傅獻(xiàn)彩《物理化學(xué)》（第5版）筆記和課后習(xí)題（含考研真題）詳解

絎?绔犮€€姘斻€€浣?/a>1.1銆€澶嶄範(fàn)絎旇銆愰€氬叧鎻愯銆?/span>鏈珷閫氳繃姘斾綋鍒嗗瓙榪愬姩妯″瀷錛屼粠寰瑙掑害浜?jiǎn)瑙ｅ垎瀛愮殑杩愬姩桢緥銆傛湰绔犻噸鐐瑰湪浜庝簡(jiǎn)瑙ｆ皵浣撳垎瀛愮殑鎬ц川錛屽榪愬姩鍏紡銆侀€熺巼鍒嗗竷銆佽兘閲忓垎甯冦€佺鎾為鐜囩瓑銆傚湪闈炵悊鎯蟲(chóng)皵浣撲腑閲嶇偣浜?jiǎn)瑙anderWaals鏂圭▼鍙?qiáng)彐瘮鐘舵€佸畾寰嬨€?/p>銆愮煡璇嗘鏋躲€?/span>銆愰噸鐐歸毦鐐瑰綊綰熾€?/span>涓€銆佹皵浣撳垎瀛愬姩鐞嗚1鐞嗘兂姘斾綋鐞嗘兂姘斾綋錛氱鍚堟柟紼媝V錛漬RT銆?/p>銆愯ˉ鍏呫€?/span>姘斾綋鍦ㄤ綆鍘嬪強(qiáng)杈冮珮娓╁害涓嬫洿絎﹀悎鐘舵€佹柟紼媝V錛漬RT2姘斾綋鍒嗗瓙鍔ㄧ悊璁虹殑鍩烘湰鍏紡錛?錛夋皵浣撶殑鏍瑰潎鏂歸€熺巼寮忎腑錛寀縐頒負(fù)姘斾綋鐨勬牴鍧囨柟閫熺巼錛?imgwidth="279"height="45"src="/uploads/ebook/944002886e844a6dae5ca4dcfc4a27b4/mobileAes/epub/OEBPS/images/image003.png">錛?錛夋皵浣撳帇鍔涘拰鏍瑰潎鏂歸€熺巼鐨勫叧緋伙紙鏍規(guī)嵁姘斾綋鍒嗗瓙鍔ㄧ悊璁哄鍑虹殑鍩烘湰鏂圭▼寮忥級(jí)3鍑犱釜緇忛獙瀹氬緥錛堣琛?-1-1錛?/p>琛?-1-1銆€緇忛獙瀹氬緥鎬葷粨浜屻€佺悊鎯蟲(chóng)皵浣撶殑鐘舵€佸浘鐞嗘兂姘斾綋鍧囪〃紺烘洸闈笂涓旀弧瓚沖叧緋誨紡錛?imgwidth="91"height="54"src="/uploads/ebook/944002886e844a6dae5ca4dcfc4a27b4/mobileAes/epub/OEBPS/images/image006.png">錛岃鐘舵€佸浘涔熺О涓虹浉鍥俱€傦紙瑙佸浘1-1-1鍜?-1-2錛?/p>鍥?-1-1銆€p-V鍧愭爣鍥句笂鐞嗘兂姘斾綋鍦ㄤ笉鍚屾俯搴︿笅鐨勭瓑娓╃嚎鍥?-1-2銆€V-T鍧愭爣鍥句笂鐞嗘兂姘斾綋鍦ㄤ笉鍚屽帇鍔涗笅鐨勭瓑鍘嬬嚎涓夈€佸垎瀛愯繍鍔ㄧ殑閫熺巼鍒嗗竷1Maxwell閫熺巼鍒嗗竷瀹氬緥鍒嗗瓙閫熺巼鍒嗗竷鏇茬嚎涓庢俯搴︾殑鍏崇郴錛堣鍥?-1-3錛?/p>鍥?-1-3銆€鍒嗗瓙閫熺巼鍒嗗竷鏇茬嚎涓庢俯搴︾殑鍏崇郴銆愬叧緋繪帹瀵箋€?/span>T2錛濼1錛岄殢鐫€娓╁害鍗囬珮錛屾渶楂樼偣涓嬬Щ銆?/p>2鍒嗗瓙閫熺巼鐨勪笁涓粺璁″鉤鍧囧€兼瘮杈冿紙瑙佽〃1-1-2錛?/p>琛?-1-2銆€鍒嗗瓙閫熺巼鐨勪笁涓粺璁″鉤鍧囧€兼瘮杈?/p>鍥涖€佸垎瀛愬鉤鍔ㄨ兘鐨勫垎甯?/p>1鍒嗗瓙鑳介噺澶勪簬E锝烇紙E錛媎E錛変箣闂寸殑鍒嗗瓙鍗犳€誨垎瀛愪腑鐨勫垎鏁?/p>鑳介噺鍒嗗竷鍑芥暟f錛圗錛?/p>2鍦ㄤ簩緇村鉤闈㈣兘閲忓ぇ浜庢煇瀹氬€糆1鐨勫垎瀛愬垎鏁?/p>3鍦ㄤ笁緇寸┖闂磋兘閲忓ぇ浜庢煇瀹氬€糆1鐨勫垎瀛愬垎鏁?/p>浜斻€佹皵浣撳垎瀛愬湪閲嶅姏鍦轟腑鐨勫垎甯?/p>Boltzmann錛堢幓鑰沖吂鏇鹼級(jí)鍏紡錛?/p>鍏€佸垎瀛愮殑紕版挒棰戠巼鍜屽鉤鍧囪嚜鐢辯▼1騫沖潎鑷敱紼?/p>2鍒嗗瓙鐨勪簰紕伴鐜?/p>3鍒嗗瓙涓庡櫒澹佺殑紕版挒棰戠巼4鍒嗗瓙闅欐祦闅欐祦閫熷害涓冦€佸疄闄呮皵浣?/p>1瀹為檯姘斾綋鐨勮涓?/p>錛?錛夊帇緙╁洜瀛愶紙Z錛夎閲忓亸宸殑澶у皬錛?/p>銆愬垽鎹€?/span>鈶?/span>鐞嗘兂姘斾綋鐨刾Vm錛漅T錛孼錛?銆?/p>鈶?/span>瀵瑰疄闄呮皵浣擄紝鑻錛?錛屽垯pVm錛濺T錛屽疄闄呮皵浣撶殑鍙帇緙╂€ф瘮鐞嗘兂姘斾綋灝忋€?/p>鈶?/span>褰揨錛?鏃訛紝鎯呭喌鍒欑浉鍙嶃€?/p>錛?錛塟鐨勫彉鍖栫被鍨?/p>鈶?/span>Z闅忓帇鍔涘鍔犺€屽鍔狅紝濡侶2銆?/p>鈶?/span>闅忓帇鍔涘鍔犺€屽厛涓嬮檷鍐嶄笂鍗囷紝鏈夋渶浣庣偣錛屽CH4銆?/p>2Boyle娓╁害鏃剁殑娓╁害涓築oyle娓╁害銆?/p>銆愬垽鎹€?/span>褰撴皵浣撴俯搴﹂珮?shù)簬TB鏃訛紝姘斾綋闅句互鍘嬬緝錛岄毦浠ユ恫鍖栥€?/p>3vanderWaals鏂圭▼寮?/p>4緇村埄鏂圭▼鍏€佹皵娑查棿鐨勮漿鍙樷€斺€斿疄闄呮皵浣撶殑絳夋俯綰垮拰娑插寲榪囩▼1vanderWaals鏂圭▼寮忕殑絳夋俯綰?/p>鑼冩皬鏂圭▼灞曞紑鍚庯紝鍙緱Vm鍊煎彲浠ユ湁涓夌鎯呭喌錛氾紙1錛変竴瀹炴牴涓よ櫄鏍癸紱錛?錛変笁涓浉絳夌殑瀹炴牴錛涳紙3錛変笁涓暟鍊間笉鍚岀殑瀹炴牴銆?/p>2瀵規(guī)瘮鐘舵€?/p>瀹氫箟錛?imgwidth="69"height="57"src="/uploads/ebook/944002886e844a6dae5ca4dcfc4a27b4/mobileAes/epub/OEBPS/images/image029.png">錛?imgwidth="58"height="59"src="/uploads/ebook/944002886e844a6dae5ca