金屬有機(jī)骨架材料及其在催化反應(yīng)中的應(yīng)用

金屬有機(jī)骨架材料及其在催化反應(yīng)中的應(yīng)用一、本文概述Overviewofthisarticle金屬有機(jī)骨架材料（Metal-OrganicFrameworks，簡(jiǎn)稱MOFs）是一類由金屬離子或金屬團(tuán)簇與有機(jī)配體通過(guò)配位鍵合形成的多孔晶體材料。自20世紀(jì)90年代首次報(bào)道以來(lái)，MOFs因其高度可調(diào)的孔徑、大的比表面積、豐富的活性位點(diǎn)和可設(shè)計(jì)性等優(yōu)點(diǎn)，在氣體儲(chǔ)存與分離、傳感器、藥物遞送和催化反應(yīng)等眾多領(lǐng)域展現(xiàn)出巨大的應(yīng)用潛力。特別是，在催化反應(yīng)中，MOFs可以作為均相催化劑的載體，也可以通過(guò)功能化修飾直接作為非均相催化劑，表現(xiàn)出優(yōu)異的催化活性和選擇性。Metalorganicframeworks(MOFs)areatypeofporouscrystallinematerialsformedbycoordinationbondingbetweenmetalionsormetalclustersandorganicligands.Sinceitsfirstreportinthe1990s,MOFshaveshowngreatpotentialforapplicationsinmanyfieldssuchasgasstorageandseparation,sensors,drugdelivery,andcatalyticreactionsduetotheirhighlyadjustableporesize,largespecificsurfacearea,richactivesites,anddesignability.Especiallyincatalyticreactions,MOFscanserveascarriersforhomogeneouscatalystsordirectlyasheterogeneouscatalyststhroughfunctionalmodifications,exhibitingexcellentcatalyticactivityandselectivity.本文旨在全面綜述金屬有機(jī)骨架材料的合成方法、結(jié)構(gòu)特點(diǎn)及其在催化反應(yīng)中的應(yīng)用。我們將介紹MOFs的合成策略，包括溶劑熱法、微波輔助法、機(jī)械化學(xué)法等，并探討這些合成方法對(duì)MOFs結(jié)構(gòu)和性能的影響。隨后，我們將重點(diǎn)關(guān)注MOFs在催化反應(yīng)中的應(yīng)用，包括有機(jī)催化、無(wú)機(jī)催化以及電催化等領(lǐng)域，并詳細(xì)分析MOFs作為催化劑或催化劑載體在反應(yīng)中的性能表現(xiàn)。我們還將討論MOFs催化反應(yīng)中的活性位點(diǎn)、反應(yīng)機(jī)理以及影響因素等問(wèn)題。我們將展望MOFs在催化領(lǐng)域未來(lái)的發(fā)展方向，以期為其在實(shí)際應(yīng)用中的進(jìn)一步推廣提供理論支持和實(shí)踐指導(dǎo)。Thisarticleaimstocomprehensivelyreviewthesynthesismethods,structuralcharacteristics,andapplicationsincatalyticreactionsofmetalorganicframeworkmaterials.WewillintroducethesynthesisstrategiesofMOFs,includingsolventthermalmethod,microwaveassistedmethod,mechanochemicalmethod,etc.,andexploretheimpactofthesesynthesismethodsonthestructureandpropertiesofMOFs.Subsequently,wewillfocusontheapplicationofMOFsincatalyticreactions,includingorganiccatalysis,inorganiccatalysis,andelectrocatalysis,andanalyzeindetailtheperformanceofMOFsascatalystsorcatalystcarriersinthereaction.Wewillalsodiscusstheactivesites,reactionmechanisms,andinfluencingfactorsinMOFscatalyticreactions.WewilllookforwardtothefuturedevelopmentdirectionofMOFsinthefieldofcatalysis,inordertoprovidetheoreticalsupportandpracticalguidancefortheirfurtherpromotioninpracticalapplications.二、金屬有機(jī)骨架材料的結(jié)構(gòu)與特性TheStructureandCharacteristicsofMetalOrganicSkeletonMaterials金屬有機(jī)骨架材料（MOFs）是一類由金屬離子或金屬簇與有機(jī)配體通過(guò)配位鍵連接形成的多孔晶體材料。其結(jié)構(gòu)豐富多樣，可以通過(guò)選擇不同的金屬節(jié)點(diǎn)和有機(jī)配體，以及調(diào)整合成條件來(lái)定制其結(jié)構(gòu)和性質(zhì)。MOFs的孔徑大小、形狀和表面性質(zhì)都可以通過(guò)精確的設(shè)計(jì)和控制來(lái)實(shí)現(xiàn)，這使得MOFs在催化領(lǐng)域具有巨大的應(yīng)用潛力。Metalorganicframeworkmaterials(MOFs)areatypeofporouscrystallinematerialsformedbycoordinatingmetalionsormetalclusterswithorganicligands.Itsstructureisrichanddiverse,anditsstructureandpropertiescanbecustomizedbyselectingdifferentmetalnodesandorganicligands,aswellasadjustingsynthesisconditions.Theporesize,shape,andsurfacepropertiesofMOFscanbeachievedthroughprecisedesignandcontrol,whichmakesMOFshaveenormouspotentialforapplicationinthefieldofcatalysis.MOFs的孔徑通常在納米尺度范圍內(nèi)，這為反應(yīng)物提供了足夠的空間，使得催化反應(yīng)可以在MOFs的孔道中進(jìn)行。MOFs的孔徑大小和形狀可以通過(guò)選擇不同的有機(jī)配體來(lái)精確調(diào)控，從而實(shí)現(xiàn)對(duì)特定反應(yīng)物分子的選擇性吸附和催化。TheporesizeofMOFsisusuallywithinthenanoscalerange,whichprovidessufficientspaceforreactantstoundergocatalyticreactionswithintheporesofMOFs.TheporesizeandshapeofMOFscanbepreciselycontrolledbyselectingdifferentorganicligands,therebyachievingselectiveadsorptionandcatalysisofspecificreactantmolecules.MOFs的另一個(gè)重要特性是其高度可調(diào)的表面性質(zhì)。通過(guò)引入不同的官能團(tuán)或配體，可以實(shí)現(xiàn)對(duì)MOFs表面的修飾，從而改變其對(duì)反應(yīng)物分子的吸附和催化性能。這種高度的可調(diào)性使得MOFs在催化反應(yīng)中具有廣泛的應(yīng)用范圍，可以催化多種類型的反應(yīng)，如氧化、還原、酸堿催化等。AnotherimportantcharacteristicofMOFsistheirhighlyadjustablesurfaceproperties.Byintroducingdifferentfunctionalgroupsorligands,surfacemodificationofMOFscanbeachieved,therebychangingtheiradsorptionandcatalyticperformancetowardsreactantmolecules.ThishighdegreeofadjustabilitymakesMOFswidelyapplicableincatalyticreactions,capableofcatalyzingvarioustypesofreactions,suchasoxidation,reduction,acid-basecatalysis,etc.MOFs還具有良好的熱穩(wěn)定性和化學(xué)穩(wěn)定性，這使得它們可以在高溫、高壓或強(qiáng)酸強(qiáng)堿等極端條件下進(jìn)行催化反應(yīng)。而且，MOFs的骨架結(jié)構(gòu)還可以通過(guò)后合成修飾（PSM）等方法進(jìn)行進(jìn)一步的優(yōu)化和改進(jìn)，從而進(jìn)一步提高其催化性能。MOFsalsohavegoodthermalandchemicalstability,whichallowsthemtocatalyzereactionsunderextremeconditionssuchashightemperature,highpressure,orstrongacidandalkali.Moreover,theskeletonstructureofMOFscanbefurtheroptimizedandimprovedthroughmethodssuchaspostsynthesismodification(PSM),therebyfurtherenhancingtheircatalyticperformance.MOFs的獨(dú)特結(jié)構(gòu)和可調(diào)性質(zhì)使其在催化反應(yīng)中具有廣泛的應(yīng)用前景。通過(guò)精確的設(shè)計(jì)和合成，可以制備出具有特定結(jié)構(gòu)和性質(zhì)的MOFs，以滿足不同催化反應(yīng)的需求。隨著對(duì)MOFs研究的深入，相信其在催化領(lǐng)域的應(yīng)用將會(huì)越來(lái)越廣泛。TheuniquestructureandtunablepropertiesofMOFsmakethemwidelyapplicableincatalyticreactions.Byprecisedesignandsynthesis,MOFswithspecificstructuresandpropertiescanbepreparedtomeettheneedsofdifferentcatalyticreactions.WiththedeepeningofresearchonMOFs,itisbelievedthattheirapplicationsinthefieldofcatalysiswillbecomeincreasinglywidespread.三、金屬有機(jī)骨架材料在催化反應(yīng)中的應(yīng)用ApplicationofMetalOrganicSkeletonMaterialsinCatalyticReactions金屬有機(jī)骨架材料（MOFs）因其獨(dú)特的結(jié)構(gòu)和性質(zhì)，在催化反應(yīng)中表現(xiàn)出極高的應(yīng)用潛力。這些材料的多孔性、高比表面積以及可調(diào)諧的功能性，使它們成為設(shè)計(jì)高效催化劑的理想選擇。Metalorganicframeworkmaterials(MOFs)haveshownhighpotentialforapplicationincatalyticreactionsduetotheiruniquestructureandproperties.Theporosity,highspecificsurfacearea,andtunablefunctionalityofthesematerialsmakethemidealchoicesfordesigningefficientcatalysts.MOFs的催化應(yīng)用主要集中在有機(jī)合成、能源轉(zhuǎn)換和儲(chǔ)存等領(lǐng)域。在有機(jī)合成中，MOFs可以作為均相或非均相催化劑，用于各種有機(jī)反應(yīng)，如酯化、氧化、還原和碳碳偶聯(lián)等。例如，某些MOFs中的金屬中心可以直接參與催化反應(yīng)，而有機(jī)配體則可以提供反應(yīng)所需的活性位點(diǎn)。MOFs的多孔性使得反應(yīng)物能夠更容易地接觸到催化活性位點(diǎn)，從而提高了催化效率。ThecatalyticapplicationsofMOFsaremainlyconcentratedinthefieldsoforganicsynthesis,energyconversion,andstorage.Inorganicsynthesis,MOFscanserveashomogeneousorheterogeneouscatalystsforvariousorganicreactions,suchasesterification,oxidation,reduction,andcarboncarboncoupling.Forexample,metalcentersincertainMOFscandirectlyparticipateincatalyticreactions,whileorganicligandscanprovidetherequiredactivesitesforthereaction.TheporousnatureofMOFsallowsreactantstomoreeasilycontactcatalyticactivesites,therebyimprovingcatalyticefficiency.在能源轉(zhuǎn)換和儲(chǔ)存方面，MOFs也展現(xiàn)出廣闊的應(yīng)用前景。例如，一些MOFs具有優(yōu)異的電化學(xué)性質(zhì)，可以作為電催化劑用于電解水、燃料電池等反應(yīng)。MOFs還可以用于儲(chǔ)存氫氣、甲烷等能源氣體，其高比表面積和多孔性使得這些氣體能夠在MOFs中高效儲(chǔ)存和釋放。MOFsalsoshowbroadapplicationprospectsinenergyconversionandstorage.Forexample,someMOFshaveexcellentelectrochemicalpropertiesandcanbeusedaselectrocatalystsforreactionssuchaswaterelectrolysisandfuelcells.MOFscanalsobeusedtostoreenergygasessuchashydrogenandmethane,andtheirhighspecificsurfaceareaandporosityenablethesegasestobeefficientlystoredandreleasedinMOFs.值得一提的是，MOFs的催化性能還可以通過(guò)后合成修飾（PSM）進(jìn)行進(jìn)一步優(yōu)化。通過(guò)改變配體、金屬中心或引入功能性基團(tuán)等方式，可以調(diào)控MOFs的催化活性和選擇性，使其更加適應(yīng)特定的催化反應(yīng)需求。ItisworthmentioningthatthecatalyticperformanceofMOFscanbefurtheroptimizedthroughpostsynthesismodification(PSM).Bychangingligands,metalcenters,orintroducingfunctionalgroups,thecatalyticactivityandselectivityofMOFscanberegulatedtobettermeetspecificcatalyticreactionrequirements.然而，盡管MOFs在催化反應(yīng)中展現(xiàn)出諸多優(yōu)勢(shì)，但仍存在一些挑戰(zhàn)需要克服。例如，MOFs的水穩(wěn)定性、熱穩(wěn)定性以及化學(xué)穩(wěn)定性等問(wèn)題仍需要進(jìn)一步提高。如何實(shí)現(xiàn)MOFs的大規(guī)模合成和應(yīng)用也是當(dāng)前研究的熱點(diǎn)之一。However,althoughMOFshaveshownmanyadvantagesincatalyticreactions,therearestillsomechallengesthatneedtobeovercome.Forexample,thewaterstability,thermalstability,andchemicalstabilityofMOFsstillneedtobefurtherimproved.Howtoachievelarge-scalesynthesisandapplicationofMOFsisalsooneofthecurrentresearchhotspots.金屬有機(jī)骨架材料在催化反應(yīng)中的應(yīng)用具有廣闊的前景和巨大的潛力。隨著研究的深入和技術(shù)的不斷進(jìn)步，相信MOFs將在未來(lái)的催化領(lǐng)域中發(fā)揮更加重要的作用。Theapplicationofmetalorganicframeworkmaterialsincatalyticreactionshasbroadprospectsandenormouspotential.Withthedeepeningofresearchandcontinuoustechnologicalprogress,itisbelievedthatMOFswillplayamoreimportantroleinthefuturecatalyticfield.四、金屬有機(jī)骨架材料在催化反應(yīng)中的優(yōu)勢(shì)與挑戰(zhàn)Theadvantagesandchallengesofmetalorganicframeworkmaterialsincatalyticreactions金屬有機(jī)骨架材料（MOFs）作為一種新型的多孔材料，在催化反應(yīng)中展現(xiàn)出了顯著的優(yōu)勢(shì)和廣闊的應(yīng)用前景。然而，與此MOFs也面臨著一些挑戰(zhàn)，需要科研工作者不斷深入研究與改進(jìn)。Metalorganicframeworkmaterials(MOFs),asanewtypeofporousmaterial,haveshownsignificantadvantagesandbroadapplicationprospectsincatalyticreactions.However,MOFsalsofacesomechallengesthatrequirecontinuousin-depthresearchandimprovementbyresearchers.高度可定制性：MOFs的結(jié)構(gòu)和組成可以通過(guò)選擇不同的金屬離子和有機(jī)配體進(jìn)行精確調(diào)控，從而實(shí)現(xiàn)對(duì)其孔徑、孔形以及表面性質(zhì)的定制。這種高度的可定制性使得MOFs能夠針對(duì)特定的催化反應(yīng)進(jìn)行優(yōu)化設(shè)計(jì)，提高催化效率。Highlycustomizable:ThestructureandcompositionofMOFscanbepreciselycontrolledbyselectingdifferentmetalionsandorganicligands,therebyachievingcustomizationoftheirporesize,shape,andsurfaceproperties.ThishighdegreeofcustomizationenablesMOFstobeoptimizedforspecificcatalyticreactionsandimprovecatalyticefficiency.高比表面積和多孔性：MOFs通常具有極高的比表面積和多孔性，這有利于反應(yīng)物分子的擴(kuò)散和傳質(zhì)，提高了催化反應(yīng)的速率。Highspecificsurfaceareaandporosity:MOFstypicallyhaveextremelyhighspecificsurfaceareaandporosity,whichfacilitatethediffusionandmasstransferofreactantmoleculesandimprovetherateofcatalyticreactions.活性位點(diǎn)豐富：MOFs中的金屬離子和有機(jī)配體都可以作為潛在的催化活性位點(diǎn)，使得MOFs在催化反應(yīng)中表現(xiàn)出較高的催化活性。Richactivesites:MetalionsandorganicligandsinMOFscanserveaspotentialcatalyticactivesites,makingMOFsexhibithighcatalyticactivityincatalyticreactions.良好的穩(wěn)定性：許多MOFs材料在常見(jiàn)的化學(xué)環(huán)境中表現(xiàn)出良好的穩(wěn)定性，能夠在苛刻的反應(yīng)條件下保持結(jié)構(gòu)的穩(wěn)定，從而實(shí)現(xiàn)高效催化。Goodstability:ManyMOFmaterialsexhibitgoodstabilityincommonchemicalenvironments,abletomaintainstructuralstabilityunderharshreactionconditions,therebyachievingefficientcatalysis.水熱穩(wěn)定性問(wèn)題：盡管許多MOFs材料在有機(jī)溶劑中表現(xiàn)出良好的穩(wěn)定性，但在水或高溫條件下，其結(jié)構(gòu)往往容易發(fā)生坍塌。這限制了MOFs在一些需要水或高溫環(huán)境的催化反應(yīng)中的應(yīng)用。Hydrothermalstabilityissue:AlthoughmanyMOFmaterialsexhibitgoodstabilityinorganicsolvents,theirstructuresareoftenpronetocollapseunderwaterorhightemperatureconditions.ThislimitstheapplicationofMOFsincatalyticreactionsthatrequirewaterorhightemperatureenvironments.活性位點(diǎn)利用率低：由于MOFs的孔道結(jié)構(gòu)復(fù)雜，部分活性位點(diǎn)可能難以接觸到反應(yīng)物分子，導(dǎo)致活性位點(diǎn)的利用率較低。如何提高活性位點(diǎn)的利用率是MOFs催化領(lǐng)域需要解決的一個(gè)重要問(wèn)題。Lowutilizationofactivesites:DuetothecomplexporestructureofMOFs,someactivesitesmayhavedifficultycontactingreactantmolecules,resultinginlowutilizationofactivesites.HowtoimprovetheutilizationofactivesitesisanimportantissuethatneedstobeaddressedinthefieldofMOFscatalysis.合成成本較高：目前，MOFs的合成通常需要在較為苛刻的條件下進(jìn)行，且需要使用昂貴的金屬鹽和有機(jī)配體，導(dǎo)致合成成本較高。如何降低MOFs的合成成本，實(shí)現(xiàn)其規(guī)?；瘧?yīng)用，是MOFs催化領(lǐng)域面臨的另一個(gè)挑戰(zhàn)。Highsynthesiscost:Currently,thesynthesisofMOFsusuallyrequiresharshconditionsandtheuseofexpensivemetalsaltsandorganicligands,resultinginhighsynthesiscosts.HowtoreducethesynthesiscostofMOFsandachievetheirlarge-scaleapplicationisanotherchallengefacingthefieldofMOFscatalysis.盡管面臨這些挑戰(zhàn)，但隨著科研工作的不斷深入和技術(shù)的不斷進(jìn)步，相信未來(lái)MOFs在催化反應(yīng)中的應(yīng)用將會(huì)得到更廣泛的發(fā)展。Despitefacingthesechallenges,withthecontinuousdeepeningofscientificresearchandtechnologicalprogress,itisbelievedthattheapplicationofMOFsincatalyticreactionswillbemorewidelydevelopedinthefuture.五、金屬有機(jī)骨架材料在催化反應(yīng)中的發(fā)展趨勢(shì)與展望DevelopmentTrendsandProspectsofMetalOrganicSkeletonMaterialsinCatalyticReactions隨著科學(xué)技術(shù)的不斷進(jìn)步，金屬有機(jī)骨架材料在催化反應(yīng)中的應(yīng)用也呈現(xiàn)出日益廣闊的發(fā)展前景。這些材料以其獨(dú)特的結(jié)構(gòu)和性質(zhì)，為催化領(lǐng)域帶來(lái)了新的機(jī)遇和挑戰(zhàn)。Withthecontinuousprogressofscienceandtechnology,theapplicationofmetalorganicframeworkmaterialsincatalyticreactionshasalsoshownincreasinglybroaddevelopmentprospects.Thesematerials,withtheiruniquestructuresandproperties,bringnewopportunitiesandchallengestothefieldofcatalysis.從材料設(shè)計(jì)角度來(lái)看，金屬有機(jī)骨架材料的發(fā)展將更加注重精準(zhǔn)合成和調(diào)控。通過(guò)精確控制材料的組成、結(jié)構(gòu)和形貌，可以進(jìn)一步優(yōu)化其催化性能，實(shí)現(xiàn)更高效、更環(huán)保的催化過(guò)程。利用計(jì)算化學(xué)等先進(jìn)手段進(jìn)行材料設(shè)計(jì)，可以預(yù)測(cè)和優(yōu)化材料的催化性能，為實(shí)驗(yàn)合成提供有力指導(dǎo)。Fromtheperspectiveofmaterialdesign,thedevelopmentofmetalorganicframeworkmaterialswillplacegreateremphasisonprecisesynthesisandregulation.Bypreciselycontrollingthecomposition,structure,andmorphologyofmaterials,theircatalyticperformancecanbefurtheroptimized,achievingmoreefficientandenvironmentallyfriendlycatalyticprocesses.Usingadvancedmethodssuchascomputationalchemistryformaterialdesigncanpredictandoptimizethecatalyticperformanceofmaterials,providingstrongguidanceforexperimentalsynthesis.金屬有機(jī)骨架材料在催化反應(yīng)中的應(yīng)用將不斷拓展。目前，這些材料已經(jīng)在許多重要的催化反應(yīng)中展現(xiàn)出優(yōu)異的性能，如有機(jī)合成、能源轉(zhuǎn)換和存儲(chǔ)等。未來(lái)，隨著研究的深入，金屬有機(jī)骨架材料有望在更多領(lǐng)域發(fā)揮催化作用，如生物醫(yī)學(xué)、環(huán)境保護(hù)等。Theapplicationofmetalorganicframeworkmaterialsincatalyticreactionswillcontinuetoexpand.Atpresent,thesematerialshaveshownexcellentperformanceinmanyimportantcatalyticreactions,suchasorganicsynthesis,energyconversion,andstorage.Inthefuture,withthedeepeningofresearch,metalorganicframeworkmaterialsareexpectedtoplaycatalyticrolesinmorefields,suchasbiomedicalandenvironmentalprotection.金屬有機(jī)骨架材料的循環(huán)利用和可持續(xù)發(fā)展也是未來(lái)研究的重點(diǎn)。目前，這些材料的穩(wěn)定性和壽命仍面臨一定挑戰(zhàn)，如何提高其循環(huán)使用性能、降低環(huán)境污染是亟待解決的問(wèn)題。通過(guò)改進(jìn)合成方法、優(yōu)化材料結(jié)構(gòu)以及開(kāi)發(fā)新型催化劑再生技術(shù)，有望實(shí)現(xiàn)金屬有機(jī)骨架材料的可持續(xù)利用。Therecyclingandsustainabledevelopmentofmetalorganicframeworkmaterialsarealsothefocusoffutureresearch.Atpresent,thestabilityandlifespanofthesematerialsstillfacecertainchallenges,andhowtoimprovetheirrecyclingperformanceandreduceenvironmentalpollutionisanurgentproblemtobesolved.Byimprovingsynthesismethods,optimizingmaterialstructures,anddevelopingnewcatalystregenerationtechnologies,itisexpectedtoachievesustainableutilizationofmetalorganicframeworkmaterials.金屬有機(jī)骨架材料在催化反應(yīng)中的發(fā)展趨勢(shì)與展望十分廣闊。通過(guò)不斷創(chuàng)新和深入研究，我們有信心將這些材料的應(yīng)用范圍進(jìn)一步擴(kuò)大，為催化領(lǐng)域的發(fā)展做出更大貢獻(xiàn)。也需要關(guān)注材料的環(huán)境友好性和可持續(xù)性，為實(shí)現(xiàn)綠色化學(xué)和可持續(xù)發(fā)展貢獻(xiàn)力量。Thedevelopmenttrendandprospectsofmetalorganicframeworkmaterialsincatalyticreactionsareverybroad.Throughcontinuousinnovationandin-depthresearch,weareconfidentinfurtherexpandingtheapplicationscopeofthesematerialsandmakinggreatercontributionstothedevelopmentofthecatalyticfield.Wealsoneedtopayattentiontotheenvironmentalfriendlinessandsustainabilityofmaterials,andcontributetoachievinggreenchemistryandsustainabledevelopment.六、結(jié)論Conclusion隨著科技的進(jìn)步和研究的深入，金屬有機(jī)骨架材料作為一種新型的多孔材料，已經(jīng)在催化反應(yīng)中展現(xiàn)出其獨(dú)特的優(yōu)勢(shì)和應(yīng)用前景。本文綜述了金屬有機(jī)骨架材料的合成方法、性質(zhì)特點(diǎn)以及在催化反應(yīng)中的應(yīng)用，進(jìn)一步強(qiáng)調(diào)了這種材料在催化領(lǐng)域的重要性和潛力。Withtheadvancementoftechnologyandthedeepeningofresearch,metalorganicframeworkmaterials,asanewtypeofporousmaterial,haveshowntheiruniqueadvantagesandapplicationprospectsincatalyticreactions.Thisarticlereviewsthesynthesismethods,properties,andapplicationsofmetalorganicframeworkmaterialsincatalyticreactions,furtheremphasizingtheimportanceandpotentialofthismaterialinthefieldofcatalysis.金屬有機(jī)骨架材料因其高度可調(diào)的孔徑、大的比表面積以及豐富的活性位點(diǎn)，使其在催化反應(yīng)中具備優(yōu)異的性能。通過(guò)合理的設(shè)計(jì)和合成，可以實(shí)現(xiàn)對(duì)材料孔徑、形狀和功能的精準(zhǔn)調(diào)控，從而優(yōu)化催化反應(yīng)路徑，提高反應(yīng)效率和選擇性。金屬有機(jī)骨架材料還具備良好的穩(wěn)定性和可循環(huán)性，使得其在工業(yè)生產(chǎn)中具有廣闊的應(yīng)用前景。Metalorganicframeworkmaterialsexhibitexcellentperformanceincatalyticreactionsduetotheirhighlyadjustableporesize,largespecificsurfacearea,andabundantactivesites.Throughreasonabledesignandsynthesis,precisecontrolofmaterialporesize,shape,andfunctioncanbeachieved,therebyoptimizingcatalyticreactionpathways,improvingreactionefficiencyandselectivity.Metalorganicframeworkmaterialsalsohavegoodstabilityandrecyclability,ma