橡塑合金產(chǎn)品說明書中英文

橡塑合金產(chǎn)品說明書RUBBER-PLASTICALLOYS(NBR/PVCBlends)Productionmanual本公司的“橡塑合金”是丁腈橡膠（NBR）與聚氯乙烯（PVC）的熔融共混膠。由于丁腈橡膠與聚氯乙烯有很好的相容性，兩種材料可以用任何比例進(jìn)行共混。Thecompany's"Rubber-PlasticAlloy"isaNBRandPVCmeltingblends.BecausethegoodcompatibilityofNBRandPVC,twomaterialscanbeblendedwithanyproportion.“橡塑合金”為非污染型淺黃色膠片.牌號、技術(shù)參數(shù)、重要特性和特殊用途見下表“Rubber-PlasticAlloys”,nonpollutinglightyellowfilms.Thiertrademark,technicalparameters,maincharacteristicsandspecialusageareinthetablebelow:牌號NBR的丙烯腈含量%共混比(NBR/PVC)典型門尼粘度ML(1+4)100特性特殊用途耐臭氧耐候性耐油耐溶劑性抗燃油透過性耐磨抗撕強(qiáng)度阻燃性耐寒性擠出壓延工藝NV72181870/3060B~CB~CDB~CAAA~B耐寒優(yōu)，適宜生產(chǎn)膠輥、安全靴、膠管NV50702870/3055B~ABB~CBAA~BA耐寒優(yōu)良，擠出壓延性能優(yōu)NV50753370/3055AA~BA~BA~BABA與金屬及織物粘合性佳，擠出壓延性優(yōu)NV54953370/3065AA~BA~BA~BABA工藝性能優(yōu)?？膳c國外相稱品牌匹比NV70503370/3045AA~BA~BA~BABA制品表面光潔度高，工藝性能佳NV64203360/4065AA~BA~BAAB~CA耐磨、屈撓性優(yōu)異，宜生產(chǎn)膠輥、輸送帶NV50934070/3075AAAAADA耐臭氧及屈撓性能優(yōu)，適宜生產(chǎn)紡織器材Trade-markAcrylonitrilecontentofNBR,%(NBR/PVC),%TypicalMooneyviscosityML(1+4)100NV72181870/3060NV50702870/3055NV50753370/3055NV54953370/3065NV70503370/3045NV64203360/4065NV50934070/3075Trade-markFeature 特殊用途OzoneandweatherresistanceOilandsolventresitanceAnti-fuelpermeabilityWearandtearstrengthFuelre-tardanceColdre-sistanceExtrudingandcalen-deringSpecialUsageNV7218B~CB~CDB~CAAA~BExcellentcoldresistanse,suitableforproductionofrubberrollers,safetyboots,rubberhoseNV5070B~ABB~CBAA~BAExcellentcoldreresistance,excellentextrudingandcalenderingperformanceNV5075AA~BA~BA~BABAgoodadhesionwithmetalsandfablics,excellentextrudingandcalendaringperformaceNV5495AA~BA~BA~BABAExcellentprocessingproperty.CanbecomparedwithforeignbrandsratherNV7050AA~BA~BA~BABAGlossysurfaceonProducts,goodprocessingpropertyNV6420AA~BA~BAAB~CAExcellentwearandflexresistance,fshouldproducerubberroller,conveyorbeltNV5093AAAAADAExcellentflexAndozoneresistance,suitableforproductionoftextileequipment橡塑合金的特點(diǎn)CharacteristicsofNBR/PVCBlend：與丁腈橡膠相比，橡塑合金有如下優(yōu)點(diǎn)：Comparedwiththenitrilerubber,NBR/PVCBlendhasthefollowingadvantages：耐臭氧性和耐候性（耐臭氧龜裂性和耐陽光龜裂性）顯著提高。Ozoneresistanceandweatherability（ResistancetoozonecrackingandSunshinecrackingresistance）Significantlyincreased在標(biāo)準(zhǔn)臭氧老化實(shí)驗(yàn)條件下（臭氧濃度50pphm、拉伸20%、溫度40℃）實(shí)驗(yàn)72小時(shí)，橡塑合金不龜裂(化學(xué)工業(yè)合成材料老化質(zhì)量監(jiān)督檢查中心和上海市橡膠制品研究所檢查報(bào)告)，而丁腈橡膠則嚴(yán)重龜裂（見照片）。在更苛刻的條件下拉伸40%、溫度40℃）實(shí)驗(yàn)96小時(shí)，橡塑合金也不龜裂(沈陽橡膠四廠研究所檢測報(bào)告)50pphm×20%×40℃×臭氧老化實(shí)驗(yàn)后試樣表面狀況←丁腈橡膠（丙烯腈含量33%）NitrileRubber(Acrylonitrilecontent33%)←橡塑合金（共混比70/30、丙烯腈含量33%）NBR/PVCBlend(blendratio70/30,Acrylonitrilecontent33%)After72hourstestingunderastandardozoneagingconditions(Ozoneconcentration50pphm,extend20%,tempreture40℃),NBR/PVCBlenddoesnotcracks,buttheNBRisseverelycracking(seeingthephoto).Undermoresevereconditions,(Ozone370-520pphmX40%,X40℃)耐油、耐溶劑和耐化學(xué)藥品性能提高。Oil,solventandchemicalresistanceincrease橡塑合金與丁腈橡膠的耐油性均隨丙烯腈含量的增長而提高，在丙烯腈含量同等的情況下，橡塑合金明顯優(yōu)于丁腈橡膠。增長PVC的比例，橡塑合金的耐油性提高。OilresistanceofNBR/PVCBlendandnitrilerubberwithacrylonitrilecontentswereincreasedwiththeincrease,Acrylonitrilecontentinthesamecase,NBR/PVCBlendissuperiortoNBR.IncreasetheproportionofPVC,theblendincreasedoilresistance.圖中英文更改→左inNo.3Oil，volumechange，NBR，NBR/PVC右inNo.2OilI，volumechange英文更改：左infuelB右infuelB左Tensilestrengthnretention右volumechange左NBR/PVCBlend右Blendratio★燃油透過率明顯減少，并且丙烯腈含量越高?！颬ermeabilityoffueldecreaseobviously,andthehighertheacrylonitrilecontent,thelowerthepermeability英文更改左infuelC右infuelM15左，右volumechange左，右NBRNBR/PVCblend（70/30）【NoteA】【注A】1.標(biāo)準(zhǔn)實(shí)驗(yàn)油（standardtestoils）①2號油—苯胺點(diǎn)93±3℃①No.2Oil—AnilinePoint93±3℃②3號油—苯胺點(diǎn)70±1℃②No.3Oil—AnilinePoint70±1℃2.實(shí)驗(yàn)用燃油（以下組成均為體積比）2.Testfuels（thefollowingcomponentarevolumeratio）①燃油B—甲/異辛烷（30/70）,模擬普通汽油（無添加劑）①FueloilB—Toluene/isooctane(30/70),Simulationofregulargasoline(no-additive)②燃油C—甲苯/異辛烷（50/50）模擬高芳烴含量汽油；②FuelC-toluene/isooctane(50/50),Simulationofhigharomaticcontentofgasoline③燃油E-10—燃油B/乙醇（90/10），模擬中、美使用的乙醇汽油；③FuelE-10—FuelB/ethanol(90/10),SimulationchinaandtheU.S.useofTheethanolgasoline.④燃油M-15—燃油C/甲醇（85/15）,模擬歐洲使用的甲醇汽油；④FuelM-15—fuelC/Methanol(85/15),SimulationmethanolfuelusedinEurope;⑤燃油M-85—燃油C/甲醇（15/85），模擬歐洲特種車輛使用的燃油。⑤FuelM-85---fuelC/Methanol(15/85),SimulationspecialvehiclesfuelusedinEurope以上各圖的英文修改：透過率--Permeability燃油C透過率—PermeabilityoffuelC燃油透過率—PermeabilityoffuelsFuelB,FuelC,fuelE-10,fuelM15,FuelM85

耐磨性和撕裂強(qiáng)度提高。Abrasionresistanceandtearstrengthincreased以下圖的英文修改：左-耐磨性Abrasionresistance右-撕裂強(qiáng)度tearstrength左-阿克隆磨耗Akronabration右-同上左-丙烯腈含量-Acrylonitrilecontent右-共混比blendratio丁腈橡膠-NBR橡塑合金-NBR/PVCBlend阻燃性提高。氧指數(shù)是衡量高聚物是否易燃的一項(xiàng)重要指標(biāo)：氧指數(shù)越小，則越容易燃燒。氧指數(shù)＜21的材料，一般在空氣中很容易燃燒。如下圖可見，丁腈橡膠屬易燃材料。由于聚氯乙烯樹脂的含氯量達(dá)56%左右，氧指數(shù)＞40，屬自熄性材料。丁腈橡膠與聚氯乙烯共混的“橡塑合金”，氧指數(shù)比丁腈橡膠高，使阻燃性提高★improveflameretardance.Oxygenindexisameasureofwhetherthecombustiblepolymerisanimportantindicator:thesmallertheoxygenindex,themoreeasytoburn.Oxygenindex<21ofmaterial,usuallyintheairiseasytoburn.Followingchartshows,nitrilerubberisflammablematerials.AsthePVCresinreachedabout56%chlorine,oxygenindex>40,isself-extinguishingmaterial.OxygenindexofNBR/PVCBlendhigherthanthenitrilerubbertoimprovetheflameretardancy上圖英文：阻燃性（生膠）Flameretardance(rawrubber),氧指數(shù)Oxygenindex★加工性能改善。與丁腈橡膠相比，擠出速度加快、擠出口型膨脹減少、表面光潔。對壓延和模壓制品的加工和外觀質(zhì)量都有改善?！飌rocessingpropertyimprovement.ComparedwiththeNBR,fasterextrusion,dieswellreduction,cessingandappearanceofcalenderedandmoldedproductshasimproved.上圖的英文：擠出速度extrusionspeed擠出膨脹率dieswell●●橡塑合金的局限性：壓縮永久變形及耐寒性比丙烯腈含量相同的丁腈橡膠要差。但是，通過合理選擇牌號、并用以及配方調(diào)整，可以填補(bǔ)局限性、改善性能。上圖英文：壓縮永久變形compressionset耐寒性coldresistance脆性溫度brittlenesstemperature【說明】以上橡塑合金與丁腈橡膠性能對比圖例是供客戶選用作參考。使用不同的助劑、配方以及工藝條件，會獲得不同的性能數(shù)據(jù)?！綝escription】aboverubberalloycomparedwiththeNBRisforcustomerstousethelegendforreference.Usingdifferentadditives,formulationandprocessconditions,willbedifferentperformancedata.●橡塑合金的重要應(yīng)用●●膠管—燃油膠管、液壓膠管的內(nèi)、外層膠，消防膠管；●●電線、電纜—耐油電纜護(hù)套、礦用電纜護(hù)套、阻燃電纜護(hù)套、船用電纜護(hù)套；；●●紡織配件—紡織皮圈、紡織皮輥；●●膠輥—印刷膠輥（墨輥、酒精潤版輥、UV油墨輥）、橡塑并用膠輥；●●輸送帶—阻燃輸送帶、耐油輸送帶；●●密封件—密封墊圈、高硬度防塵圈、防塵罩、密封條；●●膠板—耐油膠板、阻燃地板；●●膠布—軟體貯油制品（油箱、油囊、油罐）；●●鞋底—安全鞋、遠(yuǎn)動鞋?！瘛衿渌陀凸I(yè)配件●ThemainapplicationofNBR/PVCBlend:

●●Hose-Outerandinnerruueroffuelhoseandhydraulichose,firehose;

●●Wires,cables-Oilresistantcablejacket,minecablesheath,flameretardantcablejacket,marinecablesheath;

●●TextileAccessories-Textileapron,textileroller;

●●Roller-printingrubberroller(roller,alcoholdampeningrollers,UVinkroller),industrialrubberrollers

●●Conveyor–Flameretardantandoilresistantconveyorbelt;

●●seals-sealinggaskets,highhardnessdustring,automobiledustcover

●●Rubbersheet-oilresistantrubbersheet,flameretardantfloor;

●●Rubbercoatedfabric-oilstorageproducts(fueltank,oilbag,tank);

●●shoes-safetyshoes,sportsshoes

●●

Otheroilresistantindustryparts●配方舉例●Formulationexample【說明】以下舉例系初始配方，僅供參考?？蛻粜韪鶕?jù)產(chǎn)品的技術(shù)規(guī)定、使用的橡膠原材料、生產(chǎn)設(shè)備、工藝條件以及成本的具體情況設(shè)計(jì)合理的生產(chǎn)配方。1.膠管（1）燃油膠管內(nèi)層膠橡塑合金（NV5495）100、氧化鋅5、硬脂酸2、防老劑RD1、防老劑4010NA1、N550炭黑20、N770炭黑60、增塑劑DOP20,、增塑劑TCP20、古馬隆樹脂8、促進(jìn)劑CZ1.5、促進(jìn)劑TMTD0.5、硫黃0.5，合計(jì)239.5（2）鋼絲編織膠管外層膠橡塑合金（NV5075）100、丁苯橡膠（1500）30、氧化鋅5、硬脂酸1、防老劑RD1、防老劑4010NA2、石蠟1、N550炭黑30、N770炭黑50、增塑劑DOP25、環(huán)烷油5、古馬隆樹脂6、促進(jìn)劑CZ1.5、促進(jìn)劑TMTD0.2、硫黃2，合計(jì)259.7【Description】Thefollowingexamplelineinitialformulaforreferenceonly.Customertechnicalrequirementsbasedproducts,theuseofrubberrawmaterials,productionequipment,processconditionsandspecificconditionsdesignedcostofproductionformula.

1.Hose

(1)Theinnerrubberoffuelhose

NV5495100,5zincoxide,stearicacid2,antioxidantRD1,antioxidant4010NA1,N550carbonblack20,N770CarbonBlack60,plasticizerDOP20,,plasticizerTCP20,coumaroneresin8,AcceleratorCZ1.5,acceleratorTMTD0.5,sulfur0.5,Total239.5

(2)Outerrubberofsteelwirebraidedrubberhose

NV5075100,SBR(1500)30,zincoxide5stearicacid1,antioxidantRD1,Antioxidant4010NA2,paraffin1,N550carbonblack30,N770carbonblack50,plasticizerDOP25,Naphthenicoil5,6,coumaroneresin,acceleratorCZ1.5,acceleratorTMTD0.2,sulfur2,Total259.7

2電纜（1）普通電纜護(hù)套橡塑合金(NV5075)100、氧化鋅5、硬脂酸2、防老劑RD1、防老劑4010NA1、N550炭黑10、白炭黑30、滑石粉40、氫氧化鋁50、三氧化二銻5、增塑劑DOP10、氯化石蠟（52）15、促進(jìn)劑DM0.3、促進(jìn)劑TMTD0.5硫黃0.3，合計(jì)270.1（2）阻燃電纜護(hù)套橡塑合金(NV5075)100、氧化鋅5、硬脂酸2、防老劑RD1、防老劑MB1、N550炭黑5、白炭黑50、超細(xì)滑石粉20、超細(xì)氫氧化鋁50、三氧化二銻10、阻燃劑氯化石蠟（70）10、增塑劑氯化石蠟（52）10、硅烷偶聯(lián)劑A-1890.8、促進(jìn)劑DM0.3、促進(jìn)劑TMTD0.6、硫黃0.5、交聯(lián)劑DCP(40%)1,合計(jì)267.22cable

(1)GeneralCablejaket

NV5075100,5zincoxide,stearicacid2,antioxidantRD1,Antioxidant4010NA1,N55010carbonblack,silica30,talc40,aluminumhydroxide50,antimonytrioxide5,plasticizerDOP10,Chlorinatedparaffin(52)15,AcceleratorDM0.3,,acceleratorTMTD0.5,Sulfero.3,Total270.1

(2)flame-retardantcablejacket

NV5075100,5zincoxide,stearicacid2,antioxidantRD1,AntioxidantMB1,N550carbonblack5,silica50,super-finetalc20,50super-finealuminumhydroxide,antimonytrioxide10,flameretardantChlorinatedparaffin(70)10,plasticizerchlorinatedparaffin(52)10,silanecouplingagentA-1890.8,acceleratorDM0.3,AcceleratorTMTD0.6,sulfur0.5,cross-linkingagentDCP(40%)1,Total267.2

3紡織配件（1）紡織皮圈橡塑合金（NV5093）100、氧化鋅5、硬脂酸1、防老劑22461、防老劑MB0.5、白炭黑15、鈦白粉10、增塑劑DOP12、液體丁腈橡膠10、抗靜電劑SN0.5、著色劑適量、促進(jìn)劑DM2.8、硫黃2.3，合計(jì)160.1+（2）紡織皮輥橡塑合金（NV5093）100、氧化鋅4、硬脂酸0.5、防老劑22461.5、白炭黑30、明膠30、鈦白粉15、增塑劑DOP15、抗靜電劑SN1.5、促進(jìn)劑DM1.5、硫黃10、著色劑適量，合計(jì)210.5+3TextileAccessories

(1)textileapron

NV5093100,zincoxide5stearicacid1,antioxidant22,461,antioxidantMB0.5,silica15,titaniumdioxide10,plasticizerDOP12,liquidNBR10,antistaticagentsSN0.5,pigmentappropriately,acceleratorDM2.8,sulfur2.3,Total160.1+

(2)textileroller

NV5093100,4zincoxide,stearicacid0.5,Antioxidant22461.5,silica30,gelatin30,pigmenttitaniumdioxide,15,plasticizerDOP15,antistaticagentsSN1.5,acceleratorDM1.5,sulfur10,pigmentappropriately,total210.5+4膠輥（1）印刷膠輥（硬度~30A橡塑合金（NV6420）100、氧化鋅10、硬脂酸1、氧化鎂3、防老劑22461、白炭黑15、鈦白粉5、增塑劑DOP60、液體丁腈橡膠30、專用油膏10、促進(jìn)劑DM0.6、促進(jìn)劑TMTD0.3、促進(jìn)劑TMTM0.6、硫化劑DTDM1.2、硫黃0.3、著色劑適量，合計(jì)237+（2）耐油膠輥（硬度60A）橡塑合金（NV5075）100、氧化鋅5、硬脂酸1.5、氧化鎂3、防老劑RD1、防老劑4010NA1.5、N550炭黑30、白炭黑15、增塑劑DOP30、石油樹脂10、促進(jìn)劑TMTD0.2、硫化劑DTDM1.5、硫黃1.5，合計(jì)200.24Roller

(1)printingroller(hardness~30A)

NV6420230,10zincoxide,stearicacid1,magnesiumoxide3Antioxidant22461,silica15,titaniumdioxide,5,plasticizerDOP60,liquidNBR30,specialfactice10,acceleratorDM0.6,acceleratorTMTD0.3,acceleratorTMTM0.6,curingagentDTDM1.2,sulfur0.3,pigmentappropriately,total237+

(2)Oilresistantroller(Hardness60A)

NV5075100,5zincoxide,stearicacid1.5,MgO3,antioxidantRD1,antioxidant4010NA1.5,N550carbonblack30,silica15,plasticizerDOP30,petroleumresin10,AcceleratorTMTD0.2,curingagentDTDM1.5,sulfur1.5,Total200.25輸送帶*阻燃輸送帶覆蓋膠橡塑合金（NV6240）100、氧化鋅3、硬脂酸2、防老劑4010NA1、防老劑BLE2、石蠟1、N220炭黑30、氯化石蠟（70）10、氯化石蠟（52）15、增塑劑DOP8、古馬隆樹脂5、三氧化二銻5、氫氧化鋁15、硼酸鋅15、促進(jìn)劑CZ1、硫黃1.5，、合計(jì)214.55conveyorbelt

*Flame-retardantconveyorbeltcover

NV6240100,zincoxide3,stearicacid2,antioxidant4010NA1,antioxidantBLE2,paraffin1,N220carbonblack30,chlorinatedparaffin(70)10,chlorinatedparaffin(52)15plasticizerDOP8,coumaroneresin,5,antimonytrioxide5,aluminumhydroxide,15,zincborate15,acceleratorCZ1,sulfur1.5,total214.56密封件（1）防塵密封圈（高硬度85～90A）橡塑合金（NV5070）100、氧化鋅5、硬脂酸1、防老劑RD1、防老劑4010NA1、石蠟1、N330炭黑40、N550炭黑60、增塑劑DBS10、促進(jìn)劑DM1.5、促進(jìn)劑ZDC1.5、硫黃0.3、交聯(lián)劑DCP（40%）5，合計(jì)227.8（2）防塵罩橡塑合金（NV5075）100、納米氧化鋅4、硬脂酸1、氧化鎂3微晶蠟1.5、N550炭黑25、N774炭黑30、增塑劑DOP18、增塑劑DOS6、促進(jìn)劑CZ2、促進(jìn)劑TMTD1、硫黃2.5，合計(jì)196seals

(1)dustseals(highhardnessof85~90A)

NV5070100,zincoxide5stearicacid1,antioxidantRD1,antioxidant4010NA1,paraffin1,N330CarbonBlack40,N550carbonblack60,plasticizerDBS10,DM1.5,ZDC1.5,sulfur0.3,cross-linkingagentDCP(40%)5,Total227.8

(2)dustcover

NV5075100,ZnO4,stearicacid1,microcrystallinewax3MgO1.5,N550carbonblack25,N774CarbonBlack30PlasticizerDOP18,plasticizerDOS6,acceleratorCZ2,acceleratorTMTD1,sulfur2.5,Total19447膠板*耐油膠板橡塑合金（NV5070）100、再生膠50、氧化鋅5、硬脂酸1、防老劑4010NA1、天然氣半補(bǔ)強(qiáng)爐黑100、輕質(zhì)碳酸鈣40、重質(zhì)碳酸鈣5