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1、216Vol.21No.6 200712CHINESE JOURNAL OF MATERIALS RESEARCH December2007NiTi(51064010NiTi,:(1 (NiTi;(2NiTi;(3NiTi,.,NiTi,NiTi.,NiTi,TG1391005-3093(200706-0561-09Recent advances in research and development of porousNiTi shape memory alloysZHANG XinpingZHANG Yupeng(School of Mechanical Engineering,South

2、 China University of Technology,Guangzhou510640 *Supported by National Nature Science Foundation of China No.50471038and50671037.Manuscript received on November24,2006;in revised form on May14,2007.*To whom correspondence should be addressed,TelEmail:mexzhang ABSTRACT This paper presen

3、ts a comprehensive review on state-of-the-art of the research and application of porous NiTi shape memory alloys(SMAs,including:(1development history and evolution of the porous NiTi SMAs,microstructural features,mechanical and functional properties of the porous NiTi SMAs;(2main processing methods

4、for fabricating the porous NiTi SMAs,advantages and disadvantages of these methods;(3phase transformation and superelasticity behaviors of the porous NiTi SMAs witha comparison to that of the dense NiTi SMAs.Finally,an overview of future trends in the research andapplication of the porous NiTi SMAs

5、has been given,in particular for biomedicaleld as human body hard tissue implantation and repair materials,intelligent structure and damping deviceeld;and some important research issues on the porous NiTi SMAs are discussed.KEY WORDS metallic materials,porous NiTi alloys,reviews,shape memory eect,su

6、perlasticity, biomaterialNiTi,.NiTi89%20601,.2070, 2090.*5047103850671037. 20061124;2007514.:,.NiTi(,;(, (Ingrowth,(Stress shielding eect.,56221NiTi25.NiTi6,7,;,812.2090NiTi,1320.NiTi(,2123.NiTi(2428.NiTi(6%8%,10%.(.,NiTi,NiTi.,TiNi3(,.,NiTi,29,.,3,.10NiTi,NiTi,NiTi;NiTi(,NiTi.1NiTiNiTi,Ni3Ti Ti2Ni

7、Ni4Ti3.,.,NiTi.,NiTi11,30.,NiTi15,.NiTi,.,(1000,4hNi3Ti18.,.,.NiTi(,.,NiTi,(re-model., NiTi.NiTi,.,.NiTi.,NiTi.,9,10,31; ,.NiTi.,NiTi NiTi6:NiTi563,15.,NiTi.,Ni,Ni;NiTi 50%Ni,Ni;,NiTi,Ni.32, NiTi Ni.,NiTi.,NiTi.,NiTi,(.,NiTi.2NiTi,:.33.,NiTi(1310(6.45g/cm3,.,NiTi,NiTi,NiTi.,Ni Ti NiTi,(conventional

8、sintering,CS3436(selfpropagation hightemperature synthesis,SHS11,3739(hot isostatic pressing,HIP8,17,19,20,40(sparking plasma sintering, SPS41,42.2.1Ti Ni,(<45%19.TiH2,13.,Ni,(,34;Ti,(Ni.,.2.2,.;,.NiTi,(30%70%.;,37,43. TiH2Ti,44;,TiH2.NiTi,.,NiTi11.,;,.2.3NiTi15,19,20,29,40,45.:,;,;,.,(.NiTi15,20

9、,56421.,NiTi,NiTi;,.2.4, ,42.,(12%15%.,.,33.3NiTi, NiTi.NiTi,:,;,.(1%2%5;NiTi8%10%46,NiTi.NiTi,NiTi,.3.1NiTiNiTi.NiTi(B2(B19.NiTi,.NiTi B2B19 NiTi,Ti2Ni Ni3Ti;(.,.A s. ,.,.NiTi,47.NiTi,.,NiTi17,48,49.NiTi,Ni NiTi,;,R;50.NiTi,;,NH4HCO3NiTi51.,NiTi ,NiTi.,NiTi,(400,;400500;500,;,;DSC.,.,;NiTi NiTi Ti2

10、Ni Ni4Ti3 ,Ni4Ti3,Ti2Ni.,NiTi.Ni4Ti3,.Ni4Ti3NiTi., Ni4Ti3,;,Ni4Ti3,R,;,Ni4Ti3,6:NiTi56546,52.,Ni NiTi,Ni4Ti3 Ni.Ni0.1%,10,.,Ni4Ti3 ,NiTi Ni,.,DSC.,.4751h4502h DSC48,NiTi.NiTi(Nb Cu,52.NiTi,NiTi,.3.2NiTi,NiTi;NiTi,.NiTi,.,NiTi2%5%,.,NiTi;,;,NiTi15.,NiTi,.,42;.,Ni4Ti3.,R.,.773K/1h,NiTi(Ti51at.%Ni., Ni

11、4Ti3,53.,.,NiTi15.,NiTi3.NiTi,.NiTi,.,;15.,NiTi,4%54.,.4%,(30%NiTi.,NiTi.(MoriTanaka Selfconsistent8,55,(,.,NiTi.NiTi.,NiTi56,57, NiTi;NiTi,.4NiTi,NiTi566  µ ÃË Ò Ë Ý£. ¦° Þ Ý ¡Þ µ¢ Ä £½   ÕÄ

12、;Ò ÕÄ , Ö ¤Ã Å Ë , µ Ë Þ µ¡ , ¡ÆÞÝ£. ÓÃ, ¡Ã¡ ÖÕ©ÎÙ Ø ° µ Þ . ¡Þ, ¡ Þ ©ß ¿ ˪ . ´ 

13、2;, Þ ¢ Å Î Ø ¡ ¬© Þ Ñ , ÞÂÒ ¨ Ë Ì Ø Þ ¡Þ ¶ ¡ ¹Þ Õ Ý£. ¬, Æ µÏÕ , Àª   À ÐØ § ¡ Í £ , 

14、3; ƽ Ê, Þ © ¡ É «. ½ Ò ÕÄ Þ׿ ÒÂÒ ¨Þ ˫ݧ Ý £, Ó Ã¶ ¡ ¹Þ Õ ½ , ¡ ¹Þ° Ý Ë Ê ¬Æ £

15、, Àµ Ë ¸ ¦Þ© . ß NiTi Î ­ÕÄ ° Þ µ Ò ß Þ È Î, ¡Þ ° ÁÝ ¦ É ·  ÐÆ ­ÕÄ Ý ´¬ÚÏΠ À Í Ò

16、;££ . , Þ ¡Þ µ ± . ; ß NiTi Î ÒÎÍ££  NiTi ÕĦ ¦ Ó 21 Ì ½¹. Óà ÁÞ ¥ À¶ ß NiTi ÕÄ ¡ ¹Þ Õ Æ¢ ÝÊ

17、61;¿ , ½ È §Ä ¡ÞÞ© Ñ¡¡. 5 Ò µ © ± ¦ Ó Ò µ Õ, Ê µÏÕ Ã ß NiTi ÕÄ Þ Ô Ë È Å ÞÔ , ½¹ Õ. Ý ßÉ ,

18、 ݶ ß NiTi Î ­ÕĦ ¾ ´Í Ú ÐÚÒÏÎ¬Ú ²º, Ý Í Ð Ø ¡, § ÍÕÎÔ Þ À £ 4,6,7 . Ó ÃÖ ¢½Ê , Ö 

19、21;¾ , ¡± à ÕÄÞ µ¢ ß NiTi Î ­Õ ÄÞÀ©¶½Á , ß ÈµÒ Ëµ È ¦ Ù Ý £. ß ¿ © Ø Ô Þ ² . Æß¿¹ È,

20、̵ ß¿¹ É ß ¿ ¹ Þ ß NiTi ÕÄ, ÝË Óß ¿ ¶ Ô Þ Þ° . ´¡± , ß NiTi ÕÄ ° Ni « ÌÞ° , Ý ÖÊ µ ,ª Æ

21、76; Ni « Ì Ê ¡. ÓÃ ß È µ ²Ý¢È, ß¿É Ý ¬. NiTi ÕÄÖ Þ«  « Ò ± ¦ ½ÕÄ, ȧ ßÉ. , Ë  ¡ÒÚ Ï¡ 

22、 ß NiTi Õ ¡ Ý Þ± . ÄÊ ¹ (5 d §µ Ï , Ý ß NiTi ÕÄ Þ ß ¿ ÉÒ µ «Ý§ Á ¡ Ô Þ ¥ 32 (HA Þ À, ° À ¡ Ni « Ì . ± ½&#

23、169; ß¿, Ë ß NiTi ÕÄÞ Ni « ¦ © ¦ © ¦ ­­ ­£ ­ ­ ­ ´ NiTi ÕÄ ° ÖØ Ý Þ ÍË , ݧ ½ÍÈ ; ³ ´Ø ­ ÞÎ 

24、60;É ­À , ³Ý§ ¦ §©Ø § . ¬, NiTi ÕÄ ÆÀµ Õ ÎÁ«Õ Õ (Hybrid Composite, ݧ Ö °   §©  °ØÃË, Á ÐË È. ß NiTi

25、 Î ­ÕÄÕ ß ÈÞ Ö °­ Þ Í Ë, ° NiTi ÕÄÖ ° Þ¡ ­ À . Ó µ 15, ß ¿ ÎÒß Þ ¸ ¾ Ö Í Ë°Ø Þ . ¿Þß¿

26、  Ô Þߪ¸¾« Àµ ÞÉÐ, Ö Í Ë. ß NiTi ÕÄ ²ÞÓÞ Ò ½Í ÈÕÝ Í ÖË Ð±Ë ÌÛ, §¹É©Ë, ½ Í©&

27、#222;ʯ. ÓÃ, ß NiTi ÕÄ ÐË ÈÒ§©Ø ± Þ Ó ¶ Û. ´ NiTi Î ­ÕÄ ½Í È  ÈÒ§©Ø ÞÓ Ò , ¦ ¨Ý ¡ÂÁ . 

28、2; ÛÞ È · Ò Þ½ 58 ȵ¦½ Í©Ò , Ó Ö ×¡ NiTi ÕÄ Þ Ô ÍÞ µµ 59,60 . ¬, Ò Î ­¦ Þ Ö Ê ¯ÒÍ©§ ¡¨ ¡&#

29、222; , È Æ É 61,62 Æ ¨ . , ßÒ NiTi ÕÄ Ð Ë ÈÒ§©Ø Þ ÂÝ ¡ ± 62,63 , ÖÕ ÝÞ°: (1 Ù , §©Ø ° Þ ÐÆ (2 © ÒÃ Þ ¬

30、87;Ñ, ±´ È¿ Þ Æ , Ò§ ÒÃË ; (3 ÖË © Å Ø Þ Ò© Ë ; (4 Ö×ÍË ( Í , ¡¨ ÉÞ ¨ °Ø Þ × ; (5 ½ Öص , ÖÃ

31、03;ÎÙ Þ Ø , ÄÕÚÞ ; (6 ¢Ý§ Ê º Þ . Ö ¯, ßÒ NiTi ÕÄ ± ¢ ¡Â , : (1 ´ ß NiTi ÞÎ ­À NiTi , Ö© Ë · ; ( ´ 10%, ²µÎ &#

32、200; (2 Ö¬»Ë À ¹ ¿ ÒÈ Î Þ ¢© , Ë À¹Ó µ ( ,¥ © ÞË ± Þ½¦ ² À¹ÃƦ© Þ 100 ; (3 È µ Òª­ Ý¥ Ø ,

33、°¶ ° ÊÞ Ë° ÊÞ Æ© ÐÆ, Ø È Ò ÈÎ ¿Æ ¾Ï Ì»Ò Ã ØÞÎ ÔÕ NiTi ¦ ¦ ¦ ¢ ¦ ¦ ¦ « Õ Ù¡¨ ; (4 

34、0;Ê Ò Þ 6 NiTi ¦ ¨Ý ¡ÂÙÝÊÁ, Óà ² ¢ Ý Ó¡Â ° . Ê°  £: (1 ¨ß ¿ È Î ß NiTi ÕÄ Þ , Öà À© Þ Ò &

35、#180; Þ . ÄÝ ß¿ ÎÒÃË ± Ð ÌÞ ß NiTi ÕÄ ²Þ Ý£¢°¡¨Þ Ð. ½¦ ¤ Ò¡ ¨ Þ ß ¿ Î, « Ý £ ß NiTi ÕÄ

36、6; Ý¥ ¯´Þ À© Ë . ÖÝÞÀ© Þ ß NiTi ÕÄ¢ ¡Â° . , ´ ¡ ££Ò Þ ß NiTi Î ­ÕÄÞß¿È ¢ ½ Ê ¸ ¾½ 

37、12; , ß ¿ ¹¢ ½ Ê ; ½ ¦ Í Þ£ É ¥Ô ¡ °Àß ¿È , ´ È Í Þ£ É ¥ °¯, ÀÍ¶Ë ÆÒ ÐÆÔ ¬ , ¹ ËÊ Í &

38、#176; Õ Æ  ÊÞ× Ë ; ¹ , ß ¿¹Þ ¥ ݧ Í Ö Þ¡   £Ò   ¡ Ô ÜµÞ . ß NiTi ÕÄ Þ , ¶ ÃÖ­ (2 ² Ò Ô Þµ Î

39、;   ÏÒѶ. ß NiTi Î ­ÕÄÞ Ô ­ Þ ¬Äݶ½ ¸ Ï, Ø ´ ² à ٠ÞÝØ Ñ¶ÒÌ ÝÞ, Öý Ù ¡É ¼ °

40、0; ß NiTi ÕÄ Þ Ô Ò Î ­À ¶ ÕĽ¦, Ý ²     È Ò¨ ± µ§ Þ¬±. (3 ß NiTi ÕÄ µ Ë   µ ÃË   µ Ni « ¬ Þ 

41、98;Ѷ, § Ö µ ¬ ª ÞÓ . , ß NiTi Î ­ ÕÄ Þ µ ÑÀ , Ni « ·Ì°  ©µÑ, Ý Ê¡¿Ó . Ì ÖÝ µ¢ ²º Þ , ß NiTi Õ&

42、#196; Þ ÈÒ Ë Ý Þ ØØ , Öà µ  ¸¬ ± . ß NiTi Î ­ÕÄ Í (4 Æ Ë ¹É , ¡Â ° ¢ ° ÊØ ÏÃË Ë ¹ÉÞ ¬,   &

43、#207;, Ò ÖÚ ß Î¦ ­ÕÄÞ È ¤Ò ° Ö Á ¡ØØ° Ý Þ µ ¢ ÒË ¹É Í Ø ÞÎ ¦ ­ À   Ô Ò Î¦ ­ÕÄÞ &

44、#223; ȵ ÌÞ½¦´ ¤ Ö ÄÕ´ ¡ Ò § Í Æ ½Í¥ ÄÝ ß Î ¦ ­ÕÄ Þ Ó . ÞÁ ÄÉ , µÀ¢È ( : NiTi , Ø 6 Ñ¶Ë &#

45、207; °ÆÖÅÔ Ë 567 ß ¿ ζ ²  Ô ÒÉÐ (Æ Í ¹Þ ¸ , ¢ ° ½¨  Þ ; ß NiTi ÕÄÞ Í ÞÓ Ý Ø Å¿ Ò Õ Þ 

46、72; Ë, Ö . § ( . NiTi . ÆÜ Ü Æª § Õ Æß (2006, 07-09 ¨ ¶ ¼Û Ó¤ ±¯ ÜÕ Ö˦ G. Eggeler Íß ° ß ß¼ 1 S.Abkowitz, J.M.Slerglej, R.R.Regan, Titanium-Nick

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