GSP氣化爐工藝介紹

IntroductiontoFUTUREENERGYGmbHandGSPGasificationTechnology未來能源股份有限公司和GSP氣化技術(shù)的介紹September,20052005年10月Tableofcontents目錄IntroductiontoFUTUREENERGYGmbH

未來能源股份有限公司介紹2.DescriptionofGSPgasificationtechnologyGSP氣化技術(shù)描述3.IndustrialapplicationsofGSPtechnologyGSP技術(shù)的工業(yè)應(yīng)用4.Comparisonwithothersimilartechnologies

與其他類似技術(shù)的比較燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口IntroductiontoFUTUREENERGYGmbH

未來能源股份有限公司的介紹1.1Outlineofthecompany

公司概況

1.2Backgroundofthecompany

公司背景1.3Categoryoftechnicalactivities

科技活動(dòng)動(dòng)態(tài)1.4Developmentstrategyinfuture

未來發(fā)展戰(zhàn)略燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口Founded創(chuàng)建: Foundedin2002創(chuàng)建于2002年

(fromformerBabcockBorsigPowerGmbH前身是BabcockBorsig電力股份有限公司)Owner擁有者: SustecHoldingAG,Switzerland瑞士SustecHolding公司

Managingdirector總經(jīng)理: DirkVolkmannTechnicalstaffs: 15engineers工程師技術(shù)人員 5technicians技術(shù)員Testfacilities:-3MWentrained-flowgasifier(coolingwall)3MW氣流床氣化爐（水冷壁）試驗(yàn)工廠-5MWentrained-flowgasifier(coolingscreen)5MW氣流床氣化爐（水冷格柵）-Pulverizedfueldosingandfeedingsystem粉狀燃料定量給料系統(tǒng)-Pyrolysisunitespeciallyforbiomass熱解裝置，尤其對生物體-Othernecessaryauxiliaryunits其它必須的輔助裝置OutlineofFUTUREENERGYGmbH未來能源股份有限公司的概況Management經(jīng)理層QualityManagement質(zhì)管部Secretary秘書處Engineering工程技術(shù)部ProcessEngineering工藝工程組Construction建設(shè)單位PilotPlant試驗(yàn)工廠SalesManagement銷售部CommercialManagement商務(wù)部OrganizationofFUTUREENERGYGmbH未來能源股份有限公司的組織結(jié)構(gòu)GSPGasificationTestFacilitiesofFUTUREENERGYGmbHinFreiberg弗賴伯格市未來能源股份有限公司氣化試驗(yàn)工廠Sewagesludgedrier污泥干燥裝置500kg/hPyrolysisunit熱解裝置500kg/hInertgasplant惰性氣裝置1000Nm3/h80bar巴Oxygenplant制氧裝置max.300Nm3/h80bar巴Pulverizedfueldosingandfeedingsystemupto10t/h粉狀燃料定量給料系統(tǒng)，可達(dá)10t/hGasifierVV100氣化爐Reactorwithcoolingwall2-3MW帶水冷壁的反應(yīng)器max.30bar巴Gasifier氣化爐Reactorwithcoolingscreen3-5MW帶水冷壁的反應(yīng)格柵max.30bar巴Slurryfeeding300kg/h料漿供給系統(tǒng)5MW裝置3MW裝置Office辦公樓SulFeroxdesulfurizationunitWastewatertreatmentCOShydrolysisHCNhydrolysis脫硫裝置廢水處理裝置COS水解HCN水解IntroductiontoFUTUREENERGYGmbH

未來能源股份有限公司的介紹

1.1Outlineofthecompany

公司概況1.2Backgroundofthecompany

公司背景1.3Categoryoftechnicalactivities

技術(shù)活動(dòng)動(dòng)態(tài)1.4Developmentstrategyinfuture

未來發(fā)展戰(zhàn)略燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口BackgroundofFUTUREENERGYGmbH未來能源股份有限公司DeutschesBrennstoffinstitutFreiberg(DBI)弗賴伯格市DBI公司NoellGmbHNoell股份有限公司BabcockBorsigPowerGmbHBabcockBorsig電力股份有限公司FUTUREENERGYGmbH未來能源股份有限公司200219991991CentralR&DinstituteofallcoalminingrelatedindustriesoftheGDR(formerEastGermany)前東德煤碳工業(yè)的研究和發(fā)展中心Founded成立:1956inFreiberg1956年成立于弗賴伯格市Employees雇員:morethan1000超過1000人Divisions部門:CoalUpgrading煤的精選部 GasGeneration煤氣制造部

GasTransportandStorage煤氣輸送和儲存部 GasUtilization煤氣開發(fā)部 NuclearTechnology核技術(shù)部In1991theGasGenerationDivisionofDBIwastakenoverbyNoellGmbH

1991年DBI煤氣制造部被NOELL股份有限公司收購DeutschesBrennstoffinstitutFreiberg(DBI)弗賴伯格市DBI公司Founded成立:1824inWürzburgEmployees雇員:ca.（大約）8300Majorbusinesssectors主要的業(yè)務(wù)部門:

SystemandMechanicalEngineering系統(tǒng)工程和機(jī)械工程PowerandEnvironmentalEngineering能源和環(huán)境工程部ProcessEngineering工藝工程部Services售后服務(wù)部In1999NoellGmbHwastakenoverbyDeutscheBabcockAG在1999年NOELL股份有限公司被DeutscheBabcock公司收購Noell股份有限公司NoellGmbHBabcockBorsigPowerGmbHBabcockBorsig電力股份有限公司Founded成立:1898Employees雇員:10,000Majorbusinesssectors主要部門:BoilerEngineering鍋爐工程部PowerPlantEngineering電力工程部EnvironmentalEngineering環(huán)境工程部Services售后服務(wù)部InsolvencyproceedingsopeneduponSeptember1,20022002年9月1日進(jìn)入破產(chǎn)程序IntroductiontoFUTUREENERGYGmbH

未來能源股份有限公司的介紹

1.1Outlineofthecompany

公司概況

1.2Backgroundofthecompany

公司背景

1.3Categoryoftechnicalactivities

技術(shù)活動(dòng)動(dòng)態(tài)

1.4Developmentstrategyinfuture

未來發(fā)展戰(zhàn)略燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水理口激冷水冷卻夾套排水口水碎渣氣體出口

Processdesign,

basicengineeringforgasificationislandandsupplyofmainequipment氣化裝置的工藝設(shè)計(jì)，基礎(chǔ)工程設(shè)計(jì)以及主要設(shè)備供應(yīng)Coalfeedingandgasificationtestsforthepotentialclients

為潛在客戶提供煤的輸送以及氣化的試驗(yàn)Slurrymixingandgasificationtestsofbiomassslurry(pyrolysisoil+char)co-operatedwithForschungszentrumKarlsruhe(FZK)和FZK公司合作做生物漿料（油和碳熱解）的混合及氣化測試Planning,constructionandtestingofadditionaltestplantunitsforFischer-Tropschsynthesis(usinggasmainlyfromgasificationofbiomassF-T合成的試驗(yàn)裝置的規(guī)劃、設(shè)計(jì)和試驗(yàn)（使用的氣體主要來自生物漿料氣化）Planning,constructionandtestingofadditionaltestplantunitsforzeroemissionpowerplantwithCO2sequestration具有CO2多價(jià)螯合作用的無輻射電廠測試裝置的規(guī)劃、設(shè)計(jì)和試驗(yàn)CategoryofTechnicalActivitiesinFUTUREENERGYGmbH未來能源股份有限公司的技術(shù)活動(dòng)動(dòng)態(tài)IntroductiontoFUTUREENERGYGmbH

未來能源股份有限公司的介紹

1.1Outlineofthecompany

公司概況

1.2Backgroundofthecompany

公司背景

1.3Categoryoftechnicalactivities

技術(shù)活動(dòng)動(dòng)態(tài)

1.4Developmentstrategyinfuture

未來發(fā)展戰(zhàn)略燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口Developmentofadvancedtechnology

先進(jìn)技術(shù)的開發(fā)Gasificationreactorsize(upscaling)氣化反應(yīng)器的尺寸Reactordesignat8.5MPadryandslurryfeed)8.5Mpa固態(tài)和液態(tài)給料的氣化反應(yīng)器設(shè)計(jì)Heatrecoveryboilerdevelopment廢鍋的開發(fā)ConceptsforthegasificationofMSW/RDFMSW/RDF氣化原理Approachforblackliquorgasification黑液氣化的方法MarketingStrategyinFuture未來市場策略Europe歐州Coaltopower,fuelsandchemicals用煤生產(chǎn)電、燃料和化工產(chǎn)品Gasificationofchemicalresidues 化工廢料的氣化BiomasstoLiquids(BTL) 生物體液化（BTL）TheAmericas美州Coaltopower,fuelsandchemicals用煤生產(chǎn)電、燃料和化工產(chǎn)品Gasificationofchemicalresiduesandwaste化工廢料及垃圾的氣化Asia亞州Coaltopower,fuelsandchemicals用煤生產(chǎn)電、燃料和化工產(chǎn)品BiomasstoLiquids(BTL)生物體液化（BTL）Australia/NZ澳大利亞/新西蘭Coaltopower,fuelsandchemicals用煤生產(chǎn)電、燃料和化工產(chǎn)品Fischer-TropschSyntheticPilotPlant

FUTUREENERGYGmbHinFreiberg

未來能源股份有限公司F-T合成試驗(yàn)裝置PresentlyatBasicEngineeringstage基礎(chǔ)工程的目前狀

Input投入:Biomass-slurry生物漿:500kg/hRecycledliquids回收液體:50kg/h(fromFTSandHC)Oxygen氧氣:375Nm3/hOutput產(chǎn)出:Diesel柴油:156kg/hNaphtha粗氣油:20kg/hFuelgas燃料氣:7.5kg/hStart-upplannedfor2006(inoperation)計(jì)劃2006年開車

FlowsheetofFischer-Tropschsyntheticpilotplan未來能源股份有限公司的F-T合成試驗(yàn)裝置流程圖2.DescriptionofGSPgasificationtehnologyGSP氣化技術(shù)的描述2.1ThedevelopmentcourseofthetechnologyGSP技術(shù)的發(fā)展過程2.2Flowsheetoftheprocessfromcoaltogas煤制氣的工藝流程圖2.3ConfigurationofaGSPgasifierusingcoalGSP煤氣化爐的構(gòu)造

2.4OtherconfigurationsofGSPgasifiersGSP氣化爐的其他構(gòu)造燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口氣體出口水碎渣DevelopmentcourseofGSPgasificationtechnologyGSP氣化技術(shù)的發(fā)展歷程130MW3MW5MWInFreiberg弗賴伯格InSchwarzePumpe黑水泵廠年份固定床氣化在黑水泵聯(lián)合制氣廠有24臺（固定床）氣化爐氣流床氣化示范工廠褐煤含鹽褐煤褐煤42種褐煤15種無煙煤（世界范圍內(nèi)）粉狀的無煙煤和褐煤石油焦、細(xì)灰15種城市和工業(yè)垃圾、MSW、廢油、木材、麥桿料漿、細(xì)灰工業(yè)垃圾及廢料有機(jī)氯化物含氮有機(jī)廢物黑液焦油含氮有機(jī)廢物料漿、焦油/固體垃圾廢油、焦油天然氣含鹽褐煤商業(yè)化工廠DevelopmentcourseofGSPtechnologyGSP技術(shù)發(fā)展歷程Pilotplant3MW&5MWCoolingscreen/Coolingwallfrom19791979年建成的帶水冷格柵/水冷壁的3MW和5MW試驗(yàn)裝置Industrialplant130MWCoolingscreenfrom19841984年建成的帶水冷格柵的確良30MW工業(yè)裝置OriginofCoalsInvestigatedin3MWTestFacilities3MW試驗(yàn)工廠煤源調(diào)查CoalGasification煤氣化PRChina中國Poland波蘭Russia俄羅斯Bulgaria保加利亞Australia澳大利亞捷克CzechRepublicSpain西班牙SouthAfrica南非Germany德國Anthracite無煙煤Petcoke石油焦Leancoal貧煤ForgecoalFatcoal

Medium-volatilecoal中等揮發(fā)份煤

High-volatilecoal高揮發(fā)份的煤

Hardbrowncoal

Softbrowncoal959085807570656055Carboncontent碳含量Cdaf

[wt.-%]010203040506070VolatilemattercontentVdaf[wt.-%]525141272621282324222529140102151312041103CoalsGasifiedintheFacilitiesoftheR&DCenterofFUTUREENERGYGmbH未來能源股份有限公司研發(fā)中心的工廠氣化的煤(CarbonContent碳含量Cdaf無水無灰基)SOFTBROWNCOALS01GERMANYSchwarzePumpe02GERMANYBraunsbedra03BULGARIAElhovo04AUSTRALIAMineBowmansHARDBROWNCOALS11SPAINTeruel12RUSSIAKansk-Atschinsk13CHINAHarbin14CZECHREPUBLICMost15CZECHREPUBLICSokolovHARDCOALS21GERMANYRuhrgebiet22POLANDSosnica2/123POLANDSosnica24SPAINPuertollanoA(washedcoal)25SPAINPuertollano(unwashedcoal)26AUSTRALIADrayton27AUSTRALIANewlands28SOUTHAFRICAKoornfontein*)29COLOMBIACerrajon*)41PetcokeANTHRACITES51GERMANYDoberlug52GERMANYRuhrgebiet*)gasifiedasamixturechickenmanurepowder鍛造煤肥煤硬褐煤軟褐煤CoalsGasifiedintheFacilitiesoftheR&DCenterofFUTUREENERGYGmbH未來能源股份有限公司研發(fā)中心的工廠氣化的煤(OxygenContent氧含量Odaf無水無灰基)SOFTBROWNCOALS01GERMANYSchwarzePumpe02GERMANYBraunsbedra03BULGARIAElhovo04AUSTRALIAMineBowmansHARDBROWNCOALS11SPAINTeruel12RUSSIAKansk-Atschinsk13CHINAHarbin14CZECHREPUBLICMost15CZECHREPUBLICSokolovHARDCOALS21GERMANYRuhrgebiet22POLANDSosnica2/123POLANDSosnica24SPAINPuertollanoA(washedcoal)25SPAINPuertollano(unwashedcoal)26AUSTRALIADrayton27AUSTRALIANewlands28SOUTHAFRICAKoornfontein*)29COLOMBIACerrajon*)41PetcokeANTHRACITES51GERMANYDoberlug52GERMANYRuhrgebiet*)gasifiedasamixturechickenmanurepowderAnthracite無煙煤Petcoke石油焦Leancoal貧煤ForgecoalFatcoal肥煤

Medium-volatilecoal中等揮發(fā)份煤

High-volatilecoal高揮發(fā)份的煤

Hardbrowncoal

SoftbrownCoal軟褐煤4035302520151050Oxygencontent氧含量

Odaf

[wt.-%]010203040506070VolatilemattercontentVdaf[wt.-%]525141272621232422252914010215131204110328鍛造煤硬褐煤CoalsGasifiedintheFacilitiesoftheR&DCenterofFUTUREENERGYGmbH(HydrogenContentHdaf)未來能源股份有限公司研發(fā)中心的工廠氣化的煤（氫含量）1086420HydrogencontentHdaf

[wt.-%]010203040506070VolatilemattercontentVdaf[wt.-%]525141272623212422252914010215131204110328Anthracite無煙煤Petcoke石油焦Leancoal貧煤ForgecoalFatcoal

Medium-volatilecoal中等揮發(fā)份煤

High-volatilecoal高揮發(fā)份的煤

Hardbrowncoal

SoftbrowncoalSOFTBROWNCOALS01GERMANYSchwarzePumpe02GERMANYBraunsbedra03BULGARIAElhovo04AUSTRALIAMineBowmansHARDBROWNCOALS11SPAINTeruel12RUSSIAKansk-Atschinsk13CHINAHarbin14CZECHREPUBLICMost15CZECHREPUBLICSokolovHARDCOALS21GERMANYRuhrgebiet22POLANDSosnica2/123POLANDSosnica24SPAINPuertollanoA(washedcoal)25SPAINPuertollano(unwashedcoal)26AUSTRALIADrayton27AUSTRALIANewlands28SOUTHAFRICAKoornfontein*)29COLOMBIACerrajon*)41PetcokeANTHRACITES51GERMANYDoberlug52GERMANYRuhrgebiet*)gasifiedasamixturechickenmanurepowder鍛造煤肥煤硬褐煤軟褐煤CoalsGasifiedintheFacilitiesoftheR&DCenterofFUTUREENERGYGmbH(Acid/BaseRatiooftheAshConstituents)未來能源股份有限公司研發(fā)中心的工廠氣化的煤（灰組份的酸堿比例）1086420Acid/baseratiokoftheashconstituents灰組份的酸堿比例010203040506070VolatilemattercontentVdaf[wt.-%]5251272623212422252914010215131204110328Anthracite無煙煤Petcoke石油焦Leancoal貧煤ForgecoalFatcoal肥煤

Medium-volatilecoal中等揮發(fā)份煤

High-volatilecoal高揮發(fā)份的煤

Hardbrowncoal

SoftbrownCoal軟褐煤

SiO2+Al2O3+TiO2Fe2O3+CaO+MgO+Na2O+K2Ok=鍛造煤硬褐煤FuelAnalyses燃料分析Component組成Hardcoal無煙煤Unit單位Petcoke石油焦SewageSludge垃圾Lignite褐煤Oil油BiomassSprucewood生物木料HouseholdWaste家庭垃圾CHNOSMoisture水份Ash(dry)灰份Heatingvalue熱值(drybasis干基)wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%MJ/kg92.03.51.02.51.02.05.0–15.025-3227.50.510.05.0–15.018-250.5–1.517-1934.55.03.520.51.515.039.0–45.010-1330.51.510.015.0–25.012-1587.03.92.01.0–5.034-3685.512.5-1.01.0<0.1>0.539-42FuelAshAnalyses燃料灰分析Component組成Hardcoal無煙煤Unit單位Petcoke石油焦SewageSludge垃圾Lignite褐煤Oil油BiomassSprucewood生物木料HouseholdWaste家庭垃圾SiO2CaOMgOAl2O3P2O5Fe2O3K2ONa2OAsh(dry)灰（干基）wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%wt.-%47,55.51.018.0<0.55.0–15.0TracemetalsVa,Ni,K,Na46.5<0.222.01.00.55.0–15.05.556.3<0.5–1.542.020.53.51.00.539.0–45.047.522.03.51.54.015.0–25.0>0.5TracemetalsVa,Ni>0.5FluidPointt25ofTechnicalAshesasaFunctionoftheCaO/SiO2RatioTemperature溫度[°C]CaO/SiO2ratioCaO/SiO2比Fluidpointt25流動(dòng)溫度Acidic酸性Alkaline堿性灰中的CaO/SiO2比值與煤的流動(dòng)溫度的關(guān)系PhaseDiagramoftheSystemCaO-Al2O3-SiO2CaO-Al2O3-SiO2系統(tǒng)相圖Coal煤1Coal煤2Coal1+Coal2FuelPreparationReferenceValue燃料參考數(shù)據(jù)Particle-SizeDistribution顆粒尺寸范圍MoistureContent水份Petcoke石油焦Anthracite無煙煤Hardcoal無煙煤

50%-90%<63μm100%<200μm<2wt.-%Pyrolysiscoke熱解焦

99%<250μm

100%<500μm<2wt.-%Hardcoal無煙煤

94%<250μm

100%<500μm<2wt.-%Hardbrowncoal硬褐煤

94%<250μm

100%<500μm<8wt.-%Softbrowncoal軟褐煤

55%<100μm

99%<500μm<12wt.-%Sewagesludge垃圾

94%<250μm100%<500μm<10wt.-%(lowreactivity低活性Vdaf<12%)(highreactivity低活性,Vdaf>28%)>>>>>>------Fuels燃料––CompositionofRawGasfromDifferentFeedstocks不同原料所產(chǎn)的粗合成氣的比較Component組份HardCoal無煙煤Unit單位Petcoke石油焦DomesticRefuse生活垃圾Lignite褐煤Oil油Biomass生物體SewageSludge垃圾Calorificvalue熱值MJ/Nm311.110.910.39.7Calorificvalue(dry)熱值（干基）MJ/kg25-3234-3618-2539-42

17-1912-1510-13H2COCO2CH4N2H2SCOSHCNNH3vol.-%vol.-%vol.-%vol.-%vol.-%vol.-%vol.-%vol.-%vol.-%27643<60.041.00.422655<31558<00.021.00.2445484<0.010.20.4275014<2<294916<60.020.010.25324912<80.022.00.3VHmHh=RGRGucuc...Scale-upofExperimentalDataObtainedfromGasificationofCoalsofDifferentRankforCommercializationVolatilemattercontentVdaf[wt.-%]揮發(fā)份含量Medium-VolatileCoal

HardbrowncoalH2contentoftherawgas[vol.-%dry]Gasificationefficiency[%]10203040506070Anthracite無煙煤Petcoke石油焦Leancoal貧煤ForgecoalFatcoal肥煤

High-volatileCoal高揮發(fā)份煤

SoftbrowncoalSpecificrawgasoutput[Nm3dry/kg]Heatingvalueoftherawgas[MJ/Nm3dry]COcontentoftherawgas[vol.-%dry]252030635868105807882中等揮發(fā)份煤鍛造煤硬褐煤軟褐煤粗合成氣氫含量粗合成氣CO含量粗合成氣熱值產(chǎn)氣率氣化效率為了商業(yè)應(yīng)用，氣化不同等級的煤所得的經(jīng)驗(yàn)數(shù)據(jù)DevelopmentCourseofthe130MWGSPEntrained-flowGasificationTechnologyinSchwarzePumpeSchwarzePumpe130MWGSP氣流床氣化技術(shù)發(fā)展歷程19841984–19861986–19901990–19921992–1994from1994from1998Plantconstructionfinishedandcommissioning1984年裝置建成并開車Trialoperationoncommonandsaliferouslignite1984-1986年普通褐煤及含鹽褐煤氣化裝置試運(yùn)行(Peakload)plantoperationsoncommon/saliferouslignite1986-1990年普通褐煤及含鹽褐煤氣化裝置滿負(fù)荷運(yùn)行(Peakload)plantoperationsonnaturalgas1990-1992年天然氣氣化裝置滿負(fù)荷運(yùn)行Oilgasification1992-1994年油氣化裝置運(yùn)行Gasificationofslurriesandtar-oil-solidssuspensions

自1994年開始?xì)饣蠞{和焦油及有固體懸浮物的油Productionofmethanolandelectricpower(IGCC）自1998年開始生產(chǎn)甲醇和發(fā)電（IGCC）2.DescriptionofGSPgasificationtehnologyGSP氣化技術(shù)的描述

2.1ThedevelopmentcourseofthetechnologyGSP技術(shù)的發(fā)展過程

2.2Flowsheetoftheprocessfromcoaltogas煤制氣的工藝流程圖2.3ConfigurationofaGSPgasifierusingcoalGSP煤氣化爐的構(gòu)造

2.4OtherconfigurationsofGSPgasifiersGSP氣化爐的其他構(gòu)造燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口氣體出口水碎渣SchematicFlowDiagramoftheGSPTestFacility3MWth3

MWth試驗(yàn)工廠流程圖蒸汽發(fā)生器及其過熱粉狀燃料貯槽天然氣供給液體燃料供給漿料供給粉狀燃料/煙道氣鎖斗給料器制氧裝置惰性氣裝置氧氣煙道氣渣鎖斗反應(yīng)器渣池廢水灰鎖斗閃蒸罐洗滌水洗滌塔煤氣分離器回收槽冷卻塔冷卻回水管線脫硫裝置活性碳過濾器燃燒室火炬SchematicFlowDiagramoftheGSPTestFacility5MWth5MWthGSP試驗(yàn)工廠流程圖粉狀燃料惰性氣放空氣粉狀燃料供給氣化粉狀燃料氧氣/蒸汽激冷/洗滌粗合成氣冷卻COS水解硫回收裝置合成氣硫磺給水廢水處理給水渣料漿供給惰性氣料漿排渣系統(tǒng)2.DescriptionofGSPgasificationtehnologyGSP氣化技術(shù)的描述

2.1ThedevelopmentcourseofthetechnologyGSP技術(shù)的發(fā)展過程2.2Flowsheetoftheprocessfromcoaltogas煤制氣的工藝流程圖

2.3ConfigurationofaGSPgasifierusingcoalGSP煤氣化爐的構(gòu)造

2.4OtherconfigurationsofGSPgasifiersGSP氣化爐的其他構(gòu)造燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口氣體出口水碎渣GSPEntrained-flowGasifierGSP氣流床氣化爐Fig.7燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴冷卻夾套排水口水碎渣氣體出口帶壓水出口水冷格柵帶壓水進(jìn)口激冷水GSPGasificationChamberGSP氣化爐的氣化室Fig.7RawgasSlagOxygen,Steam

氧氣、蒸汽Coals煤Slagdischargeunit渣排出裝置粗氣及渣PneumaticConveyingandFeedingSystemforPulverizedSolidMaterials粉狀固態(tài)物料的氣體輸送和給料系統(tǒng)物料廢氣儲存?zhèn)}泄壓泄壓鎖斗鎖斗物料去氣化爐給料倉BurnerforCoalGasification煤氣化燒嘴冷卻水粉煤冷卻水冷卻水點(diǎn)火燒嘴燃料氣火焰檢測點(diǎn)火器冷卻水冷卻水冷卻水氧氣/蒸氣CoolingScreenoftheGasificationReactor氣化反應(yīng)器的水冷格柵Liquidslag液態(tài)渣Solidslag固態(tài)渣Membranwall隔膜墻Pressurizedwater加壓水Rammingmass夯實(shí)層Pipecoilwithstuds帶抓丁的盤管CoolingScreenStratificationinCoalGasification150kW/m2150kW/m2

煤氣化裝置中的水冷格柵各層溫度分布~500°C~1400°C水管子碳化硅渣2.DescriptionofGSPgasificationtehnologyGSP氣化技術(shù)的描述

2.1ThedevelopmentcourseofthetechnologyGSP技術(shù)的發(fā)展過程2.2Flowsheetoftheprocessfromcoaltogas煤制氣的工藝流程圖2.3ConfigurationofaGSPgasifierusingcoalGSP煤氣化爐的構(gòu)造2.4OtherconfigurationsofGSPgasifiersGSP氣化爐的其他構(gòu)造燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口氣體出口水碎渣GSPGasificationReactorsGSP氣化反應(yīng)器Reactorwithcoolingwall帶水冷壁的反應(yīng)器Reactorwithcoolingscreen帶水冷格柵的反應(yīng)器Granulatedslag▼水冷壁耐火層夯實(shí)層冷卻水部分激冷裝置插燒咀處插燒咀處氣化室氣體出口激冷部分水碎渣水碎渣氣體出口氣體和渣出口氣化室GasificationReactorsofFUTUREENERGYGmbHReactorwithcoolingscreenandspecialquenchReactorwithcoolingwallReactorwithcoolingscreen帶水冷格柵和特殊激冷室的反應(yīng)器帶水冷壁的反應(yīng)器帶水冷格柵的反應(yīng)器插燒咀處插燒咀處氣體和渣出口被冷卻的反應(yīng)器出口氣體出口氣體出口激冷系統(tǒng)部分激冷系統(tǒng)冷卻水SiC層耐火層水冷壁插燒咀處熔融物出口冷卻格柵綠液未來能源股份公司的氣化反應(yīng)器ProprietaryGasificationTechnologies專有的氣化技術(shù)黑液高鹽低灰無灰含灰含灰含灰化工廢料可回收的燃料常規(guī)燃料殘?jiān)皬U料瀝青重油油渣煤泥油天然氣沼氣FE氣流床氣化NOELL變換工藝熱解氣化殘油合成廢料：有機(jī)氯化物含氮有機(jī)物垃圾MSW有毒垃圾生物經(jīng)技術(shù)處理的部分分類垃圾Entrained-flowGasifierwithHeatRecoverySteamGenerator(HRSG)帶廢鍋的氣流床氣化爐3.IndustrialapplicationsofGSPtechnologyGSP氣化技術(shù)的工業(yè)應(yīng)用3.1GasificationofligniteinSchwarzePumpeSchwarzePumpe的褐煤的氣化

3.2Gasificationofotherfeedstocks其它物料的氣化3.3Theapplicationsoftheproductgas

GSP制氣工藝的應(yīng)用3.4Scale-upofgasifierbased-on130MWunit基于130兆瓦裝置放大的氣化爐燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口IndustrialapplicationsstatusofGSPgasificationtechnologyGSP氣化技術(shù)的工業(yè)應(yīng)用狀況SchwarzePumpeGermany德國130MWCoalfines粉煤1984-1990Otherfeeds其它物料from1991MiddlesbroughTheUnitedKingdom英國米德爾斯堡Liquidwastesfromchemicalplant30MW化工廠的液體廢料from2001VresováCzechRepubilc捷克共和國Coaltar煤焦油140MWfrom20052005年建成的捷克共和國Vresová140MW煤焦油氣化2001年建成的英國米德爾斯堡30MW的化工廠的液體廢料氣化德國SchwarzePumpe廠1984-1990130MW的粉煤氣化1991年開始其它物料氣化25%coaland75%solidwastesatthemomentPicturesource:SVZGmbH,SchwarzePumpe處理固體和液體廢料的大致流程外部處理后的固體廢料污泥廢塑料城市垃圾及其它廢料瀝青及其它泥渣液體/糊狀垃圾廢木料氧氣污泥塊壓縮塑料碎木垃圾制品制粒裝置氣流床氣化BGL氣化床層加壓氣化氣體凈化油水分離器甲醇聯(lián)合發(fā)電氣體透平鍋爐裝置污水處理凈化后的廢水硫酸鈣灰、渣電甲醇蒸汽現(xiàn)在25%煤和75%固體垃圾氣體Coalgasificationusingthe130MWGSPEntrained-flowGasificationTechnologyinSchwarzePumpe19841984–19861986–1990From1991Plantconstructionfinishedandcommissioning1984年裝置建成并開車Trialoperationoncommonandsaliferouslignite1984-1986年普通褐煤及含鹽褐煤氣化裝置試運(yùn)行(Peakload)plantoperationsoncommon/saliferouslignite1986-1990年普通褐煤及含鹽褐煤氣化裝置滿負(fù)荷運(yùn)行Plantoperationsonotherfeedstocks1991年起氣化其它物料的裝置運(yùn)行

SchwarzePumpe130MW的GSP氣流床煤氣化技術(shù)ElementalAnalysis,AshContentandHeatingValueofLignites

（褐煤的元素分析、灰份和熱值）wt.-%(waf)wt.-%(waf)wt.-%(waf)wt.-%(waf)wt.-%(waf)wt.-%wt.-%MJ/kgkg/m3CHSNOAsh(wf)灰份Moisture濕度Heatingvalue(waf)熱值Bulkdensity堆密度69.3323.6413.710.125.5520Lignite褐煤72.445.733.250.7317.8514.110.427.8540Lignite褐煤（含鹽）(saltcontaining)Itemsofanalysis分析項(xiàng)目Feedstocksforgasificationfrom1984to19901984-1990年氣化用的物料Flow-MeasurementforDensephase-Conveying密向輸送的流量測量儀器Picturesource:SWRengineering加壓漏斗壓縮氣體燃燒室DN50鋼管流動(dòng)氣體（N2）燃料（有灰）具有大的流量在機(jī)械傳輸系統(tǒng)之后，如滑道、滑動(dòng)或管道用氣體輸送的高密度物質(zhì)粉狀或粒裝物質(zhì)密向流量計(jì)用于以下情況的在線測量：密向流量計(jì)是為了測量輸送的高密度固體的流量而專門設(shè)技的初始燃料AutomationControlSystemforGSPTechnology

FailsafePLC

ProcessstationGasificationplantMODBUS

ProcessstationSootwaterplant

Sootwaterplant

Controlstation2

Controlstation3

Applicationstation

DCSconnectionby

applicationinstallation

Controlstation1

GasificationplantDCSforcontrolDCS控制系統(tǒng)PLCforsecurityPLC安全系統(tǒng)GSP技術(shù)的自動(dòng)控制系統(tǒng)控制站1控制站2控制站3應(yīng)用站DCS的連接由應(yīng)用站安裝事故安全PLC氣化裝置黑水處理裝置氣化裝置過程站黑水處理裝置過程站GasificationEfficiencyasaFunctionofLoadhv[%]Load負(fù)荷[%]Rangeofload反應(yīng)器負(fù)荷: 50%to110%Carbonconversionrate碳轉(zhuǎn)化率: >99%Hardcoal無煙煤Lignite褐煤負(fù)荷與氣化效率關(guān)系A(chǔ)vailabilityandEnduranceofMainEquipment10years年10years10年(withrepairofburnertip燒嘴頭部維修)15years年Gasifiersystem(coolingscreen)氣化爐系統(tǒng)（水冷格柵）Burner燒嘴(feedinjector噴頭)Dense-flowfeedingsystem給料系統(tǒng)Equipment設(shè)備90%~95%Endurance使用壽命Availability利用率MaintenanceCycle維護(hù)周期Maintenancedown-time維護(hù)用時(shí)間Annual一年(visualcheck檢查)half-yearly半年(redundantburner備用燒嘴)annualchangeofvalve/sealrings閥和密封圈更換/1年1week1周1shift1工作日1week1周主要設(shè)備的使用壽命和利用率3.IndustrialapplicationsofGSPtechnologyGSP氣化技術(shù)的工業(yè)應(yīng)用3.1GasificationofligniteinSchwarzePumpeSchwarzePumpe的褐煤的氣化3.2Gasificationofotherfeedstocks其它物料的氣化3.3Theapplicationsoftheproductgas

GSP制氣工藝的應(yīng)用3.4Scale-upofgasifierbased-on130MWunit基于130兆瓦裝置放大的氣化爐燃料燃?xì)馊c(diǎn)火燒咀氧氣燒嘴帶壓水出口水冷格柵帶壓水進(jìn)口激冷水冷卻夾套排水口水碎渣氣體出口PotentialfeedstocksforGSPgasificationtechnologyGSP氣化技術(shù)可能使用的物料Hydrogen氫氣Carbonmonoxide一氧化碳GasifierislandwithASUandgascleaning(Naturalgas天然氣)Refinerygas煉油廠氣Residualoil渣油Petroleumcoke石油焦Sewagesludge污泥Wasteoil廢油Biomass生物體Blackliquor黑液Municipalwaste城市垃圾Chemicalresidues化工廢料Coal煤Combinedcycle聯(lián)合發(fā)電Oxygen氧氣Potentialfeeds可能的原料PotentialproductsNitrogen氮?dú)釧rgon氬氣Carbondioxide二氧化碳Sulfur/sulfuricacid硫/硫酸Steam蒸汽Electricalenergy電能ChemicalProduction化工產(chǎn)品Fertilizers肥料Chemicals化工產(chǎn)品Methanol甲醇Aceticacid醋酸Fischer-TropschSynthesis合成Motorfuels氣車燃料Chemicals化工產(chǎn)品Slagtobuildingindustries渣用于建筑工業(yè)Reductiongas(ironore,steel)有空分和凈化的氣化裝置還原氣（鐵、銅、鋼）可能的產(chǎn)品FeedstocksforgasificationinSchwarzePumpeSchwarzePumpe氣化的原料Informationsource:SVZGmbH,SchwarzePumpeSVZ生產(chǎn)的城市煤氣來源于SchwarzePumpe的褐煤氣化這種煤氣化工藝已成功開發(fā)3百年了，被用于九十家垃圾處理工廠，涉及許多新技術(shù)，并且現(xiàn)代化裝置已建軍成。公司340名雇員包括有資格工人和機(jī)動(dòng)合作工人及技術(shù)人員我們是一家資深專業(yè)公司，引進(jìn)并實(shí)施了DINENISO9002質(zhì)量管理體系和一百萬噸污染的廢油，油水混合物和溶劑混合物自1995年起產(chǎn)量逐年增加，現(xiàn)已處理起過兩百萬噸的固體和液體垃圾。包括：廢塑料廢木料垃圾顆粒污泥瀝青渣粒LiquidwasteThewastesacceptedforgasificationinSchwarzePumpeSchwarzePumpe可接受的氣用垃圾Informationsource:SVZGmbH,SchwarzePumpe液體垃圾液體垃圾小于5%固體起過5%固體固體垃圾計(jì)量單位污染物砷鉛鎘鉻銅鎳汞鋅錫以下是SVZ處理的符合技術(shù)要求的垃圾的污染物最大濃度：氯/鹵素氰化物戴奧辛/呋喃聚氯化物聯(lián)笨AverageemissionsinSchwarzePumpeSchwarzePumpe的平均散發(fā)物Informationsource:SVZGmbH,SchwarzePumpe散發(fā)物（體積mg/m3）最大濃度SVZ平均值SVZ保證空氣中的散發(fā)物濃度在17世紀(jì)的BLMSchV標(biāo)準(zhǔn)之下（聯(lián)邦控制標(biāo)準(zhǔn)）一氧化碳有機(jī)化合物硫的氧化物灰塵氮的氧化物戴奧辛/呋喃（17世紀(jì)BlmSchvR的最大濃度為：0.1ng/m3)低于下限VresóvaPlantinCzechRepublic捷克共和國Vresóva工廠26fixed-bedgasifiers28barCondensation冷凝RectisolPlant凈化裝置GuDcombined-cycleplantHardbrowncoalOxygen氧氣Entrained-flowgasification28bar/140MWTar焦油Steam蒸汽Oxygen氧氣Steam蒸汽Wast