硫酸MSDS中英文互譯

MSDS第一部分化學(xué)品及企業(yè)標(biāo)識(shí)化學(xué)品中文名稱：硫酸Chemicalproductschinesename:liusuan國家應(yīng)急電話ationalemergencyphone二部分成分/組成信息Section2Compositionandinformation純品√混合物×有害成分濃度CASNo.硫酸98%7664-93-9第三部分危險(xiǎn)性概述Hazardstype:8.1typeCorrosivespresentingacidicproperties侵入途徑：吸入、食入健康危害：對(duì)皮膚、粘膜等組織有強(qiáng)烈的刺激和腐蝕作用。蒸氣或霧可引起結(jié)膜炎、結(jié)膜水腫、角膜混濁，以致失明；引起呼吸道刺激，重者發(fā)生呼吸困難和肺水腫；高濃度引起喉痙攣或聲門水腫而窒息死亡。口服后引起消化道燒傷以致潰瘍形成；嚴(yán)重者可能有胃穿孔、腹膜炎、腎損害、休克等。皮膚灼傷輕者出現(xiàn)紅斑、重者形成潰瘍，愈后癱痕收縮影響功能。濺入眼內(nèi)可造成灼傷，甚至角膜穿孔、全眼炎以至失明。慢性影響：牙齒酸蝕skinandmucousmembranesandothertissue.Vaporormistmaycausecauselaryngospasm,glottiseperforation,panophthalmitisandlossofsight.emphysemaandpneumosclerosiEnvironmentaleffect:ItisharmfultoenvironmentCombustionhazard:Thisproducthelpstocoandirritant,maycauseburnstohumanbody第四部分：急救措施皮膚接觸：立即脫去污染的衣著，用大SkinContact:ImmediatelyremovecontaminatEyeContact:Immediatelyfiledpalpebral,withplentyofliquidwaterorInhalation:Escapetofreshair.KeepRespiratoryTractUnobstructed,If危險(xiǎn)特性：遇水大量放熱，可發(fā)生沸濺。與易燃物(如苯)和可燃物(如糖、纖維素Hazardproperties:Contactwithwatergeneratesplentyofheat,andcauseombustiblematerial(asSugar,cellulose,etc.).andevenresultincombustion.Reactviolentlywithcalciumcarbide,perchlornitrate,picrate,metalpowder,etc.andcausecombustionorexplosion.ExplosionHazards:sulfuroxideExtinguishingmeasurement:FirefightermustwearacidandalExstinguisher:Vaporificwater,carbondioxideandsandysoil.Avoidflowstriketheproductopreventshinburnsbecauseofplentyofheatproducedincontactwithwater.急處理人員戴自給正壓式呼吸器，穿防酸堿工作服。從上風(fēng)處進(jìn)入現(xiàn)場(chǎng)。盡可能切斷泄漏源。防止流入下水道、排洪溝等限制性空間。小量泄漏：將地面灑上蘇打灰，然后用大量水沖洗，洗水稀釋后放入廢水系統(tǒng)。大量泄漏：構(gòu)筑圍堤或挖坑收容。噴霧狀水冷卻和稀釋蒸汽、保護(hù)現(xiàn)場(chǎng)人員、把泄漏物稀釋成不燃物。用泵轉(zhuǎn)移至槽車或?qū)Ｓ檬占鲀?nèi)，回收strictlyrestrictaccess.SuggestthatemergencyProcessingpersonnelwearSelf-containedbreathingapparatusandAnti-acid&alkaliworkclothing,entersitefromthewindwardside.Cutoffsourceofspills.PrevententryintoSmallspill:Sprinklethesodaashontheground,thenflushwithplentyofbeinflammablematerial.Transfertotankcaroraspecialcollectorwithpump.Recoverorremovetowastetreatmentplantsfordisposal.第七部分：操作處置與儲(chǔ)存過專門培訓(xùn)，嚴(yán)格遵守操作規(guī)程。建議操作人員佩戴自吸過濾式防毒面具(全面罩),穿橡膠耐酸堿服，戴橡膠耐酸堿手套。遠(yuǎn)離火種、熱源，工作場(chǎng)所嚴(yán)禁吸煙。防止蒸氣泄漏到工作場(chǎng)所空氣中。避免與還原劑、堿類、醇類、堿金屬接觸。搬運(yùn)時(shí)要輕裝輕卸，防止包裝及容器損壞。配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。稀釋或制備溶液時(shí)，應(yīng)把酸加入水中，避免沸騰和飛濺。Handlingshouldbemechanicalandautomaticaspossibleshouldobtainspecialtraining,andfollowclosetooperationprocedures.alkalis,alcoholsandalkalimetal.Handlewit設(shè)備和合適的收容材料。ofignition.Keepawayfromheat.Thesealed.Separatefromcombustibles,reducingagents,alkalis,alkalimetalandediblechemistry,andnomixingwitheachotherarereleaseequipmentsandcontainingmaterialshouldbereserved第八部分：接觸控制/個(gè)體防護(hù)Section8:ExposureControls/PersonalProtection職業(yè)接觸限值MAC(mg/m3):--TWA(mg/m3):1監(jiān)測(cè)方法：氰化鋇比色法Monitoringmeasurements:bariumcyanidecolorimetryEngineeringControls:KeepinasealedareaHandlingshouldbemechanicalandautomaticaspossibleasi戴自吸過濾式防毒面具(全面罩)或空氣呼吸器。緊急事態(tài)搶救或撤離時(shí)，建議佩戴氧氣呼吸器。Respiratoryprotection:ifitislikelytocontactwiththemist,wearself-EyeProtection:measurementshavebeentakeninrespiratoryprotectionOtherprotection:Nosmoking,eatinganddrinkinginwork-station.Placethe含量：工業(yè)級(jí)一級(jí)≥98.2%;二級(jí)≥97.2%。AppearanceandPhysicalstate:pureproductsarecolorlessandclearoilyliquid,odorless.molecularformula:H2S04Molecularweight:98.08pH值：無意義熔點(diǎn)(℃):10.5RelativeDensity(water=1):1.83Relativevapordensity(air=informationavailable.閃點(diǎn)(℃):無意義引燃溫度(℃):無意義爆炸上限[%(V/V)]:無意義爆炸下限[%(V/V)]:無意義燃燒熱(kJ/mol):無意義臨界溫度(℃):無資料Burningheat(kJ/mol):NotapplicableCriticalTemperature:Notinformationavailable.臨界壓力(MPa):無資料CriticalTemperature:Notinformationavailable主要用途：用于生產(chǎn)化學(xué)肥料，在化工、醫(yī)藥、塑料、燃料、石油提煉等工業(yè)也有廣泛industry,plastics,dye,oilrefiningandotherindustry第十部分：穩(wěn)定性和反應(yīng)活性Incompatibilitywithvarioussubstances:alkalis,alkali避免接觸的條件ConditionstoAvoid:聚合危害HazardousPolymerization:none分解產(chǎn)物decompositionproduct:Sectionll:ToxicologicalInforacutetoxicity:LD50:2140mg/kg(bigLC50:510mg/m3,2小時(shí)(大鼠吸入);320mg/m3,2小時(shí)(大鼠吸入)LC50:510mg/m3,twohours(bigratinhaling);320mg/m3,twohours(bigratinhaling)刺激性：家兔經(jīng)眼：1380μg,重度刺激。Otherhazardouseffect:thisproductishazardoustoenvironment,especiallythecontaminationtowatersandsoil第十三部分：廢棄處置緩慢加入堿液一石灰水中，并不斷攪拌，反應(yīng)停止后，用大量水沖入廢水系統(tǒng)。。Disposalmeasurement:slowlyaddsodasolutionorlimewaterintoproductsandstircontinuously,afterthereactionends,flushwithplentyofwateranddischargeintowastewaterHazardousgoodnumber:81007UNnumber:1830包裝標(biāo)志：腐蝕品Packagemeasurement:packagewithanti-acidjarorceramicbottlecontaining批準(zhǔn)。鐵路運(yùn)輸時(shí)應(yīng)嚴(yán)格按照鐵道部《危險(xiǎn)貨物運(yùn)輸規(guī)則》中的危險(xiǎn)貨物配裝表進(jìn)行配裝。起運(yùn)時(shí)包裝要完整，裝載應(yīng)穩(wěn)妥。運(yùn)輸過程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴(yán)禁與還原劑、堿類、醇類、堿金屬、食用化學(xué)品等混裝混運(yùn)。運(yùn)輸時(shí)運(yùn)輸車輛應(yīng)配備泄漏應(yīng)急處理設(shè)備。運(yùn)輸途中應(yīng)防曝曬、雨淋，防高溫。公路運(yùn)輸時(shí)要按規(guī)定路線Transportationcautions:ThisprodepartmentsforapprovalpaccordancewithdangerousgoodsloadtablelistedinTDGC.Ensurepackagecollapse,nofall,andnodamange.Donotmixwithreducingagent,alkalis,alcohols,alkalimetal,edible