PALL 頗爾過濾器 -乙烯系統(tǒng)培訓(xùn)

Ethylene

乙烯Ethyleneismadebya

ChemicalReaction

乙烯是通過化學(xué)反應(yīng)制成的ProducedbyCrackingofafeedstock(LiquidorGasfeedstock)

利用給料裂解進(jìn)行生產(chǎn)（液體或氣體給料）EthanegasEthylene

乙烷氣體乙烯NaphthaliquidandGasOilsEthylene

石腦油液體和柴油乙烯DifferentPrefilterandCoalescersolutionsareRequiredforGasorLiquidCrackers

氣體或液體裂解爐需要不同的預(yù)過濾器和聚結(jié)過濾器溶液乙烯裝置從原理上區(qū)分：

裂解

分離從流程和布置上分：

裂解爐區(qū)

急冷區(qū)

壓縮區(qū)

冷區(qū)

熱區(qū)主要乙烯專利商

（管式爐蒸汽熱裂解）

ABBLUMMUS/SRTSTONE&WEBSTER/USCKBRLINDE(SELAS)/LSCCTECHNIP(KTI)典型裂解氣分離流程

順序分離流程（LUMMUS/TP/KBR）脫除重?zé)N、壓縮后按照C1、C2、C3、C4等順序分離；流程最長、裂解氣壓縮機(jī)功率最大；前脫乙烷流程（LINDE）脫除重?zé)N、壓縮后先將C2、C3以及更輕的組份分開，再進(jìn)行分離；典型裂解氣分離流程

前脫丙烷流程（SW，KBR）脫除重?zé)N、壓縮后先將C3、C4以及更輕組份分開，再進(jìn)行分離；裂解氣壓縮機(jī)功率最小、丙烯壓縮機(jī)功率最大、乙烯壓縮機(jī)功率最小；該工藝能耗較低適合大型乙烯裝置。典型裂解氣分離流程

乙烯裝置的核心設(shè)備

裂解爐三機(jī)：

裂解氣壓縮機(jī)、

丙烯制冷壓縮機(jī)、

乙烯制冷壓縮機(jī)裂解氣壓縮機(jī)限制裝置最大能力

（以石腦油為原料，最大能力120-150萬噸/年）乙烯裝置的典型產(chǎn)品

三烯：

乙烯、丙烯、丁二烯三苯：

苯、甲苯、二甲苯為其它有機(jī)原料和三大合成材料的基礎(chǔ)原料用乙烯生產(chǎn)的典型產(chǎn)品聚合：聚乙烯、乙丙橡膠氧化：環(huán)氧乙烷、乙丙橡膠烷基化：乙苯、烷基鋁鹵化：氯乙烷、二氯乙烷、溴乙烷水合：乙醇齊聚：烯烴用丙烯生產(chǎn)的典型產(chǎn)品

聚合—聚丙烯、乙丙橡膠氧化—丙烯酸環(huán)氧化—環(huán)氧丙烷烷基化—異丙苯鹵化—氯丙醇、環(huán)氧氯丙烷水合—異丙醇氨氧化—丙烯晴、丙烯酰胺用丁二烯生產(chǎn)的典型產(chǎn)品聚合—順丁橡膠、丁苯橡膠、ABS低聚—環(huán)辛二烯用三苯生產(chǎn)的典型產(chǎn)品

苯：

乙苯、苯乙烯、環(huán)己烷、氯苯甲苯：

二硝基甲苯、苯甲酸、甲乙苯、

二甲苯二甲苯：

對苯二甲酸、間苯二甲酸、

鄰苯二甲酸酯乙烯的使用

聚乙烯58%氯乙烯13%環(huán)氧乙烷/乙二醇14%乙苯9%烯烴3%乙醛/醋酸乙烯2%其它2%國內(nèi)乙烯裝置

上海1＃14.5三菱遼化12撫順18/80LUMMUS/SW盤錦18LUMMUS廣州20SW中原18LUMMUS獨山子22/100LUMMUS/LINDE上海2＃70LUMMUS燕山71LUMMUS大慶60KBR揚(yáng)子65LUMMUS齊魯72LUMMUS揚(yáng)巴60SW賽科90LUMMUSCSPC80SW/SHELL吉化70LINDE茂名100SW/LUMMUS蘭州60KBR天津20/100LUMMUS鎮(zhèn)海100LUMMUS福煉80LUMMUS四川80SW武漢80LUMMUS國內(nèi)乙烯裝置

EthyleneProcess:HotSection乙烯工藝：熱區(qū)Oil/WaterSeparator

油/水分離器Steambacktofurnaces

蒸汽返回熔爐QuenchWaterTower

驟冷水塔

FuelOil

燃料油

MolSieve/GasDryer

分子篩/氣體干燥劑Fuelgas

燃料氣體QuenchOilTower

淬火塔Furnace

熔爐CausticorAmineSystem

腐蝕性或胺類系統(tǒng)ToBTXunit

到達(dá)BTX單元Caustictodischarge

腐蝕劑排放DilutionSteamSystem

稀釋蒸汽系統(tǒng)Liquid/Liquidcoalescer

液/液聚結(jié)過濾器Liquid/Gascoalescer

液/氣聚結(jié)過濾器Filter

過濾器

123467HCConden-sates

HC聚結(jié)物CompressorProtection

壓縮機(jī)防護(hù)5Gasoline

汽油9810Feed–NaphthaLiquidorEthaneGas

給料-石腦油液體或乙烷氣體Caustic/Gas.Separator

腐蝕劑/氣體分離器WashWater

沖洗水Hydrog.

氫化物PropyleneTower

丙烯塔EthyleneProcess:ColdSection乙烯工藝：冷區(qū)AcetyleneConverter

乙炔轉(zhuǎn)換器crackedGas裂解氣EthaneGasrecycledtofuelgas

乙烷氣體回收為燃料氣體Propylenetopurification

丙烯純化Lightgasolinetohydrogenation

輕汽油氫化C4richcuttofractionation

C4richcut分餾Dryer

干燥劑Gasoline

汽油Liquid/Liquidcoalescer

液/液聚結(jié)過濾器Liquid/Gascoalescer

液/氣聚結(jié)過濾器Filterorcoalescer

過濾器或聚結(jié)過濾器CausticSolution

腐蝕性溶液CH4+H2

910FinalProductEthyleneGas

最終產(chǎn)品乙烯氣體11Caustic/Gas.Separator

腐蝕劑/氣體分離器8CaustictoDischarge

腐蝕劑排放Demethaniizer

脫甲烷塔De-ethanizer

脫乙烷塔Depropanizer

脫丙烷塔Debutanizer

脫丁烷塔EthyleneTower

乙烯塔RecycledEthane

回收乙烷Hydrog.

氫化物Hydrog.

氫化物RecycledPropane

回收丙烷KnockoutDrum

分離罐TheTop10!

Filtration/SeparationApplicationsinEthylene

10大乙烯過濾/分離應(yīng)用Feedstockfiltrationandpurification

給料過濾和純化Particulatefiltrationoftheethanegasorofthenaphthaliquid

乙烷氣體或石腦油液體的微粒過濾Liquid/Liquidcoalescerontheliquidfeedstock

液體給料上的液/液聚結(jié)過濾器Liquid/Gascoalesceronthegasfeedstock

氣體給料上的液/氣聚結(jié)過濾器Purificationandfiltrationofthefuelgastotheburners

進(jìn)入熔爐的燃料氣體的純化和過濾L/Gcoalescerstoremoveimpuritiesinfuelgastoimprovethe“burn”

去除燃料氣體中的雜質(zhì)改善“燃燒”的液/氣聚結(jié)過濾器QuenchOilfiltration

淬火油過濾Removecokeparticlesfromhotoil

去除熱油中的焦炭顆粒QuenchWaterapplication

驟冷水應(yīng)用Removingpy-gasfromwaterwithL/Lcoalescer

利用L/L聚結(jié)過濾器把py-gas（裂解汽油）從水中去除Removingwaterfrompy-gasstreamwithL/Lcoalescer

利用L/L聚結(jié)過濾器把水從py-gas蒸汽中去除CompressorProtection

壓縮機(jī)保護(hù)LubeOilcleanliness

潤滑油清潔LightHCcondensatescoalescer

輕HC冷凝物聚結(jié)過濾器RemovalofwaterfromHCcondensationusingL/Lcoalescer

利用液/液聚結(jié)過濾器去除HC冷凝物中的水HydrogenationCatalystProtection

氫化催化劑保護(hù)Gasolinedewatering

汽油脫水TheTop10!十大應(yīng)用TheTop10!AndMore十大應(yīng)用及更多RedOilfromSpentCaustic；

來自廢堿的紅油9.&10. MolecularSieveProtectionandclean-up

分子篩保護(hù)和清潔GreenOilfromEthylene&EthaneGas

來自乙烯和乙烷氣體的綠油OilfromFinalEthyleneGas

來自最終乙烯氣體的油BufferSealGaspurification

緩沖封閉氣體純化AnalyzerProtection

分析機(jī)保護(hù)Gas/Gasseparation

氣體/氣體分離什么是綠油乙烯和其它石化生產(chǎn)裝置中所有C2、C3和C4加氫反應(yīng)器中形成的一種低聚物。綠油是一種含約90％脂肪族二烯烴和10％烯烴及烷烴的C4～C20不飽和反應(yīng)成分的混合物。什么是紅油堿洗塔脫硫堿洗塔上段水洗、中段濃堿液洗、下段稀堿液洗乙烯裂解氣中的重組份乳化、凝析累積在堿液中，最終隨廢堿液排出。因其顏色為紅色略帶黃色，所以叫紅油。紅油和廢堿液的比列為1：2TheApplicationsinEthylene

在乙烯中的應(yīng)用LiquidFeed–Naphtha(&GasolineOils)

液體給料—石腦油（和汽油）GasFeed–EthaneGas

氣體給料—乙烷氣體

GasorLiquidFeed

氣體或液體給料Furnace

熔爐1.TheFeedstock給料NaphthaFeed(Liquid)石腦油給料（液體）Particulates:MainlyIronoxidesduetocorrosion

微粒：腐蝕導(dǎo)致大部分是氧化鐵Ironisacokepromoter

鐵是焦炭促進(jìn)劑Saltwaterduetotransportinbarges

使用駁船運(yùn)輸帶來的鹽水Chlorideswillincreasethecorrosion

氯化物會增加腐蝕Sodiumwillincreasethecokeformation

鈉會加快焦炭形成EthaneFeed(Gas)乙烷給料（氣體）Particulates:Ironoxides

微粒：氧化鐵Solidsfromnaphthaproducedonsite現(xiàn)場生產(chǎn)石腦油中的固體Solidparticlesduetocorrosion(tanks,pipes)–Naphthacomingfromarefinerynextdoor

腐蝕導(dǎo)致的固體顆粒（油箱、管道）——

來自煉油廠隔壁的石腦油NaphthaPurification

石腦油純化 Removalofsolidsandsaltedwaterfromliquidfeedstocks

從液體給料中去除固體和鹽水ShippedNaphtha:Theremovalofsaltedwater

reducescorrosionandcoking

運(yùn)輸石腦油：去除鹽水可以降低腐蝕和焦化Naphthafromrefinery:1to3ppmwTSS

煉油廠的石腦油：1至3ppmwTSSTypicalsavings

典型節(jié)省furnace

maintenance

熔爐維護(hù)longerruns(oneplantreportedincreasedruntimeby50%)

運(yùn)行時間更長（據(jù)報道某個工廠的運(yùn)行時間增加了50%）protectionofflowmeters

保護(hù)流量計1.NaphthaPurificationtoProtectaCarbonBed

純化石腦油保護(hù)活性炭床Somesystemshavea“MercuryandArsenicRemovalSystem”

某些設(shè)備有一個“水銀和砷去除系統(tǒng)”Thiscarbonbedshouldbeprotectedoftypicalparticulatesfoundintheliquidnaphthastream

應(yīng)該對活性炭床進(jìn)行保護(hù)，避免液體石腦油流中的微粒對其造成污染10μmAbsoluteisTypicallySpecifiedbyCarbonBedManufacturersforProperProtection

10μm絕對值是由活性炭床制造商規(guī)定的，目的是為炭床提供適當(dāng)保護(hù)。1.Removalofsolidsandsaltedwaterfromliquidfeedstocks去除液體給料中的固體和鹽水PallProductstoUse使用中的頗爾產(chǎn)品ParticulateRemovalUltipleatHighFlow(LowTemp.)orProfileA/S(HighTemp.)微粒去除UltipleatHighFlow（低溫）或ProfileA/S（高溫）WaterremovalAquaSeporPhaseSepcoalescer水去除AquaSep或PhaseSep聚結(jié)過濾器PallInstallationsonNaphtha石腦油處理領(lǐng)域已安裝頗爾設(shè)備5installationsinWesternHemisphere

5個安裝在西半球3installationsinEurope

3個安裝在歐洲1inChina

1個在中國PhaseSep?Installation

EuropeanNaphthaCracker

PhaseSep?安裝歐洲石腦油裂解爐1.Removalofsolidsfromethanegas去除乙烷氣體中的固體PallProductstoUse使用中的頗爾產(chǎn)品MCC1401styleUltiporFilter

MCC1401種類Ultipor過濾器PallInstallationsonEthaneGas頗爾乙烷氣體的安裝3installationsworldwide–2inAsia,1inMiddleEast

全世界安裝了3套——2個在亞洲、1個在中東AsuccessinAustralia:在澳大利亞的一個成功案例：Pipe1500kmlong

管道長度1500kmGasfilterlifeis9-12monthsbeforechangeout

更換前氣體過濾器壽命為9-12個月2.FuelGaspurfication燃料氣體純化RemovalofParticlesandLiquidsfromBurnersGasFeed去除燃燒爐氣體給料中的微粒和液體CrackingFurnace

裂解熔爐SepraSolCoalescer

SepraSol聚結(jié)過濾器Feed

給料RegulationsrequiringreductionsintheNOxemissions:EN746-2

法規(guī)要求降低NOx排放：EN746-2LowandUltraLowNOxBurners

低NOx燃燒爐和超低NOx燃燒爐Pilotburners

點火燃燒爐MaintenanceandOperatingCosts

維護(hù)和運(yùn)行成本

2.BurnerProtection燃燒爐保護(hù)Hightemp.environmentincrackingfurnacespresentasevereenvironmentforburnerprotection

裂解熔爐內(nèi)的高溫環(huán)境為保護(hù)燃燒爐帶來嚴(yán)峻挑戰(zhàn)SchematicofanUltraLeanPremixburner超精益預(yù)混燃燒器原理圖

From“LowNoxBurnerMaintenanceinHighTemperature

Furnaces”,JohnZincAiChEMeeting,March2002

2.BurnerProtection燃燒爐保護(hù)

2.BurnerProtection:FuelTipOrificePlugging

燃燒爐的保護(hù)：燃油噴射孔堵塞Willreducethefiringcapacityofthefurnaceforthesameavailablefuelpressure

在相同燃油壓力下，燃燒爐點火性能降低Unevenflamepatterns

不規(guī)則的火焰模式Overheatingofburnercomponents

燃燒爐組件過熱Tipcoking,flameinstability

端口焦化、火焰不穩(wěn)定Burnertiporificescanbecomepluggedfrom…

燃燒爐噴嘴可能會被以下物質(zhì)堵塞：Particulatesinthefuellines:linescale,salts,dirt,mol.sievesfines

燃料管內(nèi)的微粒：管道污垢、鹽、污物、分子篩精細(xì)顆粒Hydrocarbonliquidscrackwhentheyencounterthehotsurfaceofthetip,leavingbehindcoke

碳?xì)浠衔镉龅巾敳繜岜砻鏁炎儯a(chǎn)生焦炭Pluggedtipsmustbecleanedquicklybeforemoreseriousmaintenanceproblemsdevelop,suchasflameimpingement

在更嚴(yán)重的維護(hù)問題（例如：火焰沖擊）發(fā)生前，必須盡快清洗堵塞噴嘴Liquidcontaminationisabletogetpastthede-mistersandKnock-Outdevicestomakeitallthewaytotheburnerbecausetheyareveryfinedroplets,withdiameters<5μm

液體污染物能夠穿過除霧器和分離罐裝置進(jìn)入燃燒爐，因為他們都是非常精細(xì)的油滴，直徑小于5μm。Onlysolids?Alsoliquids!

除了固體之外，還有液體！Liquidsmaycomefrom:

液體可能來自：Distillationcolumns

蒸餾塔Compressorlubricationoil

壓縮機(jī)潤滑油EthyleneProcess(greenoil…)

乙烯工藝（綠油…）Unsaturates/Heavycomponents

不飽和物/較重組分IncreasedBurnerEfficiency

提高燃燒爐效率MinimizedReplacementofNozzles

將噴嘴替換頻率降到最低ReducedMaintenanceandOperatingCosts

降低維護(hù)和運(yùn)行成本ElementLifehasbeen1YearintheField

濾材實際使用壽命已有1年UsePallSepraSolLiquid/GasCoalescerfor…

使用頗爾SepraSol液/氣聚結(jié)過濾器的好處：1.Removalofsolidsandliquidsfromfuelgasforprotectionofburnertips

去除燃料氣體內(nèi)的固體和液體，保護(hù)燃燒爐噴嘴PallProductstoUse

需要使用的頗爾產(chǎn)品RemovalofparticulatesandaerosolsinthefuelgasSepraSolLiquid/GasCoalescer

去除燃料氣體內(nèi)的微粒和氣溶膠SepraSol液/氣聚結(jié)過濾器Morethan60L/Gsystemsintheworldforburnerprotection.

世界上有超過60個L/G系統(tǒng)用來保護(hù)燃燒爐SepraSolusedonburnersinmanyindustriesincludingrefineriesandotherpetrochemicals;aqnywherecustomerhasacrackingfurnace.

燃燒爐上的SepraSol用于許多行業(yè)，包括煉油廠和其它石化行業(yè)；只要客戶擁有一個裂解熔爐就可以使用。Coalescerinstalledupstreamofthecontrolvalvetoprotectit

將聚結(jié)過濾器安裝在控制閥的上游對其進(jìn)行保護(hù)Pipingshouldbecleanedbeforeinstallation–thisisdoneduringashutdown

安裝前應(yīng)該清理管道——關(guān)機(jī)時完成PallServices

頗爾維修服務(wù)ReplacementwithStainlessSteelpiping

使用不銹鋼管道進(jìn)行替換RecommendationsforasuccessfulinstallationofaPallL/Gcoalescer

成功安裝頗爾L/G聚結(jié)過濾器的幾點建議UsePallMetallicBaskets

使用頗爾金屬濾筐

RemovalofParticlesfromQuenchOil

去除淬火油中的微粒Protectionofpumps

保護(hù)泵InstallationinBrazil

安裝在巴西

3.QuenchOilFiltration

3.淬火油過濾OilQuench

淬火油FuelOil

燃料油CrackedGas

裂解氣體GasfromFurnaces

熔爐氣體Purpose:

目的 RemovePy-GasfromQuenchWatertoa 20ppmlevel

去除驟冷水中的Py-Gas至20ppm等級-“OilandGreaseExtractionTechnique”

-“油和油脂提取技術(shù)” -EPAMethod413.2

-EPA方法413.2WaterQuenchTower

水淬塔WasteWater

廢水Oil/WaterSeparator

油/水分離器PyrolysisGasoline

裂解汽油PallPhaseSepSystem

頗爾PhaseSep系統(tǒng)PallAquaSepSystem

頗爾AquaSep系統(tǒng)4.QuenchWater:驟冷水：

RemovingPy-Gasfromwater去除水中的Py-GasWhereDoestheQuenchWaterGointheProcess?工藝中驟冷水去向何方？RecycledbacktotheQuenchWaterTower

回收至驟冷水塔WaterTreatment

水處理TotheDilutionSteamSystem(DSS)tomakesteam

至稀釋蒸汽系統(tǒng)（DSS）形成蒸汽

Clean

QuenchWater…清洗驟冷水MinimizesHeatExchangerCleaning

最大程度上減少熱交換器清洗IncreasesHeatExchangerEfficiency

提高熱交換器效率ReducesSteamUtilityCosts

降低蒸汽使用成本ReducesWasteWaterTreatmentCosts

降低廢水處理成本IncreasesBenzeneStripperEfficiency

提高苯氣提塔效率TubeSheet

管板INLET

入口ManHole

人孔PallLiquid/LiquidCoalescingunit:VesselandInternals

頗爾液/液聚結(jié)裝置：容器和內(nèi)部構(gòu)件SurfactantsarepresentintheQuenchWaterandPy-Gas

表面活性劑存在于驟冷水和Py-Gas中CorrosionInhibitors

腐蝕抑制劑ChemicalAdditives

化學(xué)添加劑SulfurCompounds

含硫化物CompressorWashOils

壓縮器清洗油WhyWillthePhaseSep?System

WorkEffectively?

PhaseSep?

系統(tǒng)為什么會有效運(yùn)行？EffectiveSeparationwithIFT’sasLowas1.0dyne/cm.

有效分離界面張力（IFT）低至1.0dyne/cm的液體。PhaseSepCoalescingElementswillnotDisarminthePresenceofSurfactants.

即使存在表面活性劑，PhaseSep聚結(jié)元件仍將發(fā)揮作用GlassFiberCartridgesWillDisarm.

玻璃纖維濾芯將失效Impactofsurfactantsoncoalescing

表面活性劑對聚結(jié)的影響Nosurfactant-coalescingislessdifficult

無表面活性劑存在-聚結(jié)就比較容易一些Liquid/LiquidCoalescersAlwaysNeedtobeProtectedwithaPre-ConditioningUnit

液/液聚結(jié)過濾器通常需要使用預(yù)處理元件進(jìn)行保護(hù)RemovesSolidstoProtectCoalescerElements

去除固體保護(hù)聚結(jié)過濾器元件EnablesSystemtoAchieve20ppm

系統(tǒng)能夠到達(dá)20ppmEnables12-24monthPhaseSep?LifePhaseSep?

壽命長達(dá)12-24月TotalSuspendedSolids(TSS)LevelsintheFieldRangefrom0.1-10ppm

現(xiàn)場總懸浮物（TSS）等級范圍為0.1-10ppmGasCrackerstypicallyhavemoresolidsthanaLiquidCracker.WemayneedtoevaluateanautomatedBackwashUnitfortheprefilter.

氣體裂解爐中的固體比液體裂解爐中多。我們可能需要為預(yù)過濾器評估自動反沖洗設(shè)備。Pre-CoalescenceoftheLiquids聚結(jié)工藝前的液體

PreconditioningElement預(yù)處理部件MCC1401E10010umEpocelintheMCC1401format

MCC1401格式下的10umEpocelLargerdiameter大直徑Greaterfilterarea大過濾面積Excellentchemicalandtemperaturecompatibility良好的化學(xué)相容性和耐溫性PallProfileA/S頗爾ProfileA/S過濾器

PPSConstruction

PPS結(jié)構(gòu)Depthfiltration深度過濾Excellentchemicalandtemperaturecompatibility良好的化學(xué)相容性和耐溫性MetalbasketsorDFTStringwoundsasprefilterstopreconditioningelements

金屬濾筐或DFTStringwounds作為預(yù)處理裝置的預(yù)過濾器PhaseSep?Installation

PreconditioningElements

PhaseSep?

安裝預(yù)處理裝置PhaseSep?Installation

ElementInstallation

PhaseSep?濾材安裝PhaseSep?Installation

HousingClosure

PhaseSep?濾殼端蓋4.Py-gasremovalfromQuenchWater去除驟冷水中的Py-gasPallProductstoUse使用中的頗爾產(chǎn)品BulkprefilterMetalBasketsofDFT制劑預(yù)過濾器DFT金屬濾筐PreconditioningfilterEpocelMCC1401預(yù)處理過濾器EpocelMCC1401Py-gasremovalfromwaterPhaseSepcoalescer去除水中的Py-gasPhaseSep聚結(jié)過濾器PallInstallationsonQuenchWater頗爾驟冷水安裝22installationsglobally全球共安裝了22處Severalnewprojectsbeingbuilt某些新項目正在建設(shè)過程中Pallisrecognizedasastrongplayerinthisapplication.

頗爾被認(rèn)為是此類應(yīng)用產(chǎn)品領(lǐng)域內(nèi)最具有競爭力的企業(yè)CompetitiveTechnologies具有競爭力的技術(shù)DispersedOilExtractorsforGasCrackers

氣體裂解爐用分散油提取器MoreCapitalIntensivethanPallUnit

與頗爾設(shè)備相比資金更密集Unreliable,InconsistentPerformance

性能不可靠、不穩(wěn)定ConventionalGlassFiberCartridgesforLiquidCrackers

液體裂解爐用傳統(tǒng)玻璃纖維濾芯Disarmwithin4-6weeksofOperation

運(yùn)行4-6周內(nèi)就報廢UnreliablePerformance

性能不可靠Napthachimie–Lavera,FranceCostJustification

Napthachimie–Lavera,法國成本分析StripperSteamCost–OldSystem

汽提塔蒸汽成本——老系統(tǒng)StripperSteamCost–PallSystem

汽提塔蒸汽成本——頗爾系統(tǒng)WasteTreatmentVolumeReductionSavings

減少廢物處理量所節(jié)省的成本TotalSavings$/Year

總節(jié)省成本$/年InitialCost

初始成本$239,000/Yr.ofExcessLPSteam

ExcessLP蒸汽：$239,000/年0ExcessLPSteam

ExcessLP蒸汽：0$10,900/Year

$10,900/年$307,100/Year

$307,100/

年$78K78,000美元PallSystemPay-Back:4Months頗爾設(shè)備投資回報時間：4個月ThaiOlefinsCorporation–Thailand

CostJustification

ThaiOlefinsCorporation（泰國石蠟公司）–

泰國成本分析CoalescerMaintenance–OldSystem

聚結(jié)過濾器維護(hù)——老系統(tǒng)CoalescerMaintenance–PallSystem

聚結(jié)過濾器維護(hù)——頗爾系統(tǒng)Re-BoilerMaintenance–OldSystem

再沸器維護(hù)——老系統(tǒng) Re-BoilerMaintenance–PallSystem

再沸器維護(hù)——頗爾系統(tǒng)StripperSteamCost–OldSystem

汽提塔蒸汽成本——老系統(tǒng)StripperSteamCost–PallSystem

汽提塔蒸汽成本——頗爾系統(tǒng)WasteTreatmentVolumeReductionSavings

廢物處理量減少所節(jié)省的成本TotalSavings$/Year

總節(jié)省成本$/

年InitialCost

創(chuàng)辦成本Every2months

每2個月9+months

9個月以上$5,500/Year

$5,500/年0

0$261,000/Yr.-ExcessLPSteam

ExcessLP蒸汽-$261,000/年ExcessLPSteam

ExcessLP蒸汽-0$10,000/Year

$10,000/年$276,500/Year

$276,500/

年$249K

$249KPallSystemPay-Back:11Months

頗爾設(shè)備投資回報期：11個月WaterQualitySpecifications水質(zhì)質(zhì)量標(biāo)準(zhǔn)PhaseSep?EffluentQuality

PhaseSep?

排出液質(zhì)量VisuallyClear目視清澈Usualclaimandrequirementis30ppmoffreeoilinwater

通常要求和規(guī)定水中游離油30ppmHydrocarbonConcentrationsto10ppmandLowerHaveBeenProvenintheField

經(jīng)驗證現(xiàn)場碳?xì)浠衔餄舛葹?0ppm以及更低Newtestingin2006and2007torewriteclaimsbasedonnewtestingguidelines

根據(jù)新的測試準(zhǔn)則，在2006年和2007年做新測試改寫要求INLETOUTLETPallPhaseSepsystemtoRemovePy-GasfromQuenchWater–Case1

去除驟冷水中Py-Gas的頗爾PhaseSep系統(tǒng)——案例1Inlet:Upto2%ofliquidHC

入口：高達(dá)液體HC的2%Outlet:<20ppm

出口：<20ppmPallPhaseSepsystemtoRemove

Py-GasfromQuenchWater–Case2

去除驟冷水中的Py-Gas的頗爾PhaseSep系統(tǒng)——案例2Py-GasfromWater

水中的Py-GasPallPhaseSepsystemtoRemove

Py-GasfromQuenchWater–Case3

去除驟冷水中的Py-Gas的頗爾PhaseSep系統(tǒng)——案例3Py-GasfromWater

水中的Py-Gas

PurifiedWatertoBenzeneStripper&SteamSystem

純化后的水到達(dá)吹苯塔和蒸汽系統(tǒng)PallAquaSepSystem

頗爾AquaSep系統(tǒng)RemovalofWaterfromPy-Gas

去除Py-Gas中的水Application#4,cont’d

應(yīng)用編號：4，續(xù)PurifiedPy-Gas

純化后的Py-GasPyrolysisGasolinewithsomewater

帶有水的裂解汽油PallPhaseSepSystem頗爾PhaseSep系統(tǒng)WaterwithPy-Gas

水和Py-GasSettlingTank

沉降槽WaterfromQuenchTower

來自驟冷塔的水Py-Gas

Water

水Py-gasremovedfromthewaterisasalableproduct

從水中去除的Py-gas是可以出售的產(chǎn)品PurposeistoSellaHigherPurityProduct

目的是為了出售一種高純度產(chǎn)品RemovalofWaterdowntolessthan15ppm

去除水降至15ppm以下PallCorporationhasInstalledDozensofLiquidLiquidCoalescersforWaterfromHydrocarbonStreams

頗爾公司已經(jīng)安裝了幾十個碳?xì)浠衔镎羝械乃靡阂壕劢Y(jié)過濾器UsetheAquaSep?VerticalConfiguration

使用AquaSep?

垂直配置RemovalofWaterfromPyrolysisGasoline

去除裂解汽油中的水WaterQuench

水淬CompressorStages

壓縮機(jī)級CrackedGas

裂解氣體5.CompressorProtection壓縮機(jī)保護(hù)RemovalofParticlesandwaterinlubeoilusingaPallPurifier

使用頗爾純化器去除潤滑油中的水和顆粒Application#5

CompressorProtection

應(yīng)用編號：5

壓縮機(jī)保護(hù)Removalofaerosolssignificantlyaffectstheperformanceofacompressor

去除氣溶膠會顯著影響壓縮機(jī)性能TypesofCompressorsaffected

受影響的壓縮機(jī)類型Reciprocating

往復(fù)式Centrifugal

離心式WaterQuenchTower

急冷水塔CompressorStages

壓縮機(jī)級AmineSystem

胺類系統(tǒng)

GasDryer

氣體干燥器SepraSolCoalescer

SepraSol聚結(jié)過濾器SepraSolCoalescer

SepraSol聚結(jié)過濾器PhaseSepCoalescer

PhaseSep聚結(jié)過濾器ParticleFilter

顆粒過濾器5.Compressorprotection

5.壓縮機(jī)保護(hù)Compressionstages

壓縮機(jī)級Removalofwaterincondensategasoline

去除凝析汽油中的水Removalofliquidhydrocarbonsinwaterusedforwashing

去除清洗水中的液體碳?xì)浠衔颬rotectionofcompressorsbyfilteringhydraulicfluids

過濾液壓油保護(hù)壓縮機(jī)UsePurifiersandlubeoilfilters

使用純化器和潤滑油過濾器Removeparticlesandwaterfromoil

去除油中的顆粒和水Protectionofcompressorinternals

保護(hù)壓縮機(jī)內(nèi)部構(gòu)造Avoidshutdownsandleaks

避免停機(jī)和泄漏PallServices:rentalofunits,totalfluidconditioning

頗爾服務(wù)：設(shè)備租賃、整體液體處理PALLPURIFIERFORLUBEOILSYSTEMS

潤滑油系統(tǒng)用頗爾純化器WaterremovalwithPallpurifier

使用頗爾純化器脫水Removalof

去除100%offreewaterand90%ofdissolvedwater

100%的游離水和90%的溶解水100%offreeandentrainedgasesand80%ofdissolvedgases

100%的游離氣體和夾帶氣體以及80%的溶解氣體UltiporIIIremovesparticlesofseveralmicronranges

UltiporIII去除多個微米范圍的微粒PALLPURIFIERFORLUBEOILSYSTEMS

潤滑油系統(tǒng)用頗爾純化器Watercanenterasysteminmanyways水能夠以許多方式進(jìn)入系統(tǒng)Condensationofair空氣凝結(jié)Seepagethroughaccesspanels,damagedseals,reservoircovers

從接觸面板、受損密封件、蓄水池外殼處滲透Leakagefromwater-cooledheatexchangers

從水冷卻熱交換器處泄漏Contaminatedmake-upfluid

受污染的補(bǔ)充液PALLPURIFIERFORLUBEOILSYSTEMS

潤滑油系統(tǒng)用頗爾純化器Corrosion腐蝕50%bearinglifereduction

軸承壽命減少50%Surfacefinishdamageincludingetching

表面拋光損壞，包括蝕刻Acceleratedsurfacefatigue

加速表面老化Rustandcorrosionpits

生銹和腐蝕坑Watercandamageasysteminmanyways

水能夠以許多方式損壞系統(tǒng)Fluidbreakdown

流體分離Precipitation

沉淀Fluidoxidation

流體氧化Reductioninlubricationfilmthickness

潤滑漆厚度減少5.CompressorProtection:LubeOilPurifiers

5.壓縮機(jī)保護(hù)：潤滑油純化器SpecificOperationDataonSteamcrackers

蒸汽裂解裝置的具體運(yùn)行數(shù)據(jù)Gasconcentrationintheoilorvacuumairmaybecritical

油中或真空中的氣體濃度可能會很重要Somecustomersusenitrogeninsteadofambientair(Germany,France,…)

某些客戶使用氮氣取代大氣（德國、法國）CommonMax.

Vol.GasConcentrations

正常最大體積的氣體濃度Propylene丙烯 1.5%Cyclopropane環(huán)丙烷 1.5%Hydrogen氫 2.5%HydrogenCyanide氫氰酸 3.5%HydrogenSulphur氫硫 3.5%Ethylene乙烯 2.0%DimethyleEther二甲醚 2.0%Propane丙烷 1.5%EthyleneOxide環(huán)氧乙烷 2.0%Acetylene 乙炔 1.5%Basedonanoperatingvacuumof-0.9barg

基于-0.9barg的運(yùn)行真空PurifierServices:

純化器維修：CleanlinessAUDIT&CONSULTING

清潔度審計和咨詢LubeoilonaProcessGasCompressorofaSteamcracker

蒸汽裂解裝置的工藝氣體壓縮機(jī)上的潤滑油Someexamplesofproblems:某些問題實例：Temperatureincreaseupto100°Cinbearings

軸承溫度高達(dá)100°Cfreewaterinoil

油中的游離水bearinggapdecrease

軸承間隙減少Customertechnicalstaff(maintenance&process)consultsPallsalespeopleforaconcretesolutiontofixthisrunningproblem

有關(guān)此運(yùn)行問題的具體解決方案，客戶技術(shù)人員（維護(hù)和工藝）可以咨詢頗爾銷售人員FirstApproach=

Auditing&consultingofProcessGasCompressorofthesteamcrackeronlube&turbinecontroloilcircuit

第一種方法=潤滑和渦輪控制油路上蒸汽裂解裝置的工藝氣體壓縮機(jī)的審計和咨詢CompressorProtection:LubeOilPurifiers

壓縮機(jī)保護(hù)：潤滑油純化器PurifierSuccessinFranceinstalledin2000

2000年安裝在法國的純化器的成功Maingoalwastodecreasethegasconcentrationintheoil

主要目標(biāo)是為降低油中的氣體濃度Pallpurifierinstalledontanksof4000and8000litersofhydraulicfluid

安裝在4000和8000升液壓油油箱上的頗爾純化器Competition:Centrifuge

競爭者：離心機(jī)Benefits:

好處：lowmaintenancecomparedtothecentrifuge

與離心機(jī)相比維護(hù)成本低extractionofH2Sgaspresentintheirfluids

提取液體中存在的H2S氣體

thiswouldbeimpossiblewithcentrifuge

離心機(jī)無法做到這一點Watermeasurementsalways<0.1%

水測量經(jīng)常<0.1%

P/N:HXP070500KPAYG19

CompressorProtection:LubeOilPurifiers

壓縮機(jī)保護(hù)：潤滑油純化器PurifierSuccessinSpaininstalled

安裝在西班牙的純化器的成功2Pallpurifiersinstalledononeethylenecracker

1個乙烯裂解爐上安裝了2個頗爾純化器Oneisfixedandisusedtocleanuptheoiltankforthemainsteamcrakercompressor

1個是固定的用于清潔主蒸汽裂解爐壓縮機(jī)的油箱Oneisnotfixed(portable)andisusedtocleanupthedifferentoiltankstheyhavefordifferentoillines.

1個是不固定的（可攜帶）可用于清潔不同油路的不同油箱Benefits

好處Protectionofthesmallnon-returnvalves

保護(hù)小號單向閥Nomoreshutdownofthemachineduetopowerpackfailures

不再因為電源組故障導(dǎo)致機(jī)器關(guān)機(jī)MobileLaboratoryPALL移動實驗室

ScientificandLaboratoryServices頗爾科學(xué)和實驗室服務(wù)S.L.S.CONDENSATES

凝結(jié)物CrackedGas

裂解氣體6.LightHCcondensatesCoalescer輕HC凝結(jié)聚結(jié)過濾器Removalofwaterinliquidhydrocarboncondensates

去除液體碳?xì)浠衔锬Y(jié)物中的水Protectionofmolecularsievesbeds

分子篩床的保護(hù)Lightgasolinegoingtoaromaticunits,protectionofdistillationtowers

輕汽油進(jìn)入芳香環(huán)，保護(hù)蒸餾塔Hydrogenationcatalysthighlysensitivetowater

氫化催化劑對水高度敏感Waterconcentrationcanbeashighas5%水濃度可能高達(dá)5%Gasolinecondensesaftercompressionstages

壓縮階段后汽油凝結(jié)LowIFTascausticwashisupstream(<5dyne/cm)堿洗為上游時低IFT（<5dyne/cm）6.WhyremovewaterfromtheHCCondensate?

6.為什么要去除HC凝結(jié)物中的水？PallProductstoUse使用中的頗爾產(chǎn)品ParticulateRemovalUltipleatHighFlow微粒去除UltipleatHighFlowWaterremovalAquaSeporPhaseSepcoalescer脫水AquaSep或PhaseSep聚結(jié)過濾器(upstreamordownstreamcausticwashingcolumn（上游或下游堿洗塔）10PallInstallationsgloballyonCondensates全球共安裝了10處頗爾凝結(jié)物裝置5installationsinAsia亞洲安裝了5處3installationsintheWH西半球有3處1intheMiddle

East中東1處1inEurope歐洲1處6.LightHCcondensatesCoalescer低HC凝結(jié)物聚結(jié)過濾器WATER

水CrackedGas

裂解氣體6.Continued:WashingWaterCoalescer續(xù)：洗水聚結(jié)過濾器RemovalofliquidHCinwaterforprotectionofwatertreatmentstation

去除水中的液體HC保護(hù)水處理站DiscontinuousWaterInjection

連續(xù)注入水PallProductstoUse

需要使用的頗爾產(chǎn)品ParticulateRemovalUltipleatHighFlow

微粒去除UltipleatHighFlow(HFU640GF100)HCremovalPhaseSepcoalescer

HC去除PhaseSep聚結(jié)過濾器2PallInstallationsgloballyonHCfromwashwater

全球洗水中的HC的頗爾裝置6.Continued:WashingWaterCoalescer續(xù)：洗水聚結(jié)過濾器Hydrogenation

氫化作用7.HydrogenationCatalystProtection氫化催化劑保護(hù)Gasoline

汽油ToBTXunit

進(jìn)入BTX單元CausticWaterremovalfromGasoline

去除汽油中的堿水PallAquaSepsystem:Verticaldesign

頗爾AquaSep系統(tǒng)：垂直設(shè)計或

PallPhaseSepsystem:Horizontaldesign

頗爾PhaseSep系統(tǒng)：水平設(shè)計IFTrange=5to15dyne/cm

IFT范圍=5至15dyne/cm7.HydrogenationCatalystProtection氫化催化劑保護(hù)PallProductstoUse使用中的頗爾產(chǎn)品ParticulateRemovalUltipleatHighFlow微粒去除UltipleatHighFlowWaterremovalAquaSeporPhaseSepcoalescer脫水AquaSep或PhaseSep聚結(jié)過濾器8PallInstallationsgloballyonHydrogenationCatalystProtection

全球氫化催化劑保護(hù)的頗爾裝置4inAsia亞洲4個2inEurope歐洲2個1intheMiddleEast中東1個1inWesternHemisphere(Chile-methanol-waterfromC3)

西半球1個（智利-甲醇-來自C3的水）Application應(yīng)用編號8

RemovalofRedOilfromSpentCaustic去除廢堿中的紅油CrackedGas

裂解氣體Caustic

堿CausticSolution

堿溶液Caustic/gasolineSeparator

堿/汽油分離器

8Application#8應(yīng)用編號：8

RemovalofRedOilfromSpentCaustic去除廢堿中的紅油PallPhaseSepSystem

頗爾PhaseSep系統(tǒng)KnockoutDrum

分離罐Oxidizer

氧化劑ToprotectWetAirOxidizerorwatertreatmentunit

欲保護(hù)濕空氣氧化劑或水處理設(shè)備BetteryieldontheWAO

高產(chǎn)量WAOLessdischarge

低排放Costofincineration

焚化成本Application#8應(yīng)用編號：8

RemovalofRedOilfromSpentCaustic去除廢堿中的紅油WetAirOxidizerProtection

濕空氣氧化劑保護(hù)KeeptheOxidizerRunningMoreEfficiently

使得氧化劑運(yùn)行更高效ProtectHeatExchangerSurfacesFromRedOilCoating

防止熱交換器表面接觸紅油涂層TestinghasShownThatWeCanAchieveLowerThan50ppmRedoilingas

測試表明我們可以到達(dá)比氣體內(nèi)紅油50ppm更低的水平InletConcentrationsasHighas5%

入口濃度高達(dá)5%MayNeed2VesselsinSeriesifoilloadingishigh

如果裝油高可能需要一系列2個容器MayHaveHighSolidsLoading

可能需要高固體加載10-18ppmhasBeenSeenintheField

現(xiàn)場已經(jīng)看到了10-18ppmApplication#8應(yīng)用編號：8

RemovalofRedOilfromSpentCaustic去除廢堿中的紅油CompetitiveTechnologies

競爭技術(shù)KnockOutPots

分離罐ConventionalGlassFiberCoalescers

普通的玻璃纖維聚結(jié)過濾器Problems:

問題：UnabletoHandleProcessUpsets

無法處理工藝干擾LowEfficiencies

效率低Application#8應(yīng)用編號：8

RemovalofRedOilfromSpentCaustic去除廢堿中的紅油頗爾液/液聚結(jié)過濾器入口頗爾液/液聚結(jié)過濾器出口凝析油Dryer干燥器109ColdBox

冷箱H2Application#9&10:應(yīng)用編號：#9&10:

MolecularSieveProtection分子篩保護(hù)Purpose:ExtendMol.SeiveBedLife

目的：延長分子篩床壽命

(Newbed$50-$75K)（新床$50-$75K）

PallSystemAverageCost:$70-$100K頗爾系統(tǒng)平均成本：$70-$100KOptimizedColdSectionTreatment

MolecularSieveDryer

Protection

優(yōu)化的冷區(qū)處理分子篩干燥器保護(hù)Benefits:好處：ReduceUtilityCosts

降低使用成本IncreaseEfficiencyofMolecularSieve

提高分子篩效率LongerDesiccantLife

干燥劑使用壽命更長LessRegenerationofDesiccantnecessary

干燥劑無需再生OptimizedColdSectionTreatment

MolecularSieveDryerProtection

優(yōu)化的冷區(qū)處理

分子篩干燥器保護(hù)TypicalAerosolsDownstrea