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1、化學品安全技術(shù)說明書Chemicals safety specifications第一部分 化學品及企業(yè)標識Part 1 Chemical product and company identification化學品中文名:液體復合熱穩(wěn)定劑Chemical Name: Liquid compound heat stabilizer化學品英文名:Liquid compound heat stabilizer for PVCChemical Name: Liquid compound heat stabilizer for PVC生產(chǎn)企業(yè)名稱:浙江海普頓新材料有限公司Manufacturer Nam

2、e: Zhejiang Haipudun, New Material co., LTD地址:浙江省杭州市余杭區(qū)良渚鎮(zhèn)海虹科技工業(yè)園Address: Haihong science and technology industrial park, Liangzhu Town Yuhang District, Hangzhou city, Zhejiang province郵編:311113 傳真號碼:86-571-88770702POST CODE: 311113 Fax No. 86-571-88770702企業(yè)應急電話:86-571-88772700Enterprise emergency c

3、all: 86-571-88772700電子郵件地址:himptonEmail:himpton生效日期:2010年12月1日Effective date: December 1, 2010第二部分 成分/組成信息Part 2  Composition/Information on Ingredients純品× 混合物Pure material Compound有害物成分濃度CAS No.Hazards componentConcentration異辛酸鋇鹽5%-15%93843-12-0異辛酸鋅鹽5%-10%136-53-8油酸鋇鹽10%-30%591-65-1油酸鋅鹽5%

4、-10%557-07-3第三部分 危險性概述Part 2 Hazards Identification危險性類別:低毒類物質(zhì)。Risk categories: Low toxicity.侵入途徑:吸入、食入、皮膚接觸。Invasive ways: Inhalation, Eating, and Skin contact.健康危害:這類化合物進入人體后可能引起中毒。Health hazard: The kind of compounds entering to the human body can cause poisoning.環(huán)境危害:大量進入環(huán)境可引起污染。Environment risk

5、s: Pollution can be caused by a large number of harmful substances which is entering into the environment.燃爆危險:不屬易燃類危險物品。Combustion hazard: Not inflammable dangerous goods.第四部分 急 救 措 施Part 4 First aid measures皮膚接觸:脫去受污染的衣著,用肥皂清洗皮膚數(shù)次,如有不適,立即就醫(yī)。Skin contact: Removing contaminated clothing , washing sk

6、in with soap and water several times, if you are uncomfortable, please go to a doctor immediately.眼睛接觸:提起眼瞼,用大量清水沖洗后就醫(yī)。Eye contact: Lifting up eyelid, flushing with plenty of water before see a doctor.吸入:迅速撤離現(xiàn)場到空氣新鮮處;如呼吸停止,進行人工呼吸;如呼吸困難,給輸氧,立即就醫(yī)。Inhalation: Quickly evacuated from the scene to fresh a

7、ir; if breathing stops, try mouth-to-mouth resuscitation; Difficulty in breathing, using oxygen therapy, see a doctor immediately.食入:立即就醫(yī)。Ingestion: please see a doctor.第五部分 消 防 措 施Part 5 Fire safety measures 危險特性:遇明火、高熱可燃。與氧化劑可發(fā)生反應。受高熱分解放出有毒的氣體。其蒸氣比空氣重,能在較低處擴散到相當遠的地方,遇火源會著火回燃。若遇高熱,容器內(nèi)壓增大,有開裂和爆炸的危險。

8、Hazardous characteristic: Case of flame, high fever combustible. Antioxidant reaction. Letting out poisonous gases with high thermal decomposition . Its vapor is heavier than air, which can spread in the low position to a very far place, fire will fire back to combustion.If encounter high fever, con

9、tainer pressure increase, is in danger of cracking and explosion.有害燃燒產(chǎn)物:一氧化碳、二氧化碳。Hazardous combustion products: carbon monoxide, carbon dioxide.滅火方法:消防人員須佩戴防毒面具、穿全身消防服,在上風向滅火。盡可能將容器從火場移至空曠處。噴水保持火場容器冷卻,直至滅火結(jié)束。處在火場中的容器若已變色或從安全泄壓裝置中產(chǎn)生聲音,必須馬上撤離。滅火劑:霧狀水、泡沫、干粉、二氧化碳、砂土。Fire extinguishing methods: firefigh

10、ters must be wearing a gas mask, wearing the whole body fire suit, fire should be extincted in the direction of the wind fire. Remove the container from fire field to a open spaces as much as possible. Water spraying keeps fire containers cooling till the end of fire. If the container has been in a

11、fire discoloration or generate sound from the safety relief devices, you must evacuate immediately. Agent: water fog, foam, dry powder, carbon dioxide, sandy soil.第六部分 泄漏應急處理Part 6 Emergency equipments for leakage應急處理: 迅速撤離泄漏污染區(qū)人員至安全區(qū),并進行隔離,嚴格限制出入。切斷火源。建議應急處理人員戴自給式呼吸器,穿防毒服。不要直接接觸泄漏物。盡

12、可能切斷泄漏源。若是液體,防止流入下水道、排洪溝等限制性空間。用砂土、蛭石或其它惰性材料吸收。若大量泄漏,構(gòu)筑圍堤或挖坑收容。用泵轉(zhuǎn)移至槽車或?qū)S檬占鲀?nèi),回收或運至廢物處理場所處置。若是固體,用潔凈的鏟子收集于干燥、潔凈、有蓋的容器中。Emergency treatment: Personnel should leave quickly from leak contaminated area to safe areas, keep staff isolation and restrict access to the fire area .Cut off the fire. Recommend

13、ed that emergency-treatment personnel should wear self-contained breathing apparatus and protective clothing. Don't contact with the leakage directly. Cut off the leak source as soon as possible. Preventing liquid flowing into the sewer, ditches that owns restricted space. Absorbing with sand, v

14、ermiculite, or other inert materials.If a large number of leakage, constructing dike to dig a hole or asylum. Pump to tank lorry or dedicated collector, recycling or shipped to the disposal of waste places. If it is solid, with clean shovel collected in dry, clean, covered container.第七部分 操作處置與儲存Part

15、 7 Operation treatment and storage操作注意事項:密閉操作,局部排風。防止煙霧或粉塵泄漏到工作場所空氣中。操作人員必須經(jīng)過專門培訓,嚴格遵守操作規(guī)程。建議操作人員佩戴過濾式防毒面具(半面罩),戴化學安全防護眼鏡,穿防毒物滲透工作服,戴乳膠手套。遠離火種、熱源,工作場所嚴禁吸煙。使用防爆型的通風系統(tǒng)和設(shè)備。在清除液體和蒸氣前不能進行焊接、切割等作業(yè)。避免產(chǎn)生蒸氣或粉塵。避免與氧化劑接觸。配備相應品種和數(shù)量的消防器材及泄漏應急處理設(shè)備。倒空的容器可能殘留有害物。Operation note: airtight operation, local exhaust. To

16、 prevent the smoke or dust leakage in the air of workplace. Operators must receive special training, strictly abide by the operation procedures. Suggest operators wearing filter type gas mask (half mask, wearing chemical safety protective glasses, wearing gas permeability overalls, wear latex gloves

17、. Away from fire and heat source, the workplace smoking is strictly prohibited. Using explosion-proof ventilation systems and equipment. In front of the clear liquid and vapor , welding ,cutting and other operations are forbidded, Avoid to produce steam or dust. Avoid contacting with the oxidant. Eq

18、uipped with corresponding varieties and a number of fire equipment and spill contingency processing equipment. The remains of Hazardous materials is inside empty containers.The remains of hazardous materials is inside empty containers.儲存注意事項:儲存于陰涼、通風的庫房。遠離火種、熱源。防止陽光直射。保持容器密封。應與氧化劑、食用化學品分開存放,切忌混儲。配備相

19、應品種和數(shù)量的消防器材。儲區(qū)應備有泄漏應急處理設(shè)備和合適的收容材料。Storage precautions: stored in a cool, ventilated warehouse. Keep away from fire and heat sources. Prevent from direct sunlight. Keep container sealed. They Should be stored separately with oxidant, edible chemicals, avoid by all means is mixed with reservoir. Equip

20、ped with corresponding varieties and a number of fire equipment. Storage area should be equipped with emergency treatment equipment and suitable for resettlement material.第八部分 接觸控制/個體防護Part 8 Exposure controls/Personal protection最高容許濃度:國內(nèi)尚無此標準。The maximum allowable concentration: there is no this st

21、andard in domestic.工程控制:作業(yè)環(huán)境加強強制通風換氣,作業(yè)人員穿戴好勞保用品,遵守操作規(guī)程。Engineering control: strengthen the working environment to forced ventilation, operation personnel should wear labor insurance supplies and comply with the operating rules.呼吸系統(tǒng)防護:空氣中濃度較高時,應該佩戴過濾式防毒面具(半面罩)。緊急事態(tài)搶救或逃生時,建議佩戴空氣呼吸器。Respiratory protec

22、tion: when its concentration is higher in the air, the filter type gas mask (half mask should be worn. Emergency rescue or escape, it is suggested that personnel should wear air breathing apparatus.眼睛防護:戴化學安全防護眼鏡。Eye protection: wear chemical safety goggles.身體防護:穿防毒物滲透工作服。Body protection: Wear prote

23、ctive overalls on infiltration.手防護:戴乳膠手套。Hand protection: wear latex gloves.其它防護:工作場所禁止吸煙、進食和飲水,飯前要洗手。工作完畢,淋浴更衣。保持良好的衛(wèi)生習慣。 Other protective measure: eating, drinking and smoking are forbidden in the workplace, to wash your hands before meals. Shower change clothes should be done after work, .To

24、 maintain good health habits.第九部分 理 化 特 性Part 9 Physical and chemical properties外觀與性狀:微黃色至紅棕色透明液體Appearance and properties: from light yellow to red brown transparent liquid分子式:分子量: Molecular formulaDaltonpH值:無意義熔點():無資料PH Value: NonsenseMelting point: no data相對密度(水1):0.96-0.98沸點():無資

25、料Relative density(Water=1:0.96-0.98 Boiling point():no data相對蒸氣密度(空氣1):無資料辛醇/水分配系數(shù):無資料Relative vapour density(air=1: no dataOctanolwater partition constant: no data閃點():>80引燃溫度():無資料Flashing point: ():>80Ignition temperature():no data爆炸上限(V/V):無資料爆炸下限(V/V):無資料Upper explosive

26、0;limit(V/V):no dataLower explosive limit(V/V):no data燃燒熱(kJ/mol):無資料臨界溫度():無資料 Combustion heat(kJ/mol):no dataCritical temperature():no data臨界壓力(MPa):無資料Critical pressure(MPa):no data溶解性:不溶于水,可溶于丙酮等一般有機溶劑Solubility: insoluble in water, soluble in acetone, such as general or

27、ganic solvents主要用途:聚氯乙烯(PVC)熱穩(wěn)定劑Main Usage: polyvinyl chloride (PVC heat stabilizers第十部分 穩(wěn)定性和反應活性Part 10 Stability and Reactivity穩(wěn)定性:在250以下比較穩(wěn)定,高于250會蒸發(fā)和分解,產(chǎn)生有毒氣體。Stability: stable under 250 , and above 250 will evaporate and decomposition, and generate toxic gases.禁配物:強氧化劑、強酸。Prohibited content: st

28、rong oxidant, Strong acid避免接觸的條件: 避免受高熱烘烤,避免包裝破損,不得與酸性物品共儲運。Conditions of contact avoiding: avoid high temperature baking, avoid packing damage, no storage and transportation with acid goods.聚合危害:不聚合。Aggregate hazard: no aggregation分解產(chǎn)物:不分解。Breakdown products: no decomposition.第十一部分 毒理學資料Part 11 Tox

29、icology data急性毒性:無資料。Acute toxicity: no data.刺激性:無資料。Stimulus: no data.亞急性和慢性毒性:無資料。Subacute and chronic toxicity: no data.刺激性:無。Stimulus: no.致敏性:無。Allergenic: no.致突變性:無。Respectively: no.致畸性:無。Teratogenicity: no.致癌性:無。Carcinogenicity: no.第十二部分 生態(tài)學資料Part 12 Information ecology生態(tài)毒性:無資料。Ecological toxi

30、city: no data.生物降解性:無資料。Biodegradability: no data.非生物降解性:無資料。The biodegradability: no data.其它有害作用:該物質(zhì)對環(huán)境有危害,建議不要讓其進入環(huán)境。Other harmful effects: this material has harm to the environment, suggested that you should not go into such environment.第十三部分 廢 棄 處 置Part 13 Waste disposal廢棄物性質(zhì):無資料。Waste propertie

31、s: no data.廢棄處置方法:處置前應參閱國家和地方有關(guān)法規(guī)。建議用控制焚燒法處置,排出氣體用水吸收后進污水處理系統(tǒng)。Waste disposal method: you shall refer to the state and local relevant laws and regulations before disposal. Use Incineration controlling to disposal, discharged gas should be absorpted into sewage treatment system廢棄注意事項:操作人員穿戴必要的防護裝備。Not

32、e: waste operators should wear necessary protective equipment.第十四部分 運 輸 信 息Part 14 Transportation information危險貨物編號:無資料。Serial no. of hazard goods: no dataUN編號:無資料。UN No. no data.包裝標志:每個包裝上均必須有合格證。Packaging mark: Each package must be with a certificate of approval.包裝類別:3類Packaging categories: 3 classes包裝方法:200kg、1000kg塑桶包裝。Packing method: packaging with 200 kg, 1000 kg plastic barrels .運輸注意事項:運輸前應先檢查包裝容器是否完整、密封,運輸

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