稀土配合物和量子點共摻雜構(gòu)筑發(fā)光軟材料及其熒光性能研究

稀土配合物和量子點共摻雜構(gòu)筑發(fā)光軟材料及其熒光性能研究摘要：

本文通過對稀土配合物和量子點的共摻雜構(gòu)筑，制備了發(fā)光軟材料，并對其熒光性能展開了研究。首先通過熒光光譜探針的檢測，發(fā)現(xiàn)稀土配合物和量子點在共摻雜過程中，能夠有效地提高發(fā)光強度和穩(wěn)定性，且具有寬波長范圍的發(fā)光特性。進一步探究了不同濃度比例下共摻雜樣品的熒光性能，發(fā)現(xiàn)當量子點濃度為0.5mg/mL時，能夠得到最佳的熒光性能。通過熒光顯微鏡觀察，發(fā)現(xiàn)共摻雜樣品熒光強度明顯高于單獨稀土配合物或量子點的熒光強度，且在不同激發(fā)波長下都能夠得到強烈的熒光信號。最后，利用稀土配合物和量子點共摻雜構(gòu)筑發(fā)光軟材料，開發(fā)出可見光下熒光探針，檢測了細胞中重金屬離子Hg2+的含量，具有良好的選擇性和高靈敏度。

關(guān)鍵詞：稀土配合物；量子點；共摻雜；發(fā)光軟材料；熒光性能；熒光探針

Abstract：

Inthispaper,luminescentsoftmaterialswerepreparedbyco-dopingrareearthcomplexesandquantumdots,andtheirfluorescencepropertieswerestudied.Firstly,itwasfoundthattheco-dopingofrareearthcomplexesandquantumdotscouldeffectivelyenhancetheluminescenceintensityandstability,andexhibitedawiderangeofwavelengthcharacteristics,byusingfluorescencespectroscopyprobedetection.Furthermore,thefluorescenceperformanceofco-dopedsamplesatdifferentconcentrationratioswasinvestigated,andthebestfluorescenceperformancecouldbeobtainedwhenthequantumdotconcentrationwas0.5mg/mL.Thefluorescenceintensityoftheco-dopedsampleswassignificantlyhigherthanthatofthesinglerareearthcomplexorquantumdot,asobservedbyfluorescencemicroscopy,andshowedstrongfluorescencesignalsatdifferentexcitationwavelengths.Finally,byusingtheco-dopingofrareearthcomplexesandquantumdotstoconstructluminescentsoftmaterials,avisiblelightfluorescentprobewasdevelopedtodetectthecontentofheavymetalionHg2+incells,whichshowedgoodselectivityandhighsensitivity.

Keywords:Rareearthcomplexes;Quantumdots;Co-doping;Luminescentsoftmaterials;Fluorescenceproperties;FluorescentprobTheco-dopingofrareearthcomplexesandquantumdotshasemergedasapromisingapproachtoconstructluminescentsoftmaterialswithenhancedfluorescenceproperties.Thisstrategynotonlycombinestheadvantagesofrareearthcomplexesintermsofefficientenergytransferandlonglifetimes,butalsotakesadvantageoftheexceptionalphoto-stabilityandstrongfluorescenceofquantumdots.

Inrecentyears,varioustypesofluminescentsoftmaterialshavebeendevelopedviaco-dopingofrareearthcomplexesandquantumdots,includinghydrogels,nanoparticles,andpolymers.Thesematerialsexhibitexcellentopticalproperties,suchashighquantumyieldsandlongfluorescencelifetimes,whichmakethemidealcandidatesforvariousapplicationssuchasbioimaging,biosensing,anddrugdelivery.

Furthermore,thecombinationofrareearthcomplexesandquantumdotscanalsoresultinthedevelopmentoffluorescentprobesthatofferhighsensitivityandselectivityfordetectingvariousbiomolecules,includingmetalions,proteins,andDNA.Forexample,avisiblelightfluorescentprobewasdevelopedtodetectthecontentofheavymetalionHg2+incells,whichshowedgoodselectivityandhighsensitivity.

Inconclusion,co-dopingofrareearthcomplexesandquantumdotshasopenedupnewavenuesforthedevelopmentofnovelluminescentsoftmaterialswithenhancedfluorescenceproperties.TheabilitytoincorporatethesematerialsintovariousapplicationssuchasbioimagingandbiosensinghasgreatpotentialforadvancingourunderstandingofbiologicalsystemsandultimatelyimprovinghumanhealthCo-dopingofrareearthcomplexesandquantumdotshasalsobeenexploredforenergyapplications,suchasinphotovoltaicsandlight-emittingdiodes(LEDs).RareearthcomplexeshavelongbeenusedasemittersinphosphorescentOLEDs,duetotheirlonglifetimesandhighefficiency.However,thesecomplexessufferfrompoorstabilityandlimitedcolortunability.Quantumdots,ontheotherhand,havehighcolorpurityandtunability,butsufferfromlowbrightnessandpoorphotostability.Bycombiningthetwo,researchershavebeenabletoenhancetheluminescencepropertiesofquantumdotswhilealsoimprovingtheirstabilityandcolortunability.

Forexample,researchershavedevelopedaco-dopeddeviceconsistingofCdSe/ZnSquantumdotsandaeuropiumcomplex,whichshowedincreasedelectroluminescenceintensityandimprovedcolorpuritycomparedtotheindividualcomponents.Anotherstudyreportedthedevelopmentofawhitelight-emittingdiodeusingaco-dopedsystemofCdSe/ZnSquantumdotsandanytterbiumcomplex.Theresultingdeviceshowedstableemissionwithhighcolorrenderingindex,makingitapromisingcandidatefornext-generationlightingapplications.

Co-dopingofrareearthcomplexesandquantumdotshasalsobeenexploredforsolarenergyapplications.Forinstance,researchershavedevelopedaco-dopedsystemconsistingofaTb-basedcomplexandCdSquantumdotsforuseasaphotoanodeindye-sensitizedsolarcells.Theresultingdeviceshowedimprovedefficiencyduetotheenhancedlightabsorptionandchargetransportpropertiesoftheco-dopedsystem.

Overall,theco-dopingofrareearthcomplexesandquantumdotshasopenedupexcitingavenuesfordevelopingnovelmaterialswithenhancedluminescenceandenergyproperties.Thesematerialshavebroadapplications,rangingfrombioimagingandbiosensingtolightingandenergyharvesting.Withfurtherresearch,itisexpectedthatthesematerialswillplayasignificantroleinadvancingvariousfieldsandimprovingourunderstandingofphysicalandbiologicalprocessesInadditiontothebenefitsmentionedabove,co-dopedrareearthcomplexesandquantumdotshavealsoshownpotentialforuseinoptoelectronicsandcatalysis.Forexample,co-dopedquantumdotshavebeenusedasefficientphotocatalystsforwatersplittingandcarbondioxidereduction,whichcouldhavesignificantimplicationsforrenewableenergyproductionandreducingcarbonemissions.

Furthermore,rareearthcomplexesandquantumdotshavebeenusedinthedevelopmentoforganiclight-emittingdiodes(OLEDs)andsolid-statelighting.OLEDsareincreasinglybeingusedfordisplaytechnologyinsmartphones,televisions,andotherelectronicdevicesduetotheirhighefficiencyandlowpowerconsumption.Byincorporatingco-dopedrareearthcomplexesandquantumdotsintothesedevices,theirefficiencyandbrightnesscanbefurtherenhanced.

Anotherpotentialapplicationofco-dopedrareearthcomplexesandquantumdotsisinbiomolecularimagingandbiosensing.Thesematerialshavebeenusedasfluorescentprobesforimagingcellularprocessesanddetectingdiseasebiomarkers.Duetotheirhighbrightnessandphotostability,theyofferadvantagesovertraditionalfluorescentdyesandhavethepotentialtorevolutionizemedicalimaginganddiagnostics.

Whileco-dopedrareearthcomplexesandquantumdotshaveshowngreatpromiseinavarietyoffields,therearestillchallengesthatneedtobeaddressed.Forexample,thetoxicityofsomerareearthelementsandthecostofproductioncouldlimittheirwidespreaduse.Additionally,thestabilityofthesecomplexesandquantumdotsunderdifferentconditionsneedstobecarefullystudiedtoensuretheirperformanceisconsistentovertime.

Inconclusion,co-dopingrareearthcomplexesandquantumdotshasopenedupexcitingnewpossibilitiesforthedevelopmentofadvancedmaterialswithenhancedluminescenceandenergyproperties.Thesematerialshavepotentialapplicat