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乙二醇冷卻液(防凍液)-45℃化學(xué)品安全技術(shù)說明書-MSDS1.化學(xué)品及企業(yè)標(biāo)識(shí)化學(xué)產(chǎn)品中文名稱使用1.化學(xué)品及企業(yè)標(biāo)識(shí)化學(xué)產(chǎn)品中文名稱使用產(chǎn)品代碼乙二醇冷卻液?45結(jié)防凍劑及冷卻液XJF0045.成分/組成信息配方說明:乙二醇單體與防銹抑制劑組合的混合物危險(xiǎn)組分 CAS 含量%乙二醇 107211 56.5%氣相防銹劑VCI649 0.5%額外說明:VCI649不含亞硝酸鹽,磷,氨,重金屬,無毒可生物降解,安全環(huán)保無污染。.危險(xiǎn)性概述 警告:口服將有致命危險(xiǎn),使人頭暈和昏昏欲睡,可引發(fā)酸毒癥,心肺疾病及腎病。吸入:對(duì)呼吸系統(tǒng)有輕微刺激作用,產(chǎn)生頭疼,惡心,睡意,意識(shí)不清和咽喉感染發(fā)炎。皮膚接觸:對(duì)皮膚有中度刺激,短時(shí)間接觸能引起輕微發(fā)炎,長(zhǎng)時(shí)間接觸局部會(huì)紅腫,能引起嚴(yán)重發(fā)炎和不適。眼睛接觸:能引起眼睛紅腫,發(fā)炎,視覺模糊等癥狀。.急救措施一般信息:切勿延遲處理,保持冷靜,立即就醫(yī)。吸入:將接觸者遷移到空氣清新的地方,如果沒有在短時(shí)間內(nèi)恢復(fù),應(yīng)將其及時(shí)就近送到醫(yī)院救治。接觸皮膚:脫去污染衣物,用水沖洗暴露部位,并用肥皂進(jìn)行清洗。如刺激持續(xù),請(qǐng)立即就醫(yī)。眼睛接觸:用大量水沖洗,如刺激癥狀不能減輕,請(qǐng)就醫(yī)。吞食:切勿延遲處理,發(fā)生吞咽,不要讓其嘔吐,如果發(fā)生自發(fā)性嘔吐,讓其頭低于臀部以下,以防止其抽吸,立即送到最近的醫(yī)療急救中心或醫(yī)院。給醫(yī)生的建議:中毒癥兆有點(diǎn)類似一般的酒醉,初期興奮,緊接著昏迷,抽搐。癥狀包括手舞足蹈,好睡,嘔吐,腹瀉,口渴,抽搐,中毒的最后階段包括因?yàn)樗嶂卸径鸬哪I臟的損害。.消防措施 使所有非急救人員撤離火區(qū)。特定的危險(xiǎn):危險(xiǎn)燃燒物品可能包括氣載固體與液體微粒及氣體(煙)的復(fù)雜混合物。一氧化碳。未被識(shí)別的有機(jī)、無機(jī)化合物。適當(dāng)?shù)臏缁鸾橘|(zhì):泡沫,灑水或噴霧。干化學(xué)滅火粉、二氧化碳、沙或泥土僅宜用于小規(guī)模火災(zāi)。不適用的滅火物:切勿噴水。消防人員保護(hù)設(shè)備:合適的保護(hù)裝置包括在密封空間內(nèi)接近起火點(diǎn)時(shí)必需配戴的呼吸裝置。.泄漏應(yīng)急處理 避免接觸溢出或釋放出來的材料。關(guān)于個(gè)人防護(hù)設(shè)備的選擇指南,見第8章材料安全數(shù)據(jù)表。關(guān)于處置信息,請(qǐng)參閱第13章。請(qǐng)遵從所有適用的地方及國(guó)際法規(guī)。保護(hù)措施:避免沾及皮膚及眼睛。使用合適的防擴(kuò)散措施,以免污染環(huán)境。用沙、泥土或其它適合的障礙物來防止擴(kuò)散或進(jìn)入排水道、陰溝或河流。清除方法:對(duì)于較多的液體溢出(大于1鼓桶),通過機(jī)械方式例如真空卡車轉(zhuǎn)移到救援罐中進(jìn)行回收或安全處理。不得用水來沖洗殘?jiān)?。?yīng)當(dāng)作污染廢物進(jìn)行保留。讓殘?jiān)舭l(fā)或用適當(dāng)?shù)奈招圆牧衔諝堅(jiān)?,并進(jìn)行安全處理。清除受污染的泥土并進(jìn)行安全處理。對(duì)于較少的液體溢出(小于1鼓桶),通過機(jī)械方式例如真空卡車轉(zhuǎn)移到有標(biāo)簽和可密封的容器內(nèi)進(jìn)行產(chǎn)品回收或安全處理。讓殘?jiān)舭l(fā)或用適當(dāng)?shù)奈招圆牧衔諝堅(jiān)⑦M(jìn)行安全處理。清除污染的泥土并進(jìn)行安全處理。額外建議:應(yīng)將無法處理的嚴(yán)重溢漏事件通知地方當(dāng)局。TSCA:hasnotbeenestablished.ClassificationTriggerComponents:containingethyleneglycol,withbitteragents.OtherInformation:GB6944-2005(dangerousgoodsclassificationandnamenumbers)GB/T16483-2008:contentofchemicalsafetytechniquemanualanditemorderGB13690-1992:classificationandlabelsofcommondangerouschemicalsGB12268-2005:nomenclaturefordangerousgoods.GBZ2.1-2007:occupationalexposurelimitsforhazardousfactorsintheworkplaceNationalhazardouswastelist16.OtherInformationRiskwarningR22swallowingharmfultothehumanbody.ITChemicalsafetymanualJ]version1.0『chemicalsafetymanual』date:『chemicalsafetymanualJ|revision:leftpageoftheverticalbar(|)Sayshereismadeonapreviousversionoftheamendments.MSDS(chemicalsafetydatamanual)distribution:allworkersloadingandunloadingthegoodsshouldbefamiliarwiththepresentinformationofthedocument.Disclaimer:Theinformationprovidedisbasedonourunderstandingofexistingdata,anddescriptionforthisproductonlyinaccordancewiththehealth,safetyandenvironmentalrequirements.Wedonotprovideanyguaranteeforspecificfeaturesofthisproduct..操作處置與儲(chǔ)存 一般預(yù)防措施:若存在吸入蒸汽、噴霧或煙霧的危險(xiǎn),請(qǐng)使用局部排氣通風(fēng)系統(tǒng).為防起火,應(yīng)適當(dāng)?shù)靥幹萌魏问芷湮廴镜氖媚ú剂匣蚯逑床牧?。將本資料單所含的信息包括進(jìn)本地情況風(fēng)險(xiǎn)評(píng)估中,將有助于為本品的搬運(yùn)、儲(chǔ)存及棄置制訂有效的控制系統(tǒng)。搬運(yùn):避免長(zhǎng)期或持續(xù)與皮膚接觸。避開吸入其蒸汽和(或)煙霧。裝卸桶裝產(chǎn)品時(shí),應(yīng)穿保護(hù)鞋,并使用恰當(dāng)?shù)难b卸工具。儲(chǔ)存:密閉容器,放在涼爽、通風(fēng)良好的地方。使用適當(dāng)加注標(biāo)簽及可封閉的容器。儲(chǔ)存溫度:0-50°C/32-122°F推薦使用的物料:對(duì)于容器或容器內(nèi)襯,應(yīng)使用軟鋼或高密度聚乙烯。不適用的物質(zhì):鋅。避免與電鍍材料接觸。額外信息:聚乙烯容器不應(yīng)置于高溫下,因?yàn)榭赡茉斐膳で冃巍?接觸控制/個(gè)體防護(hù)職業(yè)暴露極限化學(xué)產(chǎn)品來源類型PPmmg/m3標(biāo)記乙二醇ACGIHCeiling[氣溶膠]100mg/m3化學(xué)產(chǎn)品 來源 危險(xiǎn)標(biāo)志乙二醇 ACGIH 不被歸類為人類致癌物質(zhì)暴露控制:必需的保護(hù)級(jí)別和控制措施類型依潛在的接觸條件而有所不同。根據(jù)對(duì)當(dāng)?shù)貭顩r的風(fēng)險(xiǎn)評(píng)估來選擇控制措施。適當(dāng)?shù)拇胧┌ǎ和L(fēng)充足,足以控制氣體濃度。本品在加熱、噴灑或成霧后更有可能集結(jié)在空氣中。個(gè)人保護(hù)設(shè)備:個(gè)人保護(hù)設(shè)備(PPE)應(yīng)符合建議的國(guó)家標(biāo)準(zhǔn)。請(qǐng)查詢PPE供貨商。呼吸保護(hù)措施:在正常使用條件下,一般不需戴呼吸保護(hù)用具。良好的工業(yè)衛(wèi)生慣例說明應(yīng)采取能防止吸入本品的措施。如果工程控制設(shè)施未把空氣濃度保持在足以保護(hù)人員健康的水平,選擇適合使用條件及符合有關(guān)法律要求的呼吸保護(hù)設(shè)備。請(qǐng)呼吸保護(hù)裝備供應(yīng)商核實(shí)。如需戴安全過濾面罩時(shí),請(qǐng)選擇合適的面罩與過濾器組合。選擇一種適用于顆粒/有機(jī)氣體及蒸氣[沸點(diǎn)>65°C(149°F)]的混合物的過濾器。手防護(hù):在手可能接觸產(chǎn)品的情況下,為得到適當(dāng)?shù)幕瘜W(xué)保護(hù),應(yīng)使用符合有關(guān)標(biāo)準(zhǔn)(如歐洲:EN374,美國(guó):F739)并用以下材料制成的手套:聚氯乙烯、氯丁或丁睛橡膠手套.手套的合適性和耐用性取決于如何使用,例如接觸的頻率和時(shí)間長(zhǎng)度,手套材料的耐化學(xué)性.手套的厚度及靈巧性應(yīng)始終向手套供應(yīng)商尋求建議。應(yīng)更換受污染的手套。個(gè)人衛(wèi)生是有效護(hù)理手部的主要方法。必須僅在雙手洗干凈后,才能戴手套。使用手套后,必須徹底清洗及烘干雙手。建議使用非香型保濕霜。眼睛防護(hù):如可能發(fā)生濺潑,請(qǐng)戴安全護(hù)鏡或全臉面罩。防護(hù)衣服:一般而言,除了普通的工作服之外不需特殊的皮膚保護(hù)措施。監(jiān)測(cè)方法:需要對(duì)工人的呼吸區(qū)域或一般工作場(chǎng)所的各種物質(zhì)的濃度進(jìn)行監(jiān)測(cè),以確認(rèn)是否符合OEL及接觸控制的適當(dāng)性。對(duì)于某些物質(zhì),也可以采用生物監(jiān)測(cè)。環(huán)境暴露風(fēng)險(xiǎn)控制措施:減少對(duì)環(huán)境的排放。必須進(jìn)行環(huán)境評(píng)估以確保符合當(dāng)?shù)氐沫h(huán)境法規(guī)。.理化特性外觀:橙色。.室溫下液體。氣味:特性.PH值:典型7.8?9.5初沸點(diǎn)及沸程:>100°C/212°F估計(jì)值凝固點(diǎn):典型?46°C/?51°F無數(shù)據(jù)可供參考。閃點(diǎn):無數(shù)據(jù)可供參考??扇夹曰虮ㄉ舷?T限:3-15%(V)自燃溫度:>200°C/392°F蒸氣壓力:無數(shù)據(jù)可供參考。比重:無數(shù)據(jù)可供參考。密度:典型1.070-1.085kg/m3于15°C/59°F水溶性:完全可溶的分配系數(shù):正辛醇/水:無數(shù)據(jù)可供參考。運(yùn)動(dòng)粘度:不適用的。蒸氣密度(空氣=1):無數(shù)據(jù)可供參考。蒸發(fā)率(nBuAc=l):無數(shù)據(jù)可供參考。.穩(wěn)定性和反應(yīng)活性穩(wěn)定性:穩(wěn)定。應(yīng)避免的條件:極端溫度及陽(yáng)光直曬。應(yīng)避免的物質(zhì):強(qiáng)氧化劑。危險(xiǎn)化學(xué)品分解:在正常存儲(chǔ)情況下,不會(huì)形成危險(xiǎn)的分解物評(píng)鑒基礎(chǔ):所提供的信息以類似產(chǎn)品的組份及毒性數(shù)據(jù)為基礎(chǔ)??谇患毙远拘裕罕粴W盟委員會(huì)列為有害物。鼠齒類動(dòng)物和人類的急性口服毒性有顯著不同,人類更加容易受傷害。人類的死亡劑量是100毫升(1/2杯)。此物料也曾顯示對(duì)貓和狗有進(jìn)食毒性及潛在致死能力。吞服會(huì)使人頭暈和昏昏欲睡。皮膚急性毒性:預(yù)期毒性低:LD50>2000mg/kg5兔刺激皮膚:可能引起中量皮膚刺激反應(yīng)(但嚴(yán)重性不足以對(duì)其進(jìn)行分類)。刺激眼睛:對(duì)眼睛有中度刺激(但嚴(yán)重程度不足以對(duì)其進(jìn)行分類)。呼吸刺激物:吸入蒸氣或粉霧可能會(huì)引起刺激。致敏性:預(yù)期不是皮膚致敏物。重復(fù)劑量毒性:腎臟:可損害腎臟。突變性:認(rèn)為沒有誘變危險(xiǎn)。致癌性:成份是否具有致癌性,尚不可知。生殖毒性和發(fā)育毒性:對(duì)動(dòng)物有胎兒毒性;被視為母體毒性的副效應(yīng)。.生態(tài)學(xué)資料并無專門確定本產(chǎn)品的生態(tài)毒理學(xué)數(shù)據(jù)。上述資料基于對(duì)類似產(chǎn)品的成分及生態(tài)毒理學(xué)的了解而提供。急性毒性:預(yù)期實(shí)際無毒:LC/EC/IC50>100mg/1(針對(duì)水生生物)流動(dòng)性:在水中會(huì)溶解。如本品侵入土壤,因?yàn)槠淞鲃?dòng)性甚高,所以可能會(huì)污染地下水。持久性/降解性:容易生物降解。生物累積:預(yù)期沒有顯著的生物累積作用。其它不良反應(yīng):預(yù)期不存在臭氧耗減、光化學(xué)臭氧形成或全球變暖的可能性。.廢棄處置化學(xué)產(chǎn)品處置:應(yīng)盡可能回收或循環(huán)使用。鑒定所產(chǎn)生的物料的毒性和物理特性,以便制定符合有關(guān)條例的適當(dāng)?shù)膹U物分類及廢物處置方法,是廢物產(chǎn)生者的責(zé)任。切勿棄置于環(huán)境、排水溝或水道之內(nèi)。容器的處置:依照目前在施行的條例的規(guī)定,并盡可能應(yīng)該由獲認(rèn)可的廢物收集商或承包商予以處置。地方法例:棄置方法應(yīng)符合適用的地區(qū)、國(guó)家及本地的法律和條例。危險(xiǎn)廢物.部分運(yùn)輸信息 領(lǐng)域(根據(jù)ADR分類):不受管制在ADR條例之下,本品未被評(píng)為危險(xiǎn)物品。國(guó)際海事污染品(IMDG)在IMDG條例之下,本品未被評(píng)為危險(xiǎn)物品。國(guó)際航空運(yùn)輸協(xié)會(huì)(不同國(guó)家的具體規(guī)定稍有不同)在IATA條例之下,本品未被評(píng)為危險(xiǎn)物品。.法規(guī)信息有關(guān)的管制信息并不完整,尚有其它條例適用于本品中國(guó)分類:有害。EC符號(hào):Xn有害。EC危險(xiǎn)警語(yǔ):R22誤吞對(duì)人體有害。EC安全警語(yǔ):不要讓兒童接觸。S13切勿放近食物、飲品及動(dòng)物飼料。S46誤吞后立即就醫(yī)診治,并出示此容器或標(biāo)簽。EINECS:尚未建立。TSCA:尚未建立。分類觸發(fā)組件:含有乙二醇。含有苦味劑。其它信息:GB6944?2005:(危險(xiǎn)貨物分類和品名編號(hào))GB/T16483-2008:化學(xué)品安全技術(shù)說明書內(nèi)容和項(xiàng)目順序GB13690-1992:常用危險(xiǎn)化學(xué)品的分類及標(biāo)志GB12268-2005:危險(xiǎn)貨物品名表。GBZ2.1-2007:工作場(chǎng)所有害因素職業(yè)接觸限值化學(xué)有害因素國(guó)家危險(xiǎn)廢物名錄.其他信息危險(xiǎn)警語(yǔ)R22誤吞對(duì)人體有害?!夯瘜W(xué)品安全說明書』版本號(hào):1.0『化學(xué)品安全說明書』生效日期:『化學(xué)品安全說明書』修訂版:左頁(yè)邊的豎線(I)表示此處是在上一版本的基礎(chǔ)上進(jìn)行的修訂。MSDS(化學(xué)品安全數(shù)據(jù)說明書)分配:所有裝卸本品的人員均應(yīng)熟悉本文件所含的信息k免責(zé)聲明:于此提供的信息基于目前我們對(duì)已有數(shù)據(jù)的理解,對(duì)本品的描述僅為符合健康、安全和環(huán)境的要求。我們并不就本品的具體特征提供任何擔(dān)保。第一頁(yè):EthyleneGlycolCoolant(Antifreeze)-45°cChemicalSafetyDataSheet-MSDSChemicalsandBusinessIdentityChemicalProductsfortheChineseName:-45°cethyleneglycolcoolantUse:antifreezeandcoolantProductCode:XJF0045CompositionInformationRecipeDescription:mixtureofethyleneglycolmonomerandrustinhibitorHazardousIngredients: CAS content%EthyleneGlycol 107211 56.5%Gas-phaseAntirustAgentVCI649 0.5%ExtraDescription:VCI649doesnotcontainnitrite,phosphorus,ammonia,heavymetals,non-toxicbiodegradable,safetyandenvironmentalprotectionandpollution-free.OverviewoftheHazardWarning:orallethal,makingonedizzyanddrowsy,acidosis,heartandlungdiseaseandkidneydiseasecanbethrown.Inhalation:havingaslightlystimulatingeffectontherespiratorysystem,resultinginheadaches,nausea,drowsiness,confusionofconsciousnessandinflammationofthethroatinfection.ContactwithSkin:havingmoderatestimulationoftheskin,exposurecancauseslightirritationforashorttime,andprolongedexposuretolocalredness,Cancausesevereinflammationanddiscomfortcanbecaused.ContactwithEyes:causingsymptomssuchaseyesredandswollen,inflammation,blurredvision,etc.FirstAidMeasuresGeneralInformation:donotdelay,remaincalm,seekmedicaladviceimmediately.Inhalation:shiftcontactstoplacewithfreshair,ifthereisnorecoveryintheshortterm,shouldbepromptlysenttonearbyhospitalsfortreatment.ContactwithSkin:takingoffcontaminatedclothes,washexposedareacleanwithSOAP.Ifstimuluscontinues,pleaseseekmedicaladviceimmediately.ContactwithEyes:flushingwithplentyofwater,ifirritationcannotlessens,pleaseseekmedicaladvice,Swallowing:donotdelay,swallowed,donotlethe/shevomit,ifspontaneousvomitingoccurs,gethis/herheadbelowhips,topreventaspiration,andrushtothenearestmedicalemergencycentersorhospitals.AdviceforDoctors:Poisoningsymptomissomewhatsimilartointoxication,theinitialexcitement,followedbycomaandconvulsions.Symptomsincludedance,goodsleep,vomiting,diarrhea,thirstandseizures.Thelaststageincludesrenalinjurycausedbyacidosis.FireMeasures:Allnonemergencymembersevacuatethefiredistrict.SpecificHazards:dangerousgoodsmayincludecomplexmixtureofairbornesolid,liquidparticulates,gases(smoke),carbonmonoxideandunrecognizedorganicandinorganiccompounds.SuitableExtinguishingMedia:foam,watersprayorspray.Drychemicalextinguishingpowder,dioxide,sandorsoilsuitableonlyforsmallfires.NotApplicableFireExtinguishingSubstances:DONOTsprayWATER.EquipmentforFireProtection:suitableprotectivedevicesincludingclosetotheoriginoffireinthesealedspacerequiredtowearbreathingapparatus.SDillResponseProcessingAvoidcontactwithoverfloworreleasematerial.Onselectionofpersonalprotectiveequipmentguidelines,see8thchapterofmaterialsafetydatasheets.Ondisposalinformation,pleaseseechapter13th.Pleasecomplywithallapplicablelocalandinternationalregulations.ProtectiveMeasures:avoidcontactwithskinandeyes.Usetheappropriatenon-proliferationmeasures,soasnottopollutetheenvironment.Withsand,dirtorotherobstructionstopreventtheproliferationorenteringthedrain,gutterorriver. Removalmethods:formoreliquidoverflow(greaterthan1drum),throughmechanicalmeanssuchasvacuumtrucktransferringtorescuetanksforrecyclingorsafedisposal.Nowatertorinseresidue.Pollutingwasteshouldberetained.Lettheresidueofabsorbentmaterialevaporateorabsorbtheresiduewiththeappropriatematerial,thenhandlesafely.Clearandsafehandlingofcontaminatedsoil.Forlessliquidoverflow(lessthan1drum),throughmechanicalmeanssuchasvacuumtrucktransferringtosealingcontainerswithlabelsforrecyclingorsafedisposal.Lettheresidueofabsorbentmaterialevaporateorabsorbtheresiduewiththeappropriatematerial,thenhandlesafely.Clearandsafehandlingofcontaminatedsoil.AdditionalRecommendation:seriousspillseventunabletohandleshouldberepotedtolocalauthorities.HandlingandStorageGeneralPreventiveMeasures:ifthereisariskofinhalationofsteam,sprayingorsmoke,uselocalexhaustventilationsystem.Toguardagainstfire,properlydisposeofanywipeclothorcleaningofcontaminatedmaterials.Allinformationmentionedaboveincludedinthelocalriskassessmentwouldhelpforeffectivecontrolsystemontransporting,storageanddisposalofthisproduct.Transporting:avoidlong-termorcontinuingcontactwithskin.Avoidtheinhalationofsteamand(or)ofsmoke.Loadingandunloadingbottledproducts,shouldwearprotectiveshoesandproperhandlingtools.Storage:sealedcontainer,inacool,well-ventilatedplace.Labelsandcontainersthatcanbedosedwiththeappropriatesuffix.Storagetemperature:0-50°C/32-122°F.MaterialsRecommended:forcontainerorcontainerliners,softsteelorHDPEshouldbeused.MaterialDoNotApplied:zinc.Avoidcontactwiththeplatingmaterial.AdditionalInformation:polyethylenecontainersshouldnotbeplacedunderhightemperature,becauseitmaycausedistortion.ExDosureControls/PersonalProtection OccupationalExposureLimitschemicalproductsourcetypePPmmg/m3markethyleneglycolACGIHCeiling[aerosol]100mg/m3chemicalproduct source dangeroussignsethyleneglycol ACGIH NotclassifiedasahumancarcinogenExposureControls:levelofprotectionrequiredandthetypeofcontrolmeasuresinaccordancewiththepotentialofcontactconditionsvary.Choosecontrolmeasuresaccordingtoriskassessmentofthelocalsituation.Appropriatemeasuresincludeventilationsufficientenoughtocontrolgasconcentrations.Thisproductismorelikelytorallyafterheatedandthesprayormistintheair.PersonalProtectiveDevices:personalprotectivedevices(PPE)complywithrecommendednationalstandards.ConsultsuppliersofPPE.RespiratoryProtectiveMeasures:undernormalconditionsofuse,respiratoryprotectionequipmentisnotrequiredtoweargenerally.Goodindustrialhygienepracticenotethatmeasuresshouldbetakentopreventtheinhalationofthisproduct.Ifengineeringcontrollingfacilitiescannotremainthedensityofairsufficienttoprotectstaffshealthlevel,selectsuitablerespiratoryprotectivedeviceinaccordancewiththerelevantlegalrequirementsandconditions.Askrespiratoryprotectiveequipmentvendorforcheck.Ifneedingtowearsafetymaskfilter,pleaseselecttheappropriatecombinationofmasksandfilters.Selectafilterssuitableforthemixtureofparticle/organicgasesandvapors[>65boilingpoint°c(149°f)].HandProtection:whenproductsmayhavecontactwithhands,forgettingappropriatechemicalprotection,shoulduseglovesmeetingaboutstandard(suchasEuropean:EN374,UnitedStates:F739)andmadeoffollowingmaterials:PVC,chlorineDingoracrylonitrile-butadienerubbergloves.Suitabilityanddurabilityofglovesdependonhowusing,forexample,frequencyandtimelengthofcontact,chemicalresistanceofthematerialofgloves.Shouldalwaysaskthesupplierforthicknessandsmartnessofgloves.Contaminatedglovesshouldbereplaced.Personalhygieneistheprimarymethodofeffectivecareofhand.Onlyafterwashinghandscleanlythencanweargloves.Afterusinggloves,handsmustbethoroughlycleanedanddried.Non-aromaticmoisturizingcreamisrecommended.EyeProtection:ifpossiblesprayoccurs,pleasewearsafetyglassesandfullfacemasks.ProtectiveClothing:inGeneral,otherthanordinaryworkcloths,specialprotectionmeasuresarenotrequired.MonitoringMethods:needtomonitortheconcentrationofsubstancesinthebreathingzoneofworkersorthegeneralworkplace,toseeifitmeetstheOELandappropriatenessofaccesscontrol.Forsomesubstances,biologicalmonitoringcanalsobeused.EnvironmentExposureControlMeasures:reducingenvironmentalemissions.Environmentalassessmentmustbeconductedtoensurecompliancewithlocalenvironmentalregulations.PhysicalandChemicalPrcwerties Appearance:Orange.Liquidatroomtemperature.Smell:characteristic.InitialBoilingPointandBoilingRange:>100°C/212°FestimatevalueFreezingPoint:typical-46°C/-51°fnodataavailableforreference.FlashPoint:nodataavailableforreference.Upper/LowerLimitsofFlammabilityorExplosion:3-15%(v)AutoignitionTemperature:>200°C/392°FSteamPressure:nodataavailableforreference.SpecificGravity:nodataavailableforreference.Density:typical1.070-1.085kg/m3at15°C/59°FWaterSolubility:fullysolubleDistributionCoefficient:octanol/water:nodataavailableforreference.MotionViscosity:notapply.VaporDensity(air=1):nodataavailableforreference.EvaporationRate(nBuAc=l):nodataavailableforreference.StabilityandReactivityStability:stable.ConditionstoBeAvoided:directsunandextremetemperatures.MaterialtoBeAvoid:strongoxidant.DecompositionofHazardousChemicals:undernormalstorageconditions,willnotformdangerousdecomposition.ToxicologvData EvaluationBasis:theinformationprovidedbasedoncomponentofsimilarproductsandtoxicitydata.OralAcuteToxicity:listedasnoxioussubstancebytheEuropeanCommission.Acuteoraltoxicityinanimalssuchasratsandhumansissignificantlydifferent.Humansaremorevulnerable.Dosesofhumandeathis100ml(1/2glass).Thismaterialalsoshowstoxicandpotentiallylethalforcatsanddogs'eatingability.Swallowingmaymakepeopledizzyanddrowsy.SkinAcuteToxicity:lowtoxicityexpectations:LD50>2000mg/kg.SkinIrritation:maycausemoderateskinirritation(butisnotsufficienttoclassifytheseverity).EyesIrritation:eyeswithmoderatestimulation(butgravityisinsufficienttoclassify).RespiratoryIrritant:inhalationofvapororpowdermaycauseirritation.Allergenicity:expectnotaskinsensitizer.RepeatDosesToxicity:candamagekidney.Mutagenicity:supposednomutationrisk.Carcinogenicity:elementsforcarcinogenicity,itremainstobeseen.ReproductiveandDevelopmentalToxicity:animalfetaltoxicity;treatedassecondaryeffectsofmaternaltoxicity.EcologicalInformationNospecificecotoxicologicaldataforthisproductisdetermined.Aboveinformationprovidedisbasedonknowledgeofthecompositionandecologicaltoxicityofsimilarproducts.AcuteToxicity:expectactuallynon-toxic:LC/EC/IC50>100mg/1(foraquaticorganisms)Mobility:dissolveinwater.Ifthisproductinvadedsoils,becauseitsliquidityisveryhigh,itispossibletocontamina
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