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遲400 000 0 -IG?.?iy”臥”彗咕軋 畑即弘自學文獻DennisP.SIromrnenl,EllisR.Lippincon,CommentsonInfinitePointGroups,JournalofChemicalEducation,Volume49,Number5,May1972:341DennisP.Strommen,APedagogicalApproachtotheDirectProduct,JournalofChemicalEducation,Volum56,Number4,Aprill11979:248F.Leung,MolecularTermSymbols,JournalofChemicalEducation,Volume58Number5May1981:自學文獻DennisP.SIromrnenl,EllisR.Lippincon,CommentsonInfinitePointGroups,JournalofChemicalEducation,Volume49,Number5,May1972:341DennisP.Strommen,APedagogicalApproachtotheDirectProduct,JournalofChemicalEducation,Volum56,Number4,Aprill11979:248F.Leung,MolecularTermSymbols,JournalofChemicalEducation,Volume58Number5May1981:431第四章 有趣的物理化學現(xiàn)象見45分鐘光盤錄像第一節(jié)MercuryBeatingHeart汞心臟Najdoski,Metodija;Mirceski,Valentin;Petru?evski,VladimirM.;Demiri,Sani,MercuryBeatingofChemicalEducation,Heart:ModificationstotheClassical
JournalofChemicalEducation,Vol.Demonstration,Journal84No.8August2007:1292采用電極代替鐵釘,在Theclassicmercurybeatingelectrolytes.Byanalogywiththeclassicalvariantofthemercurybeatingheart(MBH),severaldemonstrations oftheMBHwithvarioussolutions ofelectrolytesproposed,wherethebeatingisgeneratedbyexternalpowersupply.DetailsforperformingtheexperimentsofMBHaregiveninthisarticle.Mercuryoscillationswereobservedwithoutphysicalcontactofmercurywiththeelectrodes.Whenaqueoussolutionofsodiumsulfateoralkalihydroxidewasusedamalgamformed(evenwithoutdirectcontactbetweentheelectrodeandamechanismisproposedforthisphenomenon.NaOH溶液中汞心臟也能挑動。heartdemonstration ismodifiedwithvariouswere采用電極代替鐵釘,在Theclassicmercurybeatingelectrolytes.Byanalogywiththeclassicalvariantofthemercurybeatingheart(MBH),severaldemonstrations oftheMBHwithvarioussolutions ofelectrolytesproposed,wherethebeatingisgeneratedbyexternalpowersupply.DetailsforperformingtheexperimentsofMBHaregiveninthisarticle.Mercuryoscillationswereobservedwithoutphysicalcontactofmercurywiththeelectrodes.Whenaqueoussolutionofsodiumsulfateoralkalihydroxidewasusedamalgamformed(evenwithoutdirectcontactbetweentheelectrodeandamechanismisproposedforthisphenomenon.NaOH溶液中汞心臟也能挑動。heartdemonstration ismodifiedwithvariouswereanaselectrolyte,andmercuryandrop)S''S''[34]Keizer,J.;Rock,P.A.;Lin,Shu-WaiJ.Amer.Chem.Soc.1979,101,5637-5649[34]Keizer,David,ChemicallyinducedpuIsationsofinterfaces: Themercurybeating[35]Avnir,David,ChemicallyinducedpuIsationsofinterfaces: Themercurybeatingheart,JournalofChemicalEducation,Volume66Number3March1989:211Whenanironneedlejusttouchesamercurydropsubmergedinapoolofanacidicsolutionofanoxidizer,itpuIsatesrapidlyinamodethatresemblesabeatingheart.yr/ 1?丄3--■I:.k[36]JamesL.Ealy,Jr,GalliumBeatingHeart,GalliumBeatingHeart,JournalofChemicalEducation.Volume70Number6June1993:491OscillatinggalliuminaPetridishoffersanexcitingdemonstration(Hg)用Ga代替自學文獻[15]MartinSanchez,M.;MartinSanchez,MaT.Themercurybeatingheart,JournalofChemicalEducation,December1993:1042該文獻提到堿性溶液心臟不能起跳。Whoisthediscovererofthephenomenondescribedbythetitlearticle?第二節(jié)OscillatingReaction振蕩反應精講文獻[37] Prypsztejn, HernanE.Chemiluminescent Oscillating Demonstrations:ChemicalBuoy,theLightingWave,andtheGhostlyCylinder,JournalofChemicalEducation,JournalofChemicalEducation,Vol.82No.1January2005:53TheAchemiluminescentoscillatingreactionispresentedinwhichachemiluminescentsubstanee(luminol)interactswithachemicaloscillatorproducinganoscillatingchemiluminescenee.Itisanexcellentwaytointroducecomplexconceptssuchasfar-from-equilibriumconditions,nonlineardynamicsandbifurcation,andchaostheories.Melka,RichardF.;Olsen,Gary;Beavers,Lindsay;Draeger,J.AThekineticsofoscillatingreactions:Laboratoryexperimentforphysicalchemistry,JournalofChemicalEducation,Volume69Number7July1992:596振蕩反應可以用偏微分方程的類周期解來模擬 )振蕩反應可以用偏微分方程的類周期解來模擬 )25.0035,0025.00—z:115.005.00-5,00■5.005,00115.00X■5.005,00115.00X25X0 35X0自學文獻[16]JohnA.PojmanandWilliamW.West,AUnifiedPhysicalChemistryLaboratoryBasedonOscillating ReactionsandTraveling Fronts,JournalofChemicalEducation,January,1996,Vol.73No.1:35第三節(jié)BlueBottle 藍瓶反應J.A.Campbell,Kinetics-Early andOften,JournalofChemicalEducation,Volume40,Number11,November1963:579A.GilbertCook,RandiM.Tollive,JanelleE.Williarns,TheBlueBottleExperimentRevisited,JournalofChemicalEducation,1994,Vol.71No.2:160WalterR.Vandaveer,etal.TheBlueBottleRevisited,JournalofChemicalEducation,Vol.74No.4April1997:402WhitneyE.Wellman,MarkE.Noble,TomHealy,GreeningtheBlueBottle,JournalofChemicalEducation,Vol.80No.5May2003:537
第四節(jié)MemoryMetal記憶反應精講文獻Gisser,KathleenR.C.etalMemoryMetal:A"Smart"MaterialExhibitingaSolid-StatePhaseChangeandSuperelasticity, JournalofChemicalEducation,January,Volume71Number4April1994:335shape-memory,mechanical, and)illustratethe馬氏體與奧氏體AusteniteB&ndSeveralsimpleexperimentsthatacousticalpropertiesofNitinol.(shape-memory,mechanical, and)illustratethe馬氏體與奧氏體AusteniteB&ndMarten&iteMarten&iteMartensiteVol.82JCEEditorialStaff,MemoryMetal,JournalofChemicalEducationVol.82No.10October2005 :1488AInthisActivity,studentsinvestigatethepropertiesofwiremadefromnitinol metalandcompareitspropertiestowiremadefromothermetalssuchascopperandgalvanizedsteel.Usingtheobservedpropertiesofnitinolmetal,studentsthendesign(andmaymake)atoythatwouldusenitinolmetaltooperate.
自學文獻[17]GeorgeB.Kauffman,IsaacMayo,TheThermobile?:ANitinol -BasedScientificToy,JournalofChemicalEducation,Vol.75No.3March1998:313第五節(jié)Superconductivity 超導體ArthurB.Ellis,Superconductors,JournalofChemicalEducation,Volume64Number10October1987:837TheMelssnerEffect andLevitationSahu,Devaraj;Langner,Andreas;George,ThomasF.BCSprimer:Aguidetocomputationalmethodsinsuperconductivity theory,AconcisesurveyoftheimportantJournalideasofthe Bardeen-Cooper-Schrieffer(BCS)theoryofsuperconductivity.JournalofChemicalEducation,Volume67Number9September1990:738Matsen,F.A.Threetheoriesofsuperconductivity,TheLondon,BCS,andthesudden-polarizationtheories.JournalofChemicalEducation,Volume64Number10October1987:842超導體的三種理論ChemicalFrederickH.JJuergens,ArthurB.Ellis,GuntherH.Dieckrnann,RonaidI.ChemicalPerkins.LevitatingaMagnetUsingaSuperconductiveMaterial,JournalofEducation.Volume64Number10October1987:8511::怕’r;裂:1::怕’r;裂:;.I.■-yr;■■氣…*-J.AnthonyL.Jacob,Charles1.Pechmarm,andArthur6.Ellis,ADouble-DeckerLevitationExperimentUsingaSandwichofSuperconductors,JournalofChemical■… ■ ..;:: :-:r ?..:;;■ f■ ■… ■ ..;:: :-:r ?..:;;■ f■ Education,Volume65Number12December1988:1094ay2u??「,■: 于:冷略5-獲■孫亦總爛”竝皿汽滬:心.諾J■■■■ ■ ■■'■■Jh.y'■勺-J.. ..:.p:一.?蘭燭門J.McHale,R.Schaeffer,andR.E.Salornon ,Demonstratinghightemperature,JournalofsuperconductivityinthechemistrylabthroughtheMeissnereffectChemicalEducation‘Volume69Number12December1992:1031,Journalofliquidnitrogenmagnetbalance—sample□(Q百希4g)support自學文獻[18]PeterPreparationofNumber6June1993:497I.Djurovichliquidnitrogenmagnetbalance—sample□(Q百希4g)support自學文獻[18]PeterPreparationofNumber6June1993:497I.Djurovich,RichardJ.YBa2Cu3O7-xSuperconducors,超導體的制備watts,JournalASimpieandReliableChemicalofChemicalEducation,Volume70第六節(jié)Ferrofluid磁流體Patricia Berger,NicholasB.Adelman,B.Ellis,GeorgeC.Lisensky, PreparationBeckman.DeanJ.Campbell,ArthurKatieJ.andPropertiesofanAqueousFerrofluid,JournalofChemicalEducation,Vol.76No.7July1999:943KerroKnox,Ferrimagnetism,JournalofChemicalEducation,Volume66Number4April1989:337**一第七節(jié)Chemiluminescenee化學發(fā)光Economou,D.Papargyris,andJ.Stratis,AutomatedFlow-InjectionInstrumentforChemiluminesceneeDetectionUsingaLow-CostPhotodiodeDetector,JournalofChemicalEducation.Vol.81No.3March2004,406WILLIAMGEORGEEEDY,ThePhenomenaofChemiluminescenee,JournalofChemicalEducation,1944:142HarryD.Gafney,ArthurW.Adamson,Chemiluminescenee,JournalofChemicalEducation,Volume52,Number7.July1975:480NHjOn+20H-It
oluminolNHjOn+20H-It
oluminolOnilJN-(嚴Illi
0dianionoflumirxjlNHjNHjO"0"+ZHjO6c:aqrauEJstateof王也alaheton1 +hv+2HjD+Nq6c:aqrauEJstateof王也alaheton1 +hv+2HjD+Nqcr第一節(jié)光致變色材料研究學時第二節(jié)熱致變色材料研究學時第三節(jié)催化聚合材料研究學時exertedstale3-amirBphittialateton第五章化學研究結合我們的工作,講授光致變色材料、熱致變色材料、催化聚合材料?!癐ntermediateionstabilityandregioselectivityinpropenepolymerizationusingneutralsalicyladiminatonickel(ll)andpalladium(II)compiexesascatalysts”,YueLiu,MichaelG.B.Drew,YingLiu,JournalofMolecularStructure:THEOCHEM,2007,809,29“AbIntioandKineticStudyonCH3RadicalReactionwithH 2CO;Cheng-BinChe,HuiZhang,XiangZhang,YueLiu,BoLiu,TheJournalofPhysicalChemistryA2003,107(16) ,2929-2933“Thecrucialimportanceofagosticinteractionsinintermediatesformedinpropylenepolymerizationusingneutralsalicyladiminatopalladium(II)andnickelcompiexesascatalysts”,YueLiu,MichaelG.B.Drew,YingLiu,JournalofMolecular
Structure:THEOCHEM,2007,821,30 -41“ADFTstudyofpropylenepolymerizationusingneutralsalicyladiminatonickel(II)andpalladium(II)ascatalysts ”,YingLiu,MilinZhangaMichaelG.B.Drew,Zhao-DiYang,YueLiu,JournalofMolecularStructure:THEOCHEM,2005,726,277-283.“ThermalIrreversibilityStudyontheAnhydridesbyDensityFunctionalCalculationsElectrocyclicReactionofDiarylMaleic”,YueLiu,QiWang,YingLiu,,373(3-4),338-343.自學文獻“DesignandTheoreticalStudyofNickelCatalystsforsyndiotacticElectrocyclicReactionofDiarylMaleic”,YueLiu,QiWang,YingLiu,,373(3-4),338-343.自學文獻“DesignandTheoreticalStudyofNickelCatalystsforsyndiotacticPolylefins”,LIU,Ying;LIU,Yue;Drew,MikeG.B.;LIU,Jia-Wen,ChineseJournalofChemistry,2003,21(5),481-484[20]RegioselectivityStudyonPropylenePolymerizationCatalyzedbyNeutralYANGZhao-D,LIUYue,LIUSalicyladiminatoPd(II)ModelComplexwithYing,ChineseJ.Struct.Chem,2005,24,723-728“Conformationof1,2-DimethoxyethaneBai-qing,SUZhong-min,WANGQi.,Chemical17(3),315-317)DFTMethod”inwater”,ResearchinLIUYue,YANGXiao-zhen,DAIChineseUniversities,2001,“ConformationandChainPackingStructuresofPoly(p-PhenyleneBenzobisthiazole)byMolecularSimulation, ”,YANGXiao-Zhen,LIUYue,HSUShawLing,ChineseJournalofPolymerScience,1997,15(4),295-304“AStudyofPackingStructureofPoly(p-PhenyleneBenzobisthiaole)byMolecularSimulation,ChineseChemicalLetters”,YueLIU,XiaoZhenYANG,1993,4(9),779-782第六章基礎理論研究大多數(shù)是是結構化學課程的延伸,內容廣泛。第一節(jié)節(jié)面與原子核位置精講文獻“WhereShouldtheNucleiBeLocated ”YingLiu,YueLiu ,MichaelG.B.Drew,JournalofChemicalEducation,2005,82(2),320-322我們在美國化學教育上發(fā)表的關于節(jié)面、原子核位置的教學論文。詳見《理論化學》235-240頁。第二節(jié)尖晶石與反式尖晶石的穩(wěn)定性精講文獻1982:357-358周公度,無機結構化學,科學出版社,1982:357-358F.AlbertCotton ,LigandFieldTheory,JournalofChemicalEducation,Volume
41,Number9,September1964:466JackL.Lambert,SpinelModelsforDemonstratingCrystalFieldStabilizationJournalofChemicalEducation.Volume41,NumberI,January1964:41尖晶石與反式尖晶石的穩(wěn)定性。第三節(jié) 球對稱性中原子軌道的特征標精講文獻RogerL.DeKock,AlbionJ.Kromminga,TimothyS.Zwier,“Thesymmetryofatomicstatesandatomicorbitals, ”J.Chem.Educ.56(8),510-511(1979)經典文獻。球對稱性中原子軌道的特征標Theformulatocalculatethecharacters7Theformulatocalculatethecharacters7ofareduciblerepresentationfromtheatomicorbitalsonthecentralatominsphericalsymmetryis.Thecharactersobtainedbytheequationforatomicorbitalsfromstoharelistedinthefollowingtable.Table.Charactersobtainedfromequation1foratomicorbitalsfromstohl*represention02 /3Z(C3)/2/(C4)徊/(C2)0s11111P3-1012d51-1-13f7-11-14g91015h11-1-11
第四節(jié)位置對稱性與雜化軌道精講文獻R.L.Flurry,Jr.,SiteSymmetryandHybridizedOrbitals,JOURNALOFCHEMICALEDUCATION,Volume53.Number9,September1976:554經典文獻。用位置對稱性構造雜化軌道PointGroupXYXYXXXXXYXYXXXXY(Y)AX.Vng'AXjVj3AXflX5gftX*XYc汕Gm%叫XgAX,XGpX罠X.XJ,巧第五節(jié) 結構化學課程相關基礎文獻精講文獻與結構化學課程相關淺易論文RogwL.DeKock,WayneB.Bosma,TheThree-Center, Two-ElectronChemicalBond,JournalofChemicalEducation,Volume65Number3March1988195DanielA.JelsklandThomasF.George,Clusters:LinkbetweenMoleculesandSolids,JournalofChemicalEducation‘Volume65Number10October1988:879Russell,JoanM.SimplemodelsforteachingequilibriumandLeChatelier'sprinciple,JournalofChemicalEducation.Volume65Number10,October1988:871'snoraPrinciple?.Chemistry'snoraPrinciple?.ChemistryinBritain,1984(9):802IrwinCohen,JanetDelBenel ,HybridOrbitalsinMolecularOrbitalTheory,JOURNALOFCHEMICALEDUCATION,Volume46,Number8,August1969:487WilliamA.Bernett,LocalizedandDelocalizedMolecularOrbitalDescriptionsofMethane,JOURNAQFCHEMICAlEDUCATION,Volume46,Number11,November1969:746JurgWaser,HybridOrbitalsandAtomicConfiguration,JOURNALOFCHEMICALEDUCATION,Volume48,Number9,September1971:603D.S.Urch,Pi-BondinginTetrahedralMolecules,JOURNAIOFCHEMICAIEDUCATION,Volume47,Number9,September1964:502
DavidE.Lewis,OrganizingOrganicReactions:TheImportaneeofAntibondingOrbitals,JournalofChemicalEducation,Vol.76No.12December1999:1718[77]R.M.Gavin,Stereochemistry,[76]M.K.Orloff,N.B.Orloff,IllustratedMolecularOrbitalsofFormaldehyde,JOURNALOFCHEMICALEDUCATION,Volume50,Number6,June1973:400[77]R.M.Gavin,Stereochemistry,Iorganic1969:413Iorganic1969:413JOURNAIOFCHEMICAlEDUCATIONVolume46,Number7,July,MolecularGeometryPredictionsusingSimpleMOTheory,,MolecularGeometryPredictionsusingSimpleMOTheory,JOURNALOFCHEMICALEDUCATION,Volume55,Number7,July1978:,AX,,systems(n=2-7)412RobertG.A.R.Maclagan,Symmetry,IonicStructuresanddOrbitalsinSF6,JOURNALOFCHEMICALEDUCATION,Volume57,Number6,June1980:428S.M.Blinder,QuantumAlchemy:TransmutationofAtomicOrbitals,JournalofChemicalEducation,Vol.78No.3March2001:91GeneratingSetsofOrthonormalVolume50,Number2.FebruaryGeneratingSetsofOrthonormalVolume50,Number2.FebruaryHybridAtomicOrbitals,JournalofChemicalEducation,1973:114BeyondtheSingleCenter—BeyondtheSingleCenter—WaysToReinforceMolecularOrbitalTheoryinanInorganicCourse,JournalofChemicalEducation,Vol.81No.7July2004:997JamesF.Harrison,DanielB.Lawson,SomeObservationsonMolecularOrbitalTheory,JournalofChemicalEducation,Vol.82No.8August2005:1205[84]TerryS.Carlton.WhytheLower-EnergyTermofSingletDioxygenHasaDoublyOccupied兀*Orbital,JournalofChemicalEducation.Vol.83No.3March2006:477JohnMorrisonGalbraith,OntheRoleofdOrbitalHybridizationintheChemistryCurriculum,JournalofChemicalEducation,Vol.84No.5May2007:783MichaelA.McKinney,DanielT.Haworth,SigmaBondedCyclopolyenylMetalCompIexes:Sigmatropicrearrangements,JournalofChemicalEducation,Volume57,Number2,February1980:110MorcenoY.Dorensbourg,DonaldJ.Dorensbourg,InfraredDeterminationofStereochemistryinMetalCompIexes:Anapplicafi.onofgrouptheory,JournalofChemicalEducation,Volume47,NumberI,January1970:33Chenier,PhilipJ.Anovelmethodofrepresenting orbitalsinthreedimensions,JournalofChemicalEducation,November1980:788J.D.Bradley,G.C.Gerrans ,FrontierMolecularOrbitals:Alinkbetweenkineticsandbondingtheory,JournalofChemicalEducation,Volume50,Number7,July1973:463
[90]OlivierHenri-Rousseau,FernandTexier,ApplicationoftheFrontierOrbitalTheorytotheInterpretationofthehammettCorrelations,ChemicalEducation,Volume55.Number7,July978:437[91]RalphG.Pearson,OrbitalTopologyandReactionMechanisms,JournalEducation,Volume[90]OlivierHenri-Rousseau,FernandTexier,ApplicationoftheFrontierOrbitalTheorytotheInterpretationofthehammettCorrelations,ChemicalEducation,Volume55.Number7,July978:437[91]RalphG.Pearson,OrbitalTopologyandReactionMechanisms,JournalEducation,Volume58Number10October1981:753[92]AnthonyJ.Duben,FrontierOrbitalAnalysisoftheBathochromicShiftofMonosubstitutedBenzens,JournalofChemicalEducation,Volume62Number5May1985:373[93]RonaldS.Lenox,Electrons,Bonding,Orbitals,andLight:Aunifiedapproachtotheteachingofstructureandbondinginorganicchemistrycourses,JournalofChemicalEducation,Volume56.Number5,May1979:299[94]RobertB.Davidson,Back-of-the-EnvelopeMolecularOrbital"Calculations":Usingbondorbitalsandgrouptheoty,JournalofChemicalEducation,Volume54,Number9.September1977:531[95]M.R.V.Sahyun,TheSilverHalides:AlocalizedmolecularJournalofChemicalEducation,Volume54,Number3,March1977:143[96]B.M.Fung,MolecularOrbitalsandAirPollution,JournalofVolume49,Number1,January1972:26[97]NelsonF.Phelan,H.H.Jaffe,MiltonOrchin,AMolecularMolecular
JournalofofChemicalorbitalChemicaltreatment,Education,OrbitalDescriptionSpectradiagrams,1983:562oftheNon-ClassicalIonin1,2Rearrangements,JournalofChemicalEducation,Volume44,Number1I,November1967:626Spectradiagrams,1983:562[98]H.H.Jaffe,DavidBeveridgel,MiltonOrchin,UnderstandingUltravioletofOrganicMolecules:SomelimitationsontheuseoforbitalenergylevelJournalofChemicalEducation,Volume44,Number7,July1967:383[99]A.KurtzCarpenter,4s,34What?,JournalofChemicalEducation,JulyClaudeE.Wintner,Two-DimensionalChiralityinThree-DimensionalChemistry,JournalofChemicalEducation,Volume60Number7July,1983:550C.W.Haigh,TheTheoryofAtomicSpectroscopy:jjCoupling,IntermediateCoupling,andConfigurationInteraction,JournalofChemicalEducation,Volume72Number3March1995:206E.R.Tuttle,AllowedvalueofJinjjcouplingofequivalentelectrons,Am.J.Phys.,July,1980:539自學文獻ScottT.Hill,SociologyandPauli'sAufbauRules,JournalofChemicalEducation,Volume64Number1,January198727RobertA.Stairs,Anotationfororbitals,JOURNALOFCHEMICALEDUCATION,November1988:980JohnJ.Fortrnan,PictorialAnalogiesVII:QuantumNumbersandOrbitals,JOURNALOFCHEMICALEDUCATION,Volume70Number8August1993:649Graham,DonaldM,A3-DDiagramoftheRelationshipsamongAtomicOrbitals,JOURNALOFCHEMICALEDUCATION,March1996:210AlbertHaim,TheRelativeEnergiesofMolecularOrbitalsforSecond-RowHomonuclearDiatomicMolecules,TheEffectofs-pMixing,JOURNALOFCHEMICALEDUCATION,Volume68Number9September1991:737RobertA.Stairs,Anotationfororbitals,JOURNALOFCHEMICALEDUCATION,November1988:980習題、實踐(實驗、實訓、實習)指導大綱中的自學文獻、因為學時限制沒有講到的精講文獻、備用章節(jié)用作習題、實踐指導內容(見教案)第40第40頁第45頁自學部分文獻四試卷及參考答案學生結課報告錄像:在10分鐘內用英語講清楚一個問題。楊雪07學生結課報告錄像:在10分鐘內用英語講清楚一個問題。楊雪07學生結課報告錄像:“分子軌道中原子核的位置”NucleiBeLocated研究”第一節(jié)“節(jié)面與原子核位置”講解文獻“WhereShouldthe”(J.Chem.Educ.2005,82(2),320-322 ,選自第六章“基礎理論果)。要講明白的這個問題并不容易。中的文獻[61],該文獻是項目申請人的一項教學研究結學生在10分鐘內基本將問題講清楚了。果)。要講明白的這個問題并不容易。Chatelier原理”,是第一章“化學平衡理論”所涉及的因為涉及多元函數(shù)微分等廣泛內容,用中文也很學生用大約10分鐘時間,講清楚了問題:“與我們通常理解的平衡移曲艷鎂07學生結課報告錄像:Chatelier原理”,是第一章“化學平衡理論”所涉及的因為涉及多元函數(shù)微分等廣泛內容,用中文也很學生用大約10分鐘時間,講清楚了問題:“與我們通常理解的平衡移動理論不同,加入一種物質,可以出現(xiàn)化學平衡向生成該物質方向移動的情況”。五參考文獻目錄以下文獻申請者都認真地研讀過,還有一些讀過的好文獻由于時間久遠一時找不出來。因為讀過,可以保證每一篇教學文章都與大學本科生的水平相適合,而且有一定深度,其中任意一篇文獻都值得一讀。精講文獻列出102篇,自學文獻列出29篇。精講部分文獻第一部分主要章節(jié)第一章化學平衡理論文劉躍,劉穎,楊小震,化學通報,2004,3,51文劉躍,賀子如,劉穎,《平衡理論》,化學工業(yè)出版社, 1995劉穎,劉躍《理論化學》,黑龍江科學技術出版社, 2002J.deHEER,Theprincipleof.LeChatelierandBraun,JOURNALOFCHEMICALEDUCATION,VOLUME34,NO.8,AUGUST,1957:375RichardS.Trepfow,LeChatelier'sPrincipieAreexaminationandmethodofgraphicillustration ,JOURNALOFCHEMICALEDUCATION,Volume57,Number6,June1980:417⑹LewisKatz,ASystematicWaytoAvoidLeChatelier'sPrincipleinChemicalReactions,JOURNALOFCHEMICALEDUCATION,Volume38,Number7,July1961:375,JOURNALOFCHEMICALFriedrichG.Helfferich ,,JOURNALOFCHEMICALEDUCATION,Volume62Number4April1985:305GeorgeM.Bodner,OntheMisuseofLeChatelier'sPrinciple forthePredictionoftheTemperatureDependeneeoftheSolubilityofSalts,JOURNALOFCHEMICALEDUCATION,Volume57,Number2,February1980:117R.Fernandez-Prini ,LeChatelier'sPrincipleandthePredictionoftheEffectofTemperatureonsolubilities,JOURNALOFCHEMICALEDUCATION,Volume59,Number7July1982:550L.K.Brice,LeChatelier'sPrincipie:TheEffectofTemperatureontheSolubilityofSolidsinLiquids,JOURNALOFCHEMICALEDUCATION,Volume60Number5May1983:387J.N.Spencer, gandcG^,JOURNALOFCHEMICALEDUCATION,Volum51,Number9,September1974:577H.R.Kemp,TheEffectofTemperatureandPressureonEquilibria: ADerivationofthevan'tHoffRules,JOURNAIOFCHEMICAlEDUCATION,Volume64Number6June1987482ZhellgXianmin,TheFreeEnergyPredictionofReactionDirectionandthePrincipleofLeChatelier,JOURNALOFCHEMICALEDUCATION,Volume66Number5May1989:401H.R.Kemp,Gibbs'ParadoxforEntropyofMixing,JOURNAQFCHEMICAIEDUCATION,Volume62Number1January1985:47J.J.MacDonald.TotheEditor,JOURNAIOFCHEMICAlEDUCATIONVolume63Number8August1986:735
H.R.Kemp,TotheEditor,JOURNALOFCHEMICALEDUCATION,Volume63Number8August1986:736第二章原子光譜項2008:60-632008:60-63[18]江元生,結構化學,高等教育出版社, 1997:[18]江元生,結構化學,高等教育出版社, 1997:50-54[19]MelGorman,RulesforWritingGroundStateRussell-SaundersSymbols,JournalofChemicalEducation,Volume50.Number3,March19731189[20]KennethE.Hyde,MethodsforObtainingRussell-SaundersTermSymbolsfromElectronicConfigurations,JOURNALOFCHEMICALEDUCATION,Vokme52,Number2,February1975:87[21]J.Vicente,ASimpleMethodforObtainingRussell-SaundersTermofChemicalEducation,Volume60Number7July1983561[22]Jyh-HorungChen,AtomicTermSymbolsbyGroupRepresentationofChemicalEducation,Volume66Number11November1989:893[23]DarlH.MeDaniel,SpinFactoringasanAidintheDeterminationTerms,JournalofChemicalEducation,Volume54,Number3,March19771Symbols,JournalMethods,JournalofSpectroscopic147Russell-SaundersE.M.R.Kiremire,ANumericalAlgorithmTechniqueforDerivingRussell-Saunders[R-S)Terms,JournalofChemicalEducation,Volume64Number11November1967:951E.M.R.Kiremire,HoleFormalismandItsEffectonPartialandRSTerms,JournalofChemicalEducation,Volume66Number6June1989479J.Rubio,J.J.Perez,EnergyLevelsinthejjcouplingScheme,JournalofChemicalEducation,Volume63Number6June1986:476EnsignStevenJ.Gauerke,USN,MarkL.Campbell,ASimple,SystematicMethodforDeterminingJLevelsforjjCoupling,JournalofChemicalEducation,Volume71Number6June1994457第三章分子光譜項SimoneMorpurgo,GroupTheoryandCrystalFieldTheory:ASimpleandRigorous2DerivationoftheSpectroscopicTermsGeneratedbythet2gElectronicConfigurationinaStrongOctahedralField,Journalof ChemicalEducation,Vol.84No.1January2007:151R.M.Mazo,“Molecularelectronictermandmolecularorbitalconfigurations,”J.Chem.Educ.1990,67(2),135-138(1990).R.L.Ellis,H.H.Jaffe,TheSymmetriesandMultiplicitiesofElectronicStatesinPolyatomicMolecules,JOURNALOFCHEMICALEDUCATION,Volume48,Number2,February1971:93E.M.R.Kiremire,PartialandLigandFieldTerms,JournalofChemicalEducation,Volume67Number3March1990:216D.I.Ford,MolecularTermSymbolsbyGroupTheory,JournalofChemicalEducation,Volume49,Number5,May1972:336
第四章有趣的物理化學現(xiàn)象[33]Najdoski,Metodija;Mirceski,Valentin;Petru?evski,VladimirM.;Demiri,Sani,MercuryBeatingofChemicalEducation,Heart:ModificationsJournalofChemicaltotheClassicalDemonstrationEducation,Vol.84No.8August第四章有趣的物理化學現(xiàn)象[33]Najdoski,Metodija;Mirceski,Valentin;Petru?evski,VladimirM.;Demiri,Sani,MercuryBeatingofChemicalEducation,Heart:ModificationsJournalofChemicaltotheClassicalDemonstrationEducation,Vol.84No.8August,Journal2007:1292[34]Keizer,J.;Rock,P.A.;Lin,Shu-WaiJ.Amer.Chem.Soc.1979,101,5637-5649David,Chemicallyinducedpulsationsofinterfaces:Themercurybeatingheart,JournalofChemicalEducation,Volume66Number3March1989:211[36]JamesL.Ealy,Jr,GalliumBeatingHeart,GalliumBeatingHeart,JournalofChemicalEducation,Volume70Number6June1993:491[37]Prypsztejn,HernanE.ChemiluminescentOscillatingDemonstrations:TheChemicalBuoy,theLightingWave,andtheGhostlyCylinder,JournalofChemicalEducation,JournalofChemicalEducation,Vol.82No.1January2005:53Melka,RichardF.;Olsen,Gary;Beavers,Lindsay;Draeger,J.AThekineticsofoscillatingreactions:Laboratoryexperimentforphysicalchemistry,JournalofChemicalEducation,Volume69Number7July1992:596J.A.Campbell,Kinetics-EarlyandOften,JournalofChemicalEducation,Volume40,Number11,November1963:579A.GilbertCook,RandiM.Tollive,JanelleE.Williarns,TheBlueBottleExperimentRevisited,JournalofChemicalEducation,1994,Vol.71No.2:160WalterR.Vandaveer,etal.TheBlueBottleRevisited,JournalofChemicalEducation,Vol.74No.4April1997:402WhitneyE.Wellman,MarkE.Noble,TomHealy,GreeningtheBlueBottle,JournalofChemicalEducation,Vol.80No.5May2003:537Gisser,KathleenR.C.etalMemoryMetal:A"Smart"MaterialExhibitingaSolid-StatePhaseChangeandSuperelasticity,JournalofChemicalEducation,January,Volume71Number4April1994:335,Vol.82JCEEditorialStaff ,MemoryMetal,Vol.82No.10October2005:1488AArthurB.Ellis,Superconductors,JournalofChemicalEducation,Volume64Number10October1987:837Sahu,Devaraj;Langner,Andreas;Geor
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