010.010.010.01102Furalaxyl呋霜靈57646-30-70.010.010.010.010.010.01103Heptachlorexo-epoxide(isomerB)環(huán)氧七氯1024-57-30.010.010.010.010.010.01104Iprodione異菌脲36734-19-70.010.010.010.010.050.01105Isodrin異艾氏劑465-73-60.010.010.010.010.010.01106Isofenphos異柳磷25311-71-10.010.010.010.010.010.01107Isofenphos-methyl甲基異柳磷99675-03-30.010.010.010.010.010.01108Methoxychlor甲氧氯72-43-50.020.010.010.010.010.01109Mirex滅蟻靈2385-85-50.010.010.010.010.010.01110Myclobutanil滅克落/腈菌唑88671-89-00.010.010.010.010.010.01111Nitrofen除草醚1836-75-50.010.010.010.010.010.01112Oxadiazon惡草酮19666-30-90.010.010.010.010.010.01113Paclobutrazol多效唑76738-62-00.010.010.010.010.010.01114Parathion對硫磷56-38-20.010.010.010.010.010.01115Parathion-methyl甲基對硫磷298-00-00.010.010.010.010.010.01116Pentachloroaniline五氯苯胺527-20-80.010.010.010.010.010.01117PhorateSulfoxide甲拌磷亞砜2513540.050.050.050.050.050.05118Phosfolan硫環(huán)磷947-02-40.010.010.010.010.010.01119PhosphamidonI磷胺I13171-21-60.010.010.010.010.010.01120Piperonylbutoxide增效醚1951/3/60.010.010.010.010.010.01121Pirimicarb抗蚜威23103-98-20.010.010.010.010.010.01122Pirimiphos-ethyl嘧啶磷23505-41-10.010.010.010.010.010.01123Prometryn撲草凈7287-19-60.010.010.010.010.010.01124Propargite炔螨特2312-35-80.010.010.010.010.010.01125Propetamphos胺丙畏（巴胺磷，烯蟲磷）31218-83-40.010.010.010.010.010.01126Pyraclofos吡唑硫磷89784-60-10.010.010.010.010.010.01127Pyriproxyfen蚊蠅醚（吡丙醚）95737-68-10.010.010.010.010.010.01128Quinalphos喹硫磷13593-03-80.010.010.010.010.010.01129Silafluofen硅醚菊酯105024-66-60.010.010.010.010.010.01序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋130Simazine西瑪津122-34-90.010.010.010.010.020.02131Tebupirimfos丁基嘧啶磷96182-53-50.010.010.010.010.010.01132Terbacil特草定5902-51-20.010.010.010.010.010.01133Terbuthylazine特丁津5915-41-30.010.010.010.010.010.01134Tetraconazole四氟醚唑112281-77-30.010.010.010.010.010.01135Thiometon二甲基硫吸磷（甲基乙拌磷）640-15-30.010.010.010.010.010.01136Trifluralin氟樂靈1582-09-80.010.010.010.010.010.01C組137Aldrin艾氏劑309-00-20.010.010.010.010.010.01138Anthraquinone蒽醌84-65-10.010.010.010.010.010.01139Atrazine-desethyl去乙基莠去津6190-65-40.010.010.010.010.010.01140BHC-gamma(Lindane)γ-六六六/林丹58-89-90.010.010.010.010.010.01141Bifenthrin聯(lián)苯菊酯82657-04-30.010.010.010.010.010.01142Bioresmethrin生物芐呋菊酯28434-01-70.010.050.050.020.050.02143Bromacil除草定314-40-90.010.010.010.010.010.01144Butachlor丁草胺23184-66-90.010.010.010.010.010.01145Butamifos抑草磷36335-67-80.010.010.010.010.010.01146Chlozolinate克氯得84332-86-50.010.010.010.010.010.01147Clomazone異惡草松81777-89-10.010.010.010.010.010.01148Cloquintocet-mexyl解毒喹99607-70-20.010.010.010.010.010.01149Cyfluthrin氟氯氰菊酯68359-37-50.010.010.010.010.010.01150Cypermethrin氯氰菊酯52315-07-80.010.010.010.010.010.01151Cyphenothrin苯醚氰菊酯/賽樂靈39515-40-70.010.010.020.010.010.01152Cyprodinil嘧菌環(huán)胺121552-61-20.010.010.010.010.010.01153DEET避蚊胺134-62-30.010.010.010.010.010.01154Dichlofenthion除線磷97-17-60.010.010.010.010.010.01155Diclobutrazol芐氯三唑醇75736-33-30.010.010.010.010.010.01156Dicofol三氯殺螨醇115-32-20.010.010.010.010.010.01157Difenoconazole苯醚甲環(huán)唑119446-68-30.010.010.010.010.010.01158Difenzoquatmethylsulfate野燕枯甲基硫酸鹽43222-48-60.010.010.010.010.010.01159Dimethenamid二甲吩草胺87674-68-80.010.010.010.010.010.01160Dioxabenzofos蔬果磷3811-49-20.010.010.010.010.010.01161Disulfoton乙拌磷298-04-40.010.010.010.010.010.01162Endosulfansulfate硫丹硫酸酯1031-07-80.010.010.010.010.010.01163Ethoprophos滅線磷13194-48-40.010.010.010.010.010.01序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋164Etrimfos乙嘧硫磷38260-54-70.010.010.010.010.010.01165Famoxadone惡唑菌酮131807-57-30.010.010.010.010.010.01166Fenitrothion殺螟硫磷（殺螟松122-14-50.010.010.010.010.010.01167Fenthion倍硫磷55-38-90.010.010.010.010.010.01168Fenthionsulfone倍硫磷砜3761-42-00.010.010.010.010.010.01169Fenthionsulfoxide倍硫磷亞砜3761-41-90.010.010.010.010.010.01170Fipronil氟蟲腈120068-37-30.010.010.010.010.010.01171Flucythrinate氟氰戊菊酯70124-77-50.010.010.010.010.010.01172Fluoroglycofen-ethyl乙羧氟草醚77501-90-70.010.010.010.010.020.01173Fluquinconazole氟喹唑136426-54-50.010.010.010.010.010.01174Fluridone氟啶草酮59756-60-40.010.010.010.010.010.01175Flusilazole氟硅唑85509-19-90.010.010.010.010.010.01176Heptachlor七氯76-44-80.010.010.010.010.010.01177Hexachlorobenzene六氯苯118-74-10.010.010.010.010.010.01178Hexaconazole六那唑/己唑醇79983-71-40.010.010.010.010.010.01179Hexazinone環(huán)嗪酮51235-04-20.010.010.010.010.010.01180Isocarbophos水胺硫磷24353-61-50.010.010.010.010.010.01181Mecarbam滅蚜磷2595-54-20.010.010.010.010.010.01182Metalaxyl甲霜靈57837-19-10.010.010.010.010.010.01183Methyl-pentachlorophenylsulfide甲基五氯苯硫醚1825-19-00.010.010.010.010.010.01184Metribuzin嗪草酮21087-64-90.010.010.010.010.010.01185Napropamide敵草胺15299-99-70.010.010.010.010.010.01186Nitrothal-isopropyl酞菌酯10552-74-60.010.010.010.010.010.01187Pentachloronitrobenzene五氯硝基苯82-68-80.010.010.010.010.010.01188Permethrin氯菊酯52645-53-10.010.010.010.010.010.01189Phenothrin苯醚菊酯26002-80-20.010.010.020.020.010.01190Phorate甲拌磷298-02-20.010.010.010.010.010.01191Phoratesulfone甲拌磷砜2513860.010.010.010.010.010.01192Phosalone伏殺硫磷2310-17-00.010.010.010.010.010.01193PhosphamidonII磷胺II13171-21-60.010.010.010.010.010.01194Phthalide四氯苯酞27355-22-20.010.010.010.010.010.01195Propyzamide炔苯酰草胺23950-58-50.010.010.010.010.010.01196Propanil敵稗709-98-80.010.010.010.010.010.01197Propiconazole丙環(huán)唑60207-90-10.010.010.010.010.010.01198Prothiofos丙硫磷34643-46-40.010.010.010.010.010.01序號英文名稱中文名稱CAS號定量限，mg/kg豬肉牛肉羊肉肝臟牛奶雞蛋199Pyrazophos吡菌磷13457-18-60.010.010.010.010.010.01200Pyridaben噠螨靈96489-71-30.010.010.010.010.010.01201Pyriminobac-methyl嘧草醚147411-69-60.010.010.010.010.010.01202Fenchlorphos皮蠅磷299-84-30.010.010.010.010.010.01203Sulfotep治螟磷3689-24-50.010.010.010.010.010.01204Tebuco