聯(lián)合國關(guān)于GHS版本化學(xué)品(含危險品)的標(biāo)簽和分類說明

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GE.06-

UNITED

STSTE

NATIONS

Secretariat

Distr.

GENERAL

ST/SG/AC.10/C.4/2006/8/Add.1

15May2006

ENGLISH

Original:ENGLISHANDFRENCH

COMMITTEEOFEXPERTSONTHETRANSPORTOF

DANGEROUSGOODSANDONTHEGLOBALLY

HARMONIZEDSYSTEMOFCLASSIFICATION

ANDLABELLINGOFCHEMICALS

Sub-CommitteeofExpertsontheGlobally

HarmonizedSystemofClassification

andLabellingofChemicals

Eleventhsession,12-14July2006

Item3(c)oftheprovisionalagenda

HAZARDCOMMUNICATIONISSUES

Codificationofhazardandprecautionarystatements

TransmittedbytherepresentativefromtheEuropeanChemicalIndustryCouncil(CEFIC)

onbehalfoftheprecautionarystatementscorrespondenceworkinggroup

Addendum1

ProposalfortherevisionofAnnex3oftheGHS.

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Annex3

SECTION1

CODIFICATIONOFHAZARDSTATEMENTS

A3.1.1 Introduction

A3.1.1.1 Hazardstatementmeansastatementassignedtoahazardclassandcategorythatdescribesthenatureofthehazardsofahazardousproduct,including,whereappropriate,thedegreeofhazard.

A3.1.1.2 ThissectioncontainsthecodesassignedtoeachofthehazardstatementsapplicabletothehazardcategoriesdefinedundertheGHS.

A3.1.1.3 ThehazardstatementcodesshallonlybeusedforreferencepurposesandshallneitherformpartofthehazardstatementtextthatappearsonaGHSlabel,norreplaceit.

A3.1.2 Codificationofhazardstatements

A3.1.2.1 Hazardstatementsareassignedauniquealphanumericalcodewhichconsistsofoneletterandthreenumbers,asfollows:

(a) theletter“H”(for“hazardstatement”);

(b) anumberdesignatingthetypeofhazardtowhichthehazardstatementisassignedaccordingtothenumberingofthedifferentpartsoftheGHS,asfollows:

“2”forphysicalhazards;

“3”forhealthhazards:

“4”forenvironmentalhazards;

(c) twonumberscorrespondingtothesequentialnumberingofhazardsarisingfromtheintrinsicpropertiesofthesubstanceormixture,suchasexplosivity(codesfrom200to210),flammability(codesfrom220to230),etc.

A3.1.2.2 Thecodestobeusedfordesignatinghazardstatementsarelisted,innumericalorder,inTableA3.1.1forphysicalhazards,TableA3.1.2forhealthhazardsandTableA3.1.3forenvironmentalhazards.Eachtableisdividedinto4columnscontainingthefollowinginformation:

Column(1) Thehazardstatementcode;

Column(2) Thehazardstatementtext;

Thetextinboldisthetextthatshallappearonthelabel,exceptotherwisespecified.Thetextinitalicsenclosedwithinbracketsprovidesextrainformationthatcanbespecified.Insuchcases,themanufacturerorsuppliercanchoose,orthecompetentauthoritiesmayprescribetheinformation.

Forexample:“causesdamagestoorgans(orstateallorgansaffected,ifknown)throughprolongedorrepeatedexposure(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)”.

Column(3) Hazardclass,withareferencetothechapteroftheGHSwhereinformationaboutthehazardclassmaybefound.

Column(4) Thehazardcategoryorcategorieswithinahazardclassforwhichtheuseofahazardstatementisapplicable.

TableA3.1.1 Hazardstatementcodesforphysicalhazards

Code

Physicalhazard

statements

Hazardclass(GHSchapter)

Hazard

category

(1)

(2)

(3)

(4)

H201

Unstableexplosive

Explosives(chapter2.1)

UnstableExplosive

H202

Explosive;massexplosionhazard

Explosives(chapter2.1)

Division1.1

H203

Explosive;severeprojectionhazard

Explosives(chapter2.1)

Division1.2

H204

Explosive;fire,blastorprojectionhazard

Explosives(chapter2.1)

Division1.3

H205

Fireorprojectionhazard

Explosives(chapter2.1)

Division1.4

H206

Maymassexplodeinfire

Explosives(chapter2.1)

Division1.5

H220

Extremelyflammablegas

Flammablegases(chapter2.2)

1

H221

Flammablegas

Flammablegases(chapter

2.2)

2

H222

Extremelyflammableaerosol

Flammableaerosols(chapter2.3)

1

H223

Flammableaerosol

Flammableaerosolschapter2.3)

2

H224

Extremelyflammableliquidandvapour

Flammableliquids(chapter

2.6)

1

H225

Highlyflammableliquidandvapour

Flammableliquids(chapter

2.6)

2

H226

Flammableliquidandvapour

Flammableliquids(chapter

2.6)

3

H227

Combustibleliquid

Flammableliquids(chapter

2.6)

4

H228

Flammablesolid

Flammablesolids(chapter

2.7)

1,2

H240

Heatingmaycauseanexplosion

Self-reactivesubstancesandmixtures(chapter2.8);andOrganicperoxides(chapter

2.15)

TypeA

H241

Heatingmaycauseafireorexplosion

Self-reactivesubstancesandmixtures(chapter2.8);andOrganicperoxides(chapter

2.15)

TypeB

H242

Heatingmaycauseafire

Self-reactivesubstancesandmixtures(chapter2.8);and

Organicperoxides(chapter

2.15)

Types

C,D,E,F

H250

Catchesfirespontaneouslyifexposedtoair

Pyrophoricliquids(chapter2.9);PyrophoricSolids(chapter2.10)

1

H251

Self-heating;maycatchfire

Self-heatingsubstancesandmixtures(chapter2.11)

1

H252

Self-heatinginlargequantities;maycatchfire

Self-heatingsubstancesandmixtures(chapter2.11)

2

H260

Incontactwithwaterreleasesflammablegaseswhichmayignitespontaneously

Substancesandmixtureswhich,incontactwithwater,emitflammablegases

(chapter2.12)

1

H261

Incontactwithwaterreleasesflammablegas

Substancesandmixtureswhich,incontactwithwater,emitflammablegases

(chapter2.12)

2,3

H270

Maycauseorintensifyfire;oxidizer

Oxidizinggases(chapter

2.4)

1

H271

Maycausefireorexplosion;strongoxidizer

Oxidizingliquids(chapter2.13);Oxidizingsolids(chapter2.14)

1

H272

Mayintensifyfire;oxidizer

Oxidizingliquids(chapter2.13);Oxidizingsolids(chapter2.14)

2,3

H280

Containsgasunderpressure;mayexplodeifheated

Gasesunderpressure(chapter2.5)

Compressedgas

Liquefiedgas

Dissolvedgas

H281

Containsrefrigeratedgas;maycausecryogenicburnsorinjury

Gasesunderpressure(chapter2.5)

Refrigeratedliquefiedgas

H290

Maybecorrosivetometals

Corrosivetometals(Chapter2.16)

1

TableA3.1.2 Hazardstatementcodesforhealthhazards

Code

(1)

Healthhazardstatements

(2)

Hazardclass(GHSchapter)

(3)

Hazardcategory

(4)

H301

Fatalifswallowed

Acutetoxicity–oral(chapter3.1)

1,2

H302

Toxicifswallowed

Acutetoxicity–oral(chapter3.1)

3

H303

Harmfulifswallowed

Acutetoxicity–oral(chapter3.1)

4

H304

Maybeharmfulifswallowed

Acutetoxicity–oral(chapter3.1)

5

H305

Maybefatalifswallowedandentersairways

Aspirationhazard(chapter3.10)

1

H306

Maybeharmfulifswallowedandentersairways

Aspirationhazard(chapter3.10)

2

H310

Fatalincontactwithskin

Acutetoxicity–dermal

(chapter3.1)

1,2

H311

Toxicincontactwithskin

Acutetoxicity–dermal

(chapter3.1)

3

H312

Harmfulincontactwithskin

Acutetoxicity–dermal

(chapter3.1)

4

H313

Maybeharmfulincontactwithskin

Acutetoxicity–dermal

(chapter3.1)

5

H314

Causessevereskinburnsandeyedamage

Skincorrosion/irritation

(chapter3.2)

1A,1B,1C

H315

Causesskinirritation

Skincorrosion/irritation

(chapter3.2)

2

H316

Causesmildskinirritation

Skincorrosion/irritation

(chapter3.2)

3

H317

Maycauseanallergicskinreaction

Sensitisation–skin(chapter3.4)

1

H318

Causesseriouseyedamage

Seriouseyedamage/eyeirritation

(chapter3.3)

1

H319

Causesseriouseyeirritation

Seriouseyedamage/eyeirritation

(chapter3.3)

2A

H320

Causeseyeirritation

Seriouseyedamage/eyeirritation

(chapter3.3)

2B

H330

Fatalifinhaled

Acutetoxicity–inhalation

(chapter3.1)

1,2

H331

Toxicifinhaled

Acutetoxicity–inhalation

(chapter3.1)

3

H332

Harmfulifinhaled

Acutetoxicity–inhalation

(chapter3.1)

4

H333

Maybeharmfulifinhaled

Acutetoxicity–inhalation

(chapter3.1)

5

H334

Maycauseallergyorasthmasymptomsorbreathingdifficultiesifinhaled

Sensitisation–respiratory

(chapter3.4)

1

H335

Maycauserespiratoryirritation

Specifictargetorgansystemictoxicity–singleexposure;Respiratorytractirritation

(chapter3.8);

3

H336

Maycausedrowsinessordizziness

Specifictargetorgansystemictoxicity–singleexposure;Narcosis(chapter3.8)

3

H350

Maycausegeneticdefects(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Germcellmutagenicity

(chapter3.5)

1A,1B

H351

Suspectedofcausinggeneticdefects(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Germcellmutagenicity

(chapter3.5)

2

H352

Maycausecancer(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Carcinogenicity(chapter3.6)

1A,1B

H353

Suspectedofcausingcancer(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Carcinogenicity(chapter3.6)

2

H354

Maydamagefertilityortheunbornchild(statespecificeffectifknown(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Reproductivetoxicity(chapter3.7)

1A,1B

H355

Suspectedofdamagingfertilityortheunbornchild(statespecificeffectifknown)(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Reproductivetoxicity(chapter3.7)

2

H356

Maycauseharmtobreast-fedchildren

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

H360

Causesdamagetoorgans(orstateallorgansaffected,ifknown)(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Specifictargetorgansystemictoxicity–singleexposure(chapter

3.8)

1

H361

Maycausedamagetoorgans(orstateallorgansaffected,ifknown)(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Specifictargetorgansystemictoxicity–singleexposure

(chapter3.8)

2

H362

Causesdamagetoorgans(orstateallorgansaffected,ifknown)throughprolongedorrepeatedexposure(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Specifictargetorgansystemictoxicity–repeatedexposure

(chapter3.9)

1

H363

Maycausedamagetoorgans(orstateallorgansaffected,ifknown)throughprolongedorrepeatedexposure(staterouteofexposureifitisconclusivelyproventhatnootherroutesofexposurecausethehazard)

Specifictargetorgansystemictoxicity–repeatedexposure

(chapter3.9)

2

TableA3.1.3 Hazardstatementcodesforenvironmentalhazards

Code

(1)

Environmentalhazardstatements

(2)

Hazardclass(GHSchapter)

(3)

Hazardcategory

(4)

H401

Verytoxictoaquaticlife

Hazardoustotheaquaticenvironment–acutetoxicity

(chapter4.1)

1

H402

Toxictoaquaticlife

Hazardoustotheaquaticenvironment–acutetoxicity

(chapter4.1)

2

H403

Harmfultoaquaticlife

Hazardoustotheaquaticenvironment–acutetoxicity

(chapter4.1)

3

H410

Verytoxictoaquaticlifewithlonglastingeffects

Hazardoustotheaquaticenvironment–chronictoxicity

(chapter4.1)

1

H411

Toxictoaquaticlifewithlonglastingeffects

Hazardoustotheaquaticenvironment–chronictoxicity

(chapter4.1)

2

H412

Harmfultoaquaticlifewithlonglastingeffects

Hazardoustotheaquaticenvironment–chronictoxicity

(chapter4.1)

3

H413

Maycauselonglastingharmfuleffectstoaquaticlife

Hazardoustotheaquaticenvironment–chronictoxicity

(chapter4.1)

4

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Annex3

SECTION2

CODIFICATIONOFPRECAUTIONARYSTATEMENTS

A3.2.1 Introduction

A3.2.1.1 APrecautionarystatementisaphrase(and/orpictogram)whichdescribesrecommendedmeasuresthatshouldbetakentominimizeorpreventadverseeffectsresultingfromexposurestoahazardousproduct,orimproperstorageorhandlingofahazardousproduct(see1.4.10.5.2

(c)).

A3.2.1.2 ForthepurposesoftheGHS,therearefivetypesofprecautionarystatements:general,prevention,response(incaseofaccidentalspillageorexposure,emergencyresponseandfirst-aid),storageanddisposal.ForguidanceontheuseofGHSprecautionarystatements,includingadviceontheselectionoftheappropriatestatementsforeachGHShazardclassandcategory,seesection3tothisannex.

A3.2.1.3 ThissectioncontainsthecodesassignedtoeachoftheprecautionarystatementtypesdescribedintheGHS.

A3.2.2 Codificationofprecautionarystatements

A3.2.2.1 Precautionarystatementsareassignedauniquealphanumericalcodewhichconsistsofoneletterandthreenumbersasfollows:

(a) aletter“P”(for“precautionarystatement”)

(b) onenumberdesignatingthetypeofprecautionarystatementasfollows:

– “1”forgeneralprecautionarystatements;

– “2”forpreventionprecautionarystatements;

– “3”forresponseprecautionarystatements;

– “4”forstorageprecautionarystatements;

– “5”fordisposalprecautionarystatements;

(c) twonumbers(correspondingtothesequentialnumberingofprecautionarystatements)

A3.2.2.2 TheprecautionarystatementcodesshallonlybeusedforreferencepurposesandshallneitherformpartoftheprecautionarystatementtextthatappearsonaGHSlabel,norreplaceit.

A3.2.2.3 Thecodestobeusedfordesignatingprecautionarystatementsarelisted,innumericalorder,inTableA3.2.1forgeneralprecautionarystatements,TableA3.2.2forpreventionprecautionarystatements,TableA3.2.3forresponseprecautionarystatements,TableA3.2.4forstorageprecautionarystatementsandTableA3.2.5fordisposalprecautionarystatements.

A3.2.3 Structureoftheprecautionarystatementtables

A3.2.3.1 Eachtableisdividedinto5columnscontainingthefollowinginformation:

Column(1) Theprecautionarystatementcode;

Column(2) Theprecautionarystatementtext;

Column(3) Thehazardclassandtherouteofexposure,whererelevant,forwhichtheuseofaprecautionarystatementisrecommendedtogetherwithareferencetothechapteroftheGHSwhereinformationaboutthehazardclassmaybefound.

Column(4) Thehazardcategoryorcategorieswithinahazardclassforwhichtheuseofaprecautionarystatementisapplicable.

Column(5) Whereapplicable,conditionsrelatingtotheuseofaprecautionarystatement;

A3.2.3.2 Thetablesshowthecorepartoftheprecautionarystatementsinboldprintincolumn

(2).Thisisthetext,exceptasotherwisespecified,thatshouldappearonthelabel.Derogationsfromtherecommendedlabellingstatementsareatthediscretionofcompetentauthorities.

A3.2.3.3 Whenabackslashordiagonalmark[/]appearsinaprecautionarystatementtextincolumn(2),itindicatesthatachoicehastobemadebetweenthephrasestheyseparate.ForexampleinP280“Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection".Insuchcases,themanufacturerorsuppliercanchoose,orthecompetentauthoritiesmayprescribethemostappropriatephrase(s).

A3.2.3.4 Whenthreefullstops[…]appearsinaprecautionarystatementtextincolumn(2),theyindicatethatallapplicableconditionsarenotlisted.ForexampleinP241“Useexplosion-proofelectrical/ventilating/lighting/.../equipment”,theuseof“...”indicatesthatotherequipmentmayneedtobespecified.Furtherdetailsoftheinformationtobeprovidedmaybefoundincolumn(5).Insuchcasesthemanufacturerorsuppliercanchoose,orthecompetentauthoritiesmayprescribetheotherconditionstobespecified.

A3.2.3.5 Incaseswhereadditionalinformationisrequiredorinformationhastobespecified,thisisindicatedbyarelevantentryincolumn(5)inplaintext.

A3.2.3.6 Whentextinitalicsisusedincolumn(5),thisindicatesspecificconditionsapplyingtotheuseorallocationoftheprecautionarystatement.Thismaybeconditionsattachingtoeitherthegeneraluseofaprecautionarystatementoritsuseforaparticularhazardclassand/orhazardcategory.Forexample,forP241“Useexplosion-proofelectrical/ventilating/lighting/.../equipment”,onlyappliesforflammablesolids“ifdustcloudscanoccur”.

A3.2.3.7 Tofacilitatetranslationintothelanguagesofusers,precautionarystatementshavebeenbrokendownintoindividualsentencesinthetablesinthissection.InanumberofinstancesthetextthatappearsonaGHSlabelrequiresthatthesebeaddedbacktogether.Thisisindicatedinthisannexbycodesconjoinedwithaplussign“+”.ForexampleP305+P351+P338indicatesthatthetexttoappearonthelabelis“IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing”.Theseadditiveprecautionarystatementscanalsobefoundattheendofeachoftheprecautionarystatementtablesinthissection.Translationofonlythesingleprecautionarystatementsisrequired,asthiswillenablethecompilationoftheadditiveprecautionarystatements.

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TableA3.2.1 Codificationofgeneralprecautionarystatements

Code

Generalprecautionarystatements

Hazardclass

Hazardcategory

Conditionsforuse

(1)

(2)

(3)

(4)

(5)

P101

Ifmedicaladviceisneeded,haveproductcontainerorlabelathand.

Consumerproducts

P102

Keepoutofreachofchildren.

Consumerproducts

P103

Readlabelbeforeuse.

Consumerproducts

TableA3.2.2 Codificationofpreventionprecautionarystatements

Code

Preventionprecautionarystatements

Hazardclass

Hazardcategory

Conditionsforuse

(1)

(2)

(3)

(4)

(5)

P201

Obtainspecialinstructionsbeforeuse.

Explosives(chapter2.1)

Unstableexplosive

Germcellmutagenicity(chapter3.5)

1A,1B,2

Carcinogenicity(chapter3.6)

1A,1B,2

Reproductivetoxicity(chapter3.7)

1A,1B,2

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

P202

Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.

Explosives(chapter2.1)

Unstableexplosive

Germcellmutagenicity(chapter3.5)

1A,1B,2

Carcinogenicity(chapter3.6)

1A,1B,2

Reproductivetoxicity(chapter3.7)

1A,1B,2

P210

Keepawayfromheat/sparks/openflames/hotsurfaces.–Nosmoking.

Explosives(chapter2.1)

Divisions1.1,1.2,1.3,1.4,1.5

...Manufacturer/supplierorthecompetentauthoritytospecifyapplicableignitionsource(s).

Flammablegases(chapter2.2)

1,2

Flammableaerosols(chapter2.3)

1,2

Flammableliquids(chapter2.6)

1,2,3

Flammablesolids(chapter2.7)

1,2

Self-reactivesubstancesandmixtures

(chapter2.8)

Types

A,B,C,D,E,F

Pyrophoricliquids(chapter2.9)

1

Pyrophoricsolids(chapter2.10)

1

Organicperoxides(chapter2.15)

Types

A,B,C,D,E,F

Flammableliquids(chapter2.6)

4

- specifytokeepawayfromflamesandhotsurfaces.

Oxidizingliquids(chapter2.13)

1,2,3

- specifytokeepawayfromheat.

Oxidizingsolids(chapter2.14)

1,2,3

P211

Donotsprayonanopenflameorotherignitionsource.

Flammableaerosols(chapter2.3)

1,2

P220

Keep/Storeawayfromclothing/.../combustiblematerials.

Oxidizinggases(chapter2.4)

1

...Manufacturer/supplierorthecompetentauthoritytospecifyincompatiblematerials.

Self-reactivesubstancesandmixtures

(chapter2.8)

Types

A,B,C,D,E,F

Oxidizingliquids(chapter2.13)

2,3

Oxidizingsolids(chapter2.14)

2,3

Organicperoxides(chapter2.15)

Types

A,B,C,D,E,F

Oxidizingliquids(chapter2.13)

1

...Manufacturer/supplierorthecompetentauthoritytospecifyincompatiblematerials.

- specifytokeepawayfromclothingaswellasotherincompatiblematerials.

Oxidizingsolids(chapter2.14)

1

P221

Takeanyprecautiontoavoidmixingwithcombustibles/...

Oxidizingliquids(chapter2.13)

1,2,3

...Manufacturer/supplierorthecompetentauthoritytospecifyincompatiblematerials.

Oxidizingsolids(chapter2.14)

1,2,3

P222

Donotallowcontactwithair.

Pyrophoricliquids(chapter2.9)

1

Pyrophoricsolids(chapter2.10)

1

P223

Keepawayfromanypossiblecontactwithwater,becauseofviolentreactionandpossibleflashfire.

Substancesandmixtureswhich,incontactwithwater,emitflammablegases(chapter

2.12)

1,2

P230

Keepwettedwith...

Explosives(chapter2.1)

Divisions1.1,1.2,1.3,1.5

...Manufacturer/supplierorthecompetentauthoritytospecifyappropriatematerial.

- ifdryingoutincreasesexplosionhazard,exceptasneededformanufacturingoroperatingprocesses(e.g.nitrocellulose).

P231

Handleunderinertgas.

Substancesandmixtureswhich,incontactwithwater,emitflammablegases

(chapter2.12)

1,2,3

P232

Protectfrommoisture.

Substancesandmixtureswhich,incontactwithwater,emitflammablegases

(chapter2.12)

1,2,3

P233

Keepcontainertightlyclosed.

Flammableliquids(chapter2.6)

1,2,3

Acutetoxicity–inhalation(chapter3.1)

1,2,3

- ifproductisvolatilesoastogeneratehazardousatmosphere.

Specifictargetorgansystemictoxicity–singleexposure;respiratorytractirritation(chapter

3.8)

3

Specifictargetorgansystemictoxicity–singleexposure;narcosis(chapter3.8)

3

P234

Keeponlyinoriginalcontainer.

Self-reactivesubstancesandmixtures(chapter

2.8)

Types

A,B,C,D,E,F

Organicperoxides(chapter2.15)

Types

A,B,C,D,E,F

Substancesandmixturescorrosivetometals

(chapter2.16)

1

P235

Keepcool.

Flammableliquids(chapter2.6)

1,2,3,4

Self-reactivesubstancesandmixtures

(chapter2.8)

Types

A,B,C,D,E,F

Self-heatingsubstancesandmixtures

(chapter2.11)

1,2

Organicperoxides(chapter2.15)

Types

A,B,C,D,E,F

P240

Ground/bondcontainerandreceivingequipment.

Explosives(chapter2.1)

Divisions1.1,1.2,1.3,1.4,1.5

- iftheexplosiveiselectrostaticallysensitive.

Flammableliquids(chapter2.6)

1,2,3

- ifelectrostaticallysensitivematerialisforreloading.

- ifproductisvolatilesoastogeneratehazardousatmosphere.

Flammablesolids(chapter2.7)

1,2

- ifelectrostaticallysensitivematerialisforreloading.

P241

Useexplosion-proofelectrical/ventilating/lighting/.../equipment.

Flammableliquids(chapter2.6)

1,2,3

…Manufacturer/supplierorthecompetentauthoritytospecifyotherequipment.

Flammablesolids(chapter2.7)

1,2

...Manufacturer/supplierorthecompetentauthoritytospecifyotherequipment.

- ifdustcloudscanoccur.

P242

Useonlynon-sparkingtools.

Flammableliquids(chapter2.6)

1,2,3

P243

Takeprecautionarymeasuresagainststaticdischarge.

Flammableliquids(chapter2.6)

1,2,3

P244

Keepreductionvalvesfreefromgreaseandoil.

Oxidizinggases(chapter2.4)

1

P250

Donotsubjecttogrinding/shock/…/friction.

Explosives(chapter2.1)

Divisions1.1,1.2,1.3,1.4,1.5

...Manufacturer/supplierorthecompetentauthoritytospecifyapplicableroughhandling.

P251

Pressurizedcontainer:Donotpierceorburn,evenafteruse.

Flammableaerosols(chapter2.3)

1,2

P260

Donotbreathedust/fume/gas/mist/vapours/spray.

Acutetoxicity–inhalation(chapter3.1)

1,2

Manufacturer/supplierorthecompetentauthoritytospecifyapplicableconditions.

Specifictargetorgansystemictoxicity–singleexposure(chapter3.8)

1,2

Specifictargetorgansystemictoxicity–prolongedorrepeatedexposure(chapter3.9)

1,2

Skincorrosion(chapter3.2)

1A,1B,1C

- ifinhalableparticlesofdustsormistsmayoccurduringuse.

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

P261

Avoidbreathingdust/fume/gas/mist/vapours/spray.

Acutetoxicity–inhalation(chapter3.1)

3,4

Manufacturer/supplierorthecompetentauthoritytospecifyapplicableconditions.

Respiratorysensitization(chapter3.4)

1

Skinsensitization(chapter3.4)

1

Specifictargetorgansystemictoxicity–singleexposure;respiratorytractirritation(chapter3.8)

3

Specifictargetorgansystemictoxicity–singleexposure;narcosis(chapter3.8)

3

P262

Donotgetineyes,onskin,oronclothing.

Acutetoxicity–dermal(chapter3.1)

1,2

P263

Avoidcontactduringpregnancy/whilenursing.

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

P264

Wash...thoroughlyafterhandling.

Acutetoxicity–oral(chapter3.1)

1,2,3,4

...Manufacturer/supplierorthecompetentauthoritytospecifypartsofthebodytobewashedafterhandling.

Acutetoxicity–dermal(chapter3.1)

1,2

Skincorrosion(chapter3.2)

1A,1B,1C

Skinirritation(chapter3.2)

2

Eyeirritation(chapter3.3)

2A,2B

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

Specifictargetorgansystemictoxicity–singleexposure(chapter3.8)

1,2

Specifictargetorgansystemictoxicity–prolongedorrepeatedexposure(chapter3.9)

1

P270

Donoteat,drinkorsmokewhenusingthisproduct.

Acutetoxicity–oral(chapter3.1)

1,2,3,4

Acutetoxicity–dermal(chapter3.1)

1,2

Reproductivetoxicity–effectsonorvialactation(chapter3.7)

Additionalcategory

Specifictargetorgansystemictoxicity–singleexposure(chapter3.8)

1,2

Specifictargetorgansystemictoxicity–prolongedorrepeatedexposure(chapter3.9)

1

P271

Useonlyoutdoorsorinawell-ventilatedarea.

Acutetoxicity–inhalation(chapter3.1)

1,2,3,4

Specifictargetorgansystemictoxicity–singleexposure;respiratorytractirritation(chapter3.8)

3

Specifictargetorgansystemictoxicity–singleexposure;narcosis(chapter3.8)

3

P272

Contaminatedworkclothingshouldnotbeallowedoutoftheworkplace.

Skinsensitization(chapter3.4)

1

P273

Avoidreleasetotheenvironment.

Hazardoustotheaquaticenvironment–acutetoxicity(chapter4.1)

1,2,3

- ifthisisnottheintendeduse.

Hazardoustotheaquaticenvironment–chronictoxicity(chapter4.1)

1,2,3,4

P280

Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

Explosives(chapter2.1)

Divisions1.1,1.2,1.3,1.4,1.5

Manufacturer/supplierorthecompetentauthoritytospecifytypeofequipment.

- Specifyfaceprotection.

Flammableliquids(chapter2.6)

1,2,3,4

Manufacturer/supplierorthecompetentauthoritytospecifytypeofequipment.

- Specifyprotectiveglovesandeye/faceprotection.

Flammablesolids(chapter2.7)

1,2

Self-reactivesubstancesandmixtures(chapter2.8)

TypesA,B,C,D,E,F

Pyrophoricliquids(chapter2.9)

1

Pyrophoric