美利肯透明聚丙烯課件

1、最新一代聚丙烯透明劑謝春平博士，美利肯化工內(nèi)容簡介 OutlineMillad 3988i, Millad NX8000產(chǎn)品概述 Product SummaryMillad NX8000介紹 What is Millad NX8000?Millad NX8000個例經(jīng)濟(jì)分析 Millad NX8000 Commercial Case Study總結(jié) Conclusion十多年來，Millad 3988一直是透明聚丙烯市場的百尺竿頭Millad 3988,the Industry Benchmark for Clear PolypropyleneMillad NX8000 更進(jìn)一步Millad

2、NX8000 is for the Ultimate in Clear PolypropyleneMillad NX8000 的產(chǎn)品定位position in the market Millad NX8000 是透明聚丙烯領(lǐng)域的重大突破。其所能達(dá)到的透明度增加了許多商機(jī)。Millad NX8000 gives a new clarity standard for cPP, a breakthrough in PP transparency, permitting attractive opportunities in market value growth through the develo

3、pment of new clear resins 通過取代別的透明塑料來加速聚丙烯的增長Accelerating PP growth through material replacement of clear polymers 在已存在的應(yīng)用通過提高顧客對更為透明產(chǎn)品的興趣來增長Reinvigorating and growing polypropylene in existing applications through improved consumer interest and acceptanceWhat is Millad NX8000?Millad NX8000是一全新分子結(jié)構(gòu)的

4、透明劑 Millad NX8000 is a new-to-the-world clarifier based on a new type chemistry that significantly expands the performance of PP clarification Millad NX8000使得透明聚丙烯看起來近似聚苯乙烯和聚碳酸酯因而使材料取代成為可能 Millad NX8000 allows polypropylene to approach the look and clarity of high clarity plastics like polystyrene a

5、nd polycarbonate creating material substitution opportunities 商業(yè)級樹脂在全球各地都有開發(fā) Commercial grades are in development in each region of the worldHaze Continuum for Selected Plastic MaterialsMillad NX8000 使聚丙烯更接近透明工程塑料 Millad NX8000 allows PP to close the haze gap on “water white” polymers5PMMAPETPSPCGla

6、ssClarified (NX8000) PP(RACO & HOMO)3.5-7.0Clarified PP (1G) RACO20-30Clarified (3G) PP (HOMO)15-20Clarified (3G) PP (RACO) 10-15Clarified (3G) mPP (HOMO)13-16Clarified (3G) mPP (RACO) 9-11Unclarified PP(HOMO) 50-70Unclarified PP (RACO) 40-50Unclarified HDPE 80+“Water White”Clarity (13)Evolutionary

7、Improvements in Polypropylene ClarityNote: 1.25 mm plaquesHaze, %40806020103150Millad NX8000 的價值何在？What is the Value?提高透明度 Improved clarity增寬加工窗口 Broad processing window縮短成型周期 Improved cycle timeMillad NX8000 的價值何在？What is the Value?提高透明度 Improved clarity增寬加工窗口 Broad processing window縮短成型周期 Improved

8、 cycle time透明聚丙烯在注塑產(chǎn)品的應(yīng)用Markets for Injection Molded Clear PP 新一代聚丙烯透明劑有何不同？Millad NX8000將 Millad 3988i 的霧度降低幾乎一半 Millad NX8000 gives half the haze as Millad 3988i at any thickness.Millad NX8000 把不同厚度產(chǎn)品的霧度都幾乎降低了一半 Millad NX8000 delivers significantly improved haze at all thickness in IM (50%) under

9、commercial conditions Millad NX8000 顯著地增寬了加工區(qū)間從而使得霧度在各種操作條件下都接近一致 Millad NX8000 has a significantly broadened processing window - allowing for consistently superior clarity across all polypropylene melt flows and processing conditions要點 Points to noteNote: DOEs conducted in 12 MFI RCP; Millad 3988i

10、at 2000 ppm; Millad NX8000 at 4000 ppm霧度 HazeFor the Ultimate in Clear PolypropyleneFor the Ultimate in Clear PolypropyleneMillad NX8000 的價值何在？What is the Value?提高透明度 Improved clarity增寬加工窗口 Broad processing window縮短成型周期 Improved cycle timeParameter LowHighMixingLow Intensity (L)High Intensity (H)Ext

11、rusionSingle Screw (S)Twin Screw (T)Extrusion Temp.190C (L)230C (H)IM Barrel Temp.190C (L)230C (H)IM Injection Rate2.4cc/s (L)30cc/s (H)新一代聚丙烯透明劑有何不同？ What is Next Generation Millad?Millad NX8000在各種條件下都能得到好的霧度 A broad processing window giving excellent haze under all processing conditions.Note: DOEs

12、 conducted in 12 MFI RCP; Millad NX8000 at 4000 ppmMillad NX8000 的價值何在？What is the Value?提高透明度 Improved clarity增寬加工窗口 Broad processing window縮短成型周期 Improved cycle timeMillad NX8000結(jié)晶溫度更高，成型周期更短,產(chǎn)能提高 5-10%Millad NX8000 has a higher Tc and shorter T1/2. When coupled with the broader processing window,

13、 productivity enhancements (generally 5 10%) are possible without reducing other quality requirements.Note: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmTc DataT1/2 DataMillad NX8000 的價值何在？What is the Value? 提高擠出吹塑產(chǎn)品的透明度EBM - Improved clarity拓寬擠出吹塑的加工窗口EBM - Impr

14、oved processing window透明聚丙烯在擠出注塑產(chǎn)品的應(yīng)用Markets for Extrusion Blow Molded Clear PPMillad NX8000 使擠出注塑瓶的外形大為改觀從而加寬了透明聚丙烯在擠出注塑領(lǐng)域的應(yīng)用 Millad NX8000 yields new PP aesthetics in EBM bottles permitting a broader application of cPP in EBM applications.Millad NX8000 在霧度和光澤度都有顯著提高 Millad NX8000 gives superior pe

15、rformance in haze and gloss at high loadings.Millad NX8000顯著提高擠出注塑產(chǎn)品的外觀Millad NX8000 consistently gives improved aesthetics in EBM要點 Points to noteDecreasing loadingNote: Expts conducted in 2 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm, 500 mL Shampoo bottle霧度 Haze內(nèi)部光澤度 Inside Gloss

16、硬度略有提高，抗沖擊不受影響 There is a modest improvement in stiffness without loss in impact resistance硬度在低溫操作條件下有所提高，抗沖擊不受影響 Stiffness is higher at cooler operating temperatures without the loss in impact resistanceMillad NX8000具有典型無規(guī)共聚的硬度/抗沖擊平衡Millad NX8000 has typical stiffness/impact balance for RCP. 要點 Poi

17、nts to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmFlexural ModulusGardner Impact優(yōu)異的重復(fù)加工穩(wěn)定性,宜于回收利用 Excellent multi-pass additive stability indicates regrind stabilityMillad NX8000在氧化裂解中具有優(yōu)良的穩(wěn)定性Millad NX8000 has excellent regrind and v

18、isc-breaking stability 要點 Points to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmNormal 12 MFICR to 35 MFIAttributeMillad NX8000Millad 3988iMillad NX8000，其他性質(zhì)類似Millad 3988i All other attributes are like Millad 3988i.霧度 Haze大約降低50% 50%

19、reduction in haze業(yè)界標(biāo)準(zhǔn)Industry Standard氣味 Taste & Odor基本一致 Similar業(yè)界標(biāo)準(zhǔn) Industry Standard操作溫區(qū) Processing190 250 C210 C注冊情況 Regulatory 全球許可申請中In progress全球許可 Globally approved提取物Extraction低 Low低 Low硬度Stiffness基本一致 Similar業(yè)界標(biāo)準(zhǔn) Standard抗沖擊Impact基本一致 Similar業(yè)界標(biāo)準(zhǔn) Standard發(fā)黃問題Yellowing沒問題 No issues沒問題 No is

20、suesFor the Ultimate in Clear PolypropyleneNX8000 商業(yè)化個案研究：更高的透明度在食品包裝的價值The Value of Clarity in Food Storage Containers 應(yīng)用： 食品包裝 Application: Food Storage Containers 加工：注塑 Process: Injection Molding 區(qū)域：北美 Region: North America 追求高清晰度的動力何在？ Drivers for higher clarity: (1) 增加銷售 Increase sales 市場研究表明顧客

21、希望更為透明的食品包裝 Market research demonstrates that consumers prefer higher clarity in food storage containers (2) 提高利潤率 Improve margins市場研究表明顧客愿意為更透明的食品包裝付出多一些 結(jié)果證明了這一點 Market research suggests that consumers will pay more for higher clarity in food storage containers. It has been proved by market.食品包裝盒轉(zhuǎn)

22、換:高清晰度導(dǎo)致高利潤率 Food Storage Conversion: Improve Clarity to Improve MarginsProduct LineSizeClear Base Weight (kg)Clear PP Cost / kg resinClear PP Material Cost / PartSales Price at RetailerServin Saver2.1 cups (500 mL)0.05$1.870.093$1.99Easy Find Lids2 cups (473 mL)0.05$2.170.109$2.19 成本增加了2美分 Higher c

23、larity adds less than $0.02 / part in cost (assume a $300/ton upcharge for NX8000) 零售價增加了20美分 Retail price is $0.20 / part higher for the Easy Find Lids商業(yè)應(yīng)用舉例：食品容器：高端顧客對更高透明度的追求包裝材料：取代高成本塑料如聚碳酸酯，聚氯乙烯，聚苯乙烯，共聚聚酯 (PETG)等 嬰兒奶瓶：取代聚碳酸酯 成本及內(nèi)分泌腺的安全考慮 擠吹塑料瓶：化妝品容器等For the Ultimate in Clear Polypropylene塑料類型價格

24、(美元/噸)Price USD/t密度(噸/米3)Density (t/m3)價格(美元/米3)Price USD/m3均聚聚丙烯 Homo PP$14500.91305高密度聚乙烯 HDPE$14500.941363共聚聚丙烯-NX8000 $16500.91485聚苯乙烯 Polystyrene $16001.041664聚氯乙烯 PVC - Rigid$16001.2-1.41920-2240聚碳酸酯 Polycarbonate$25001.23000Millad NX8000 材料取代的經(jīng)濟(jì)分析 Millad NX8000 Economics Inter-material substi

25、tutionSource: IDES, data for Oct 07材料取代商機(jī)Material Substitution Opportunities聚苯乙烯類 Styrenics (including SAN, SBC)CD盒，杯子，包裝等 CD cases, appliances, cups, packaging取代動力 Drivers成本，抗沖擊，持久性 Cost (copolymers), impact, sustainability聚酯 Polyesters包裝，杯子，瓶子 Packaging, cups, bottles取代動力 Drivers 成本， 手感 Cost (PETG), hand/feel聚碳酸酯 Polycarbonate嬰兒奶瓶，水瓶，家具，日常用具Infant feeding bottles, water packaging, furniture, housewares, appliances取代動力 Drivers 成本及內(nèi)分泌腺的安全考慮 Cost, BPA endocrine disru